The reactions of the mixed metal cluster complexes PtRu
5(CO)
16(μ
6-C)[Pt(PBu
)],
5 and PtRu
5(CO)
16(μ
6-C)[Pt(PBu
]
2,
6 with selected alkynes have been investigated. Compound
5 adds one and two equivalents of PhC
2H to yield the new compounds PtRu
5(CO)
15(μ
6-C)(μ
3-PhC
2H)[Pt(PBu
)],
8 and PtRu
5(CO)
-C)(
-PhC
2H)
2[Pt(PBu
)],
9 at 40 and 68°C, respectively. Compound
6 was found to react with PhC
2H at 40°C to yield the new compound PtRu
5(CO)
-C)(
-PhC
2H)[Pt(PBu
)]
2,
10. The reaction of
6 with PhC
2Ph at 97°C yielded the new compound PtRu
5(CO)
-C)(
-PhC
2Ph)
2[Pt(PBu
)]
2,
11. All products were characterized crystallographically by single crystal X-ray diffraction techniques. The structure of
8 consists of a pseudo-octahedral PtRu
5 cluster with a second platinum atom bridging a basal edge of the Ru
5 square pyramid. A triply bridging PhC
2H ligand is bonded to the two platinum atoms and one of the ruthenium atoms. The structure of
9 consists of a
nido-dodecahedral Pt
2Ru
5 cluster with a carbido ligand in the interior that is not bonded to all seven of the metal atoms. It also contains two triply
bridging PhC
2H ligands. The structure of
10 consists of a central octahedral cluster of five ruthenium atoms and one platinum atom. Two additional platinum atoms are
bonded to the platinum atom in this cluster but these atoms are not bonded to any other metal atoms of the PtRu
5 cluster. A triply bridging PhC
2H ligand is coordinated to the group of three platinum atoms. The structure of
11 consists of an octahedral PtRu
5 cluster with two additional platinum atoms capping two PtRu
2 triangular faces. There are two PhC
2Ph ligands bridging two Ru
3 triangular faces of the central octahedron.
This report is dedicated to Professor Ilya Moiseev on the occasion of his 75th birthday for his many pioneering contributions
to the chemistry of metal clusters.
相似文献