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101.
The corrosion behavior and surface morphology of Ni–SiC composite coatings produced by electrodeposition with the aid of magnetic
field were studied. The results of the electrochemical analysis including polarization resistance and potentiodynamic polarization
curves showed that a magnetic field of 0.1 T could significantly improve the corrosion resistance of the composite. The electrochemical
impedance spectra revealed that a passive layer was formed on the surface of the Ni–SiC coating with the magnetic field. The
microstructures of electrodeposited Ni–SiC composite coatings were also examined. More SiC particles were found to be incorporated
into the coating with the presence of magnetic field, which was considered to be one of the reasons for the enhancement of
corrosion resistance as SiC particles were reported to be corrosion inhibitors.
Contribution to special issue “Magnetic field effects in Electrochemistry” 相似文献
102.
采用改进的Hummers法制备了氧化石墨烯,用水热法首次制备了Fe_3O_4/GO/PPy(聚吡咯)三元复合粒子用于处理含2-硝基-1,3-苯二酚(NRC)的废水,研究了其对水中NRC的吸附性能。采用紫外-可见吸收光谱(UV-Vis)、透射电子显微镜(TEM)、傅里叶变换红外光谱(FT-IR)、X射线衍射(XRD)、振动样品磁强计及ζ电位等对所制备复合粒子的结构进行了表征;研究了溶液pH值、吸附剂用量、NRC的初始浓度、吸附时间和温度对吸附NRC的吸附性能的影响,并对吸附过程进行了吸附动力学模拟。结果表明:制备的Fe_3O_4/GO/PPy复合材料为层状分散结构,PPy及Fe_3O_4颗粒无规则地镶嵌在石墨烯片层之间。Fe_3O_4颗粒为多面体晶体结构,尺寸为100~300 nm。Fe_3O_4/GO/PPy具有超顺磁性,40 s可以磁分离,NRC移除率达91.6%;在NRC浓度为200 mg·L~(-1)、pH=5±0.05、温度T=318 K、吸附剂用量10 mg·L~(-1)和吸附时间6 h的条件下Fe_3O_4/GO/PPy对NRC的吸附量最大,达到163.3mg·g~(-1)。NRC吸附动力学符合二级动力学模型,吸附等温线符合Langmuir模型。循环使用5次后,NRC的移除率由最初的91.6%下降至77.6%,说明Fe_3O_4/GO/Ppy磁性复合物的结构具有较好的稳定性,且可以再重复利用。 相似文献
103.
104.
Design of TiO2@graphene nanosheets with rough surface and its reinforcement to polyarylene ether nitriles 下载免费PDF全文
The interfacial interaction is extremely important when dealing with filler‐reinforced polymer materials. Herein, in order to improve the interfacial interaction with the polyarylene ether nitriles (PEN) matrix, a three‐dimensional rough structure was designed. First, needle‐like TiO2 nanocrystals were grown on each surface of the graphene. Morphology analysis proved that rough TiO2 nanocrystals were coated on the graphene nanosheets. Then, TiO2@graphene/PEN composites were fabricated to investigate the filler–matrix interaction. Thereafter, the different polymer chains could be interlocked by the TiO2 “needles” when the rough TiO2@graphene was embedded into the polymer resin. The surrounding PEN polymer chains (work as ropes) could tie to the “needles” (work as wood pile). That is to say, the effective polymer chain length was greatly lengthened, resulting in the improvement of interfacial interactions and mechanical properties. Most importantly, the morphology, mechanical and rheological tests of the composites also proved the improvement of interfacial interactions and mechanical properties. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
105.
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107.
研究了水润滑下炭纤维、石墨及聚四氟乙烯填充聚醚醚酮复合材料与不锈钢对摩时的摩擦磨损性能,利用扫描电子显微镜观察分析了磨损表面和磨屑形貌,利用X射线能量色散谱仪分析了磨损表面的元素组成.结果表明:炭纤维含量对摩擦副的摩擦系数影响不大,磨损率随着炭纤维含量的增加而减小;随着载荷增大,摩擦系数先降低而后升高,当载荷较小时,填充聚醚醚酮复合材料的磨损率随载荷增大而缓慢增加,当载荷超过一定值后,磨损率急剧增加;填充聚醚醚酮复合材料在较低载荷下主要呈现疲劳磨损特征,在较高载荷下主要呈现微切削特征. 相似文献
108.
玻璃纤维增强复合材料被广泛应用于航天、航空及其他军民各领域,它在制备和使用过程中通常会出现多个缺陷。太赫兹时域光谱成像技术有望成为玻璃纤维增强复合材料无损检测的有力补充手段。在太赫兹时域光谱成像过程中,可以选取时域或频域波形中的不同参数来进行成像。对于不同的缺陷,能够有效地对其进行检测的参数是不一样的。采用基于小波分解的图像融合方法将多幅不同参数获取的太赫兹反射图像结合起来,得到一幅包含所有缺陷信息的新图像。研究表明,基于小波分解的图像融合方法在太赫兹无损检测中的应用,能够获取单一参数成像无法检测的缺陷信息,为复合材料太赫兹图像后期处理提供了新的技术方法。 相似文献
109.
Electrical, dielectric and surface wetting properties of multi-walled carbon nanotubes/nylon-6 nanocomposites 下载免费PDF全文
This paper reports that the multi-walled carbon nanotubes(MWCNT)/nylon-6 (PA6) nanocomposites with different MWCNT loadingshave been prepared by a simple melt-compounding method. Theelectrical, dielectric, and surface wetting properties of theCNT/PA6 composites have been studied. The temperature dependence ofthe conductivity of the CNT/PA6 composite with 10.0 wt{\%} CNTloading ($\sigma _{\rm RT} \sim 10^{-4}$ S/cm) are measured, andafterwards a charge-energy-limited tunnelling model (ln $\sigma (T)\sim T^{-1/2})$ is found. With increasing CNT weight percentage from0.0 to 10.0 wt%, the dielectric constant of the CNT/PA6composites enhances and the dielectric loss tangent increases twoorders of magnitude. In addition, water contact angles of theCNT/PA6 composites increase and the composites with CNT loadinglarger than 2.0 wt%even become hydrophobic. The obtainedresults indicate that the electrical and surface properties of thecomposites have been significantly enhanced by the embedded carbonnanotubes. 相似文献
110.
The scattering behavior of P-waves in piezoelectric composites with 1–3 connectivity is studied. The method of wave function expansion is adopted for the theoretical derivations. Analytical expressions are obtained for the distributions of mechanical displacement in z-direction along the circumferences of piezoelectric cylinders. These solutions are used to study the influence of each element of the stiffness matrix and the piezoelectric matrix on the various resonant modes of vibration. Numerical results obtained indicate that perturbations of the elements c44 and e15 significantly affect resonant frequencies and amplitudes, perturbations of c11 and c12 have pronounced effects on resonant modes of high frequencies also. However, the resonant modes are not so sensitive to the perturbations of c13, e31 and e33. The dynamic characteristics of 1–3 connectivity piezoelectric composites exposed here are meaningful for the design and manufacture of sensor/actuator elements by this kind of composites as well as the on-line health monitoring of the mechanical properties variations of the composites itself. 相似文献