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21.
22.
室温或近室温固相反应要求绿色化、清洁化[1,2]。我们以KMnO4和MnCl2·4H2O为原料,用室温固相氧化还原反应制备氧化锰粉体时,得到了一种对H2O2分解具有较高催化活性的纳米KMn8O16粉体,用XRD、SEM、IR等技术对其进行了表征,发现研磨时间对粉体性能有显著影响。1 实验部分1 1 粉体的制备按摩尔比(2∶3)准确称取一定量的分析纯KMnO4和MnCl2·4H2O,分别置于玛瑙研钵中充分研细,再混合研磨,固相反应立即发生,体系颜色逐渐加深,并有刺激性气体产生,充分研磨后70℃恒温12h,固相产物依次经水洗至中性、醇洗、抽滤,真空干燥得黑色粉… 相似文献
23.
Qing An WU Zhen Yuan XU Mei ZHENG Dan Qian XU Jun XU Yin Chu SHENCollege of Chemical Engineering Materials Zhejiang University of Technology Hangzhou 《中国化学快报》2004,(7)
Six new 13-O-acylavermectin Bl aglycones(3-8) were synthesized from avermectin B1 aglycone and their bioactivities were evaluated against Spodoptera exigua, Spodoptera eridania, Tetranychus urticae and Aphis fabae. 相似文献
24.
The knowledge of hydrocarbon/water phase equilibria is important in the design and operation of equipment for petroleum transport and refining and petrochemical plants. The presence of water in a hydrocarbon mixture can affect the product quality and damage the operation equipment due to corrosion and formation of gas hydrates. Tracing the concentration of hydrocarbons in aqueous media is also important for technical purposes like preventing oil spills and for ecological concerns such as predicting the fate of these organic pollutants in the environment. 相似文献
25.
Zhihui Zhao Hui Dai Xiangmei Wu Haitao Chang Xiaoming Gao Mengjun Liu Pengfei Tu 《Chemistry of Natural Compounds》2007,43(4):374-376
A pectic polysaccharide was isolated from the fruits of Ziziphus jujuba Mill. cv. jinsixiaozao Hort. and its structure was characterized by acid hydrolysis, methylation, and NMR spectroscopies.
The purified fraction Ju-B-7 had a molecular mass of over 2000 kDa. Chemical and spectroscopic analyses indicated that Ju-B-7
is composed mainly of α-1,4-linked D-galactopyranosyluronic acid and 1,2-linked L-rhamnose with a molar ratio of 8.1:1. It can significantly stimulate
spleen cell proliferation in vitro (P<0.01, 10 μmg/mL).
Published in Khimiya Prirodnykh Soedinenii, No. 4, pp. 311–312, July–August, 2007. 相似文献
26.
Utilization of carbohydrates by radiation processing 总被引:2,自引:0,他引:2
Upgrading and utilization of carbohydrates such as chitosan, sodium alginate, carrageenan, cellulose, pectin have been investigated for recycling these bio-resources and reducing the environmental pollution. These carbohydrates were easily degraded by irradiation and various kinds of biological activities such as anti-microbial activity, promotion of plant growth, suppression of heavy metal stress, phytoalexins induction, etc. were induced. On the other hand, some carbohydrate derivatives, carboxymethylcellulose and carboxymethylstarch, could be crosslinked under certain radiation condition and produce the biodegradable hydrogel for medical and agricultural use. 相似文献
27.
J. C. Raines J. P. Schmidt J. P. Burelbach H. K. Fauske 《Journal of Thermal Analysis and Calorimetry》2006,85(1):53-55
Hydrogen
peroxide is a very versatile oxidizing agent, and it is also environmentally
compatible considering that the products of its exothermic decomposition are
oxygen and water.When kept in a clean temperature-controlled environment,
the self-reaction (decomposition) rate is extremely low. However, it is well
known that even a small amount of contamination will dramatically increase
the reaction rate. This paper describes the use of the fast thermal activity
interpreter (FTAI) instrument to examine the chemical reactivity of commercially
available 50% hydrogen peroxide at two different temperatures (30 and 40°C)
both with and without contamination. The results show that at 30°C a small
amount of rust (330 ppm) increases the reaction rate of 50% hydrogen peroxide
by a factor of 50. When the temperature is increased to 40°C, the reaction
rate is further increased by almost a factor of four. The implication for
reactivity management is that at this contamination level most practical vessel
sizes would require emergency venting capability.
An evaluation
was then performed to determine the emergency venting requirement for the
safe transportation or storage of the contaminated hydrogen peroxide. It was
determined that for quantities of the material less than 5 gallons, conventional
breather vents would be sufficient to accommodate the gas evolved. However,
for larger quantities, a safety relief device would be needed. For example,
for a 400-gallon tote bin at 40°C the required minimum vent area is estimated
to be 4.3 in2, corresponding to a minimum vent
diameter of 2.3 inches. 相似文献
28.
Maria G. Semenova Larisa E. Belyakova Anna S. Antipova Yu. N. Polikarpov Lida Klouda Anna Markovic Michael M. Il'in 《Colloids and surfaces. B, Biointerfaces》2003,31(1-4):47-54
We report on the effect of commercially important polysaccharides (maltodextrins with variable dextrose equivalent (Paselli SA-2, MD-6 and MD-10) on the surface activity at the air–water interface of small-molecule surfactants (sms), possessing different hydrophobic–lipophilic balance ((SSL (Na+), the main component is a sodium salt of stearol–lactoyl lactic acid, and PGE (080), polyglycerol ester of C18 fatty acid), and widely used in food products. A marked change of the surface activity of sms was found in the presence of maltodextrins by tensiometry. The combined data of laser multiangle light scattering and mixing calorimetry have suggested that this result is governed by specific complex formation between maltodextrins and sms in aqueous medium. Measurements have been made of the molar mass, the second virial coefficient and the enthalpy of intermolecular interactions in aqueous solutions. The implication of a degree of polymerization of maltodextrins in this phenomenon was shown. The interrelation between the molecular parameters of the formed complexes and their surface activity at the air–water interface has been revealed and discussed. 相似文献
29.
This paper presents a quantum chemical calculation of native (2–7 fructoside residues) and chemically modified (2–4 fructoside residues) levan molecule models. A levan modification was carried out by oxidation and the following reduction or hyrdazonation of the fructoside rings. The conformational particularity and reaction ability was studied for the native and for the modified levan molecules. 相似文献
30.
The major achievements of the G. F. Gauze Scientific-Research Institute of New Antibiotics, Russian Academy of Medical Sciences, over the last 50 years are reviewed. The structures of antibiotics and related compounds discovered at the Institute and important for medical practise and/or of theoretical interest as new compounds with high biological activity are described.Dedicated to the memory of Director of the G. F. Gauze Scientific-Research Institute of New Antibiotics, Russian Academy of Medical Sciences, and Corresponding Member of the Russian Academy of Medical Sciences Prof. Yu. V. Dudnik (1938–2003).Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1603–1618, November, 2004. 相似文献