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251.
Kun-Pyo Hong Young-Hyun Choi Young-Uk Kwon Duk-Young Jung Jeong-Soo Lee Hae-Sub Shim Chang-Hee Lee 《Journal of solid state chemistry》2000,150(2):383
The crystal structures of double perovskite BaLaMRuO6 (M=Mg, Zn) obtained from the refinements on both X-ray and neutron diffraction data, different from those reported previously that used either X-ray or neutron diffraction data alone, are reported. The room temperature X-ray and neutron data were refined with a model in the tetragonal space group I4/m (a=5.6230(4), c=7.964(1) Å, V=251.81(4) Å3 for M=Mg; a=5.6521(3), c=7.9987(9) Å, V=255.53(3) Å3 for M=Zn). The low-temperature neutron diffraction data of the two compounds are also refined in the same space group (a=5.6156(4), c=7.953(1) Å, V=250.80(4) Å3 for M=Mg at 13 K; a=5.6418(4), c=7.981(1) Å, V=254.03(4) Å3 for M=Zn at 10 K). Both compounds show almost complete ordering of B-site atoms (M/Ru). For both compounds, the low-temperature neutron diffraction data below about 20 K showed magnetic diffraction peaks that could be accounted for with a Type I antiferromagnetic ordering of Ru spins in an atomically ordered double perovskite structure. These compounds showed discrepancies between field cooled and zero field cooled magnetization data below the antiferromagnetic ordering temperatures. 相似文献
252.
E. Chappel M.D. Núñez-Regueiro F. Dupont G. Chouteau C. Darie A. Sulpice 《The European Physical Journal B - Condensed Matter and Complex Systems》2000,17(4):609-614
Magnetisation measurements up to 23 T and submillimeter wave ESR in the frequency region 48-380 GHz have been performed on
NaNiO2 powders at low temperature. Also typical spectra above the Néel temperature are shown. At 4 K the magnetisation shows a spin-flop transition at 1.8 T and saturation at 10 T. /Ni confirms the low spin state of the Ni3+ ions. The susceptibility exhibits a maximum at K with and K. NaNiO2 is an A-type antiferromagnet: we derive K and K for the interactions between Ni ions within and between adjacent layers, respectively. The AFMR spectra yield an energy
gap of 52.5 GHz, in agreement with the spin-flop value derived from the magnetisation. The anisotropy of the g factor observed at 100 K with can be attributed to the Jahn-Teller effect for Ni3+ ions in the low spin state, which stabilises the occupation. We finally comment on the isomorphic controversial Li1-xNi1+xO2 compound.
Received 9 March 2000 and Received in final form 13 July 2000. 相似文献
253.
By using density matrix renormalization group (DMRG) method a model for organic molecule-based ferromagnetic chain is proposed. It is found that the ground states of undoped and doped systems both exhibit ferrimagnetic ordering. The e-e repulsion plays an important role in the stability of the ferromagnetic state either in doped system or undoped system. For the undoped system, each unit cell contains half of the total spins, which is consistent with Lieb‘s theorem. It is convinced that when the system is doped with one electron, a charge density wave is excited, which decreases the amplitude of spin density wave, therefore acting against the stability of ferromagnetic state. 相似文献
254.
采用铁磁共振方法,研究了交换各向异性和应力各向异性对铁磁/反铁磁双层薄膜性质的影响。结果表明:界面交换作用导致单向各向异性,应力各向异性对材料的磁化难易程度有较大影响。在外磁场方向接近应力场方向时,共振频率向高值方向移动,其它区域共振频率则向低值方向移动。对频率线宽而言,接近应力场方向,频率线宽加宽,其它区域频率线宽则变窄。此外,当磁场变化时,应力的存在使得共振频率向低值方向移动,尤其在β=π方向情况较为复杂,在弱场范围出现了两个区域:即在某磁场范围内,共振频率向高值方向移动,且频率线宽加宽;而其它范围的共振频率(线宽)是向高值方向移动(加宽)还是向低值方向移动(变窄),取决于外磁场的相对强弱。 相似文献
255.
Dr. Qiuhua Liang Prof. Dr. Geert Brocks Dr. Anja Bieberle-Hütter 《Chemphyschem》2023,24(5):e202200429
Magnetic exchange force microscopy (MExFM) is an important experimental technique for mapping the magnetic structure of surfaces with atomic resolution relying on the spin-dependent short-range exchange interaction between a magnetic tip and a magnetic surface. RuO2 is a significant compound with applications in heterogeneous catalysis and electrocatalysis. It has been characterized recently as an antiferromagnetic (AFM) material, and its magnetism has been predicted somewhat surprisingly to play an important role in its catalytic properties. In the current study, we explore theoretically whether MExFM can visualize the magnetic surface structure of RuO2. We use density functional theory (DFT) calculations to extract the exchange interactions between a ferromagnetic Fe tip interacting with an AFM RuO2(110) surface, as a function of tip-surface distance and the position of the tip over the surface. Mimicking the MExFM experiment, these data are then used to calculate the normalized frequency shift of an oscillating cantilever tip versus the minimum tip-surface distance, and construct corrugation height line profiles. It is found that the exchange interaction between tip and surface is strongest for a parallel configuration of the spins of the tip and of the surface; it is weakest for an anti-parallel orientation. In a corrugation profile, this gives rise to a sizable height difference of 25 pm between the spin-up and spin-down Ru atoms in the RuO2(110) surface at a normalized frequency shift =−10.12 fNm1/2. The O atoms in the surface are not or hardly visible in the corrugation profile. 相似文献
256.