全文获取类型
收费全文 | 5433篇 |
免费 | 578篇 |
国内免费 | 1479篇 |
专业分类
化学 | 3557篇 |
晶体学 | 54篇 |
力学 | 1037篇 |
综合类 | 76篇 |
数学 | 1564篇 |
物理学 | 1202篇 |
出版年
2024年 | 11篇 |
2023年 | 80篇 |
2022年 | 117篇 |
2021年 | 225篇 |
2020年 | 233篇 |
2019年 | 209篇 |
2018年 | 183篇 |
2017年 | 206篇 |
2016年 | 285篇 |
2015年 | 197篇 |
2014年 | 281篇 |
2013年 | 542篇 |
2012年 | 323篇 |
2011年 | 362篇 |
2010年 | 311篇 |
2009年 | 341篇 |
2008年 | 322篇 |
2007年 | 385篇 |
2006年 | 338篇 |
2005年 | 350篇 |
2004年 | 363篇 |
2003年 | 273篇 |
2002年 | 255篇 |
2001年 | 206篇 |
2000年 | 163篇 |
1999年 | 155篇 |
1998年 | 123篇 |
1997年 | 88篇 |
1996年 | 72篇 |
1995年 | 95篇 |
1994年 | 64篇 |
1993年 | 64篇 |
1992年 | 54篇 |
1991年 | 36篇 |
1990年 | 31篇 |
1989年 | 19篇 |
1988年 | 15篇 |
1987年 | 20篇 |
1986年 | 9篇 |
1985年 | 14篇 |
1984年 | 14篇 |
1983年 | 7篇 |
1982年 | 10篇 |
1981年 | 5篇 |
1980年 | 5篇 |
1979年 | 8篇 |
1978年 | 6篇 |
1977年 | 4篇 |
1976年 | 4篇 |
1973年 | 4篇 |
排序方式: 共有7490条查询结果,搜索用时 46 毫秒
51.
提出了线性扫描溶出伏安法测定福美双的电分析化学方法.在 pH 5.0 HAc-NaAc缓冲溶液中福美双在汞电极上出现一还原峰,峰电位为-610 mV(vs.Ag/AgCl).采用各种电化学技术如循环伏安法和线性扫描溶出伏安法等对本体系进行研究,发现采用线性扫描溶出伏安法能得到较灵敏的还原峰,呈现不可逆电极反应现象,并具有一定的吸附性,在210 s时能达到吸附平衡.选择吸附时间为180 s时,线性范围为0.02~0.14 μg·mL-1,最低检测限为9.5 ng·mL-1.将本方法用于实际样品的测定,得到满意的结果. 相似文献
52.
We quantify the long-time behavior of solutions to the nonlinear Boltzmann equation for spatially uniform freely cooling inelastic Maxwell molecules by means of the contraction property of a suitable metric in the set of probability measures. Existence, uniqueness, and precise estimates of overpopulated high energy tails of the self-similar profile proved in ref. 9 are revisited and derived from this new Liapunov functional. For general initial conditions the solutions of the Boltzmann equation are then proved to converge with computable rate as t → ∞ to the self-similar solution in this distance, which metrizes the weak convergence of measures. Moreover, we can relate this Fourier distance to the Euclidean Wasserstein distance or Tanaka functional proving also its exponential convergence towards the homogeneous cooling states. The findings are relevant in the understanding of the conjecture formulated by Ernst and Brito in refs. 15, 16, and complement and improve recent studies on the same problem of Bobylev and Cercignani(9) and Bobylev, Cercignani and one of the authors.(11) 相似文献
53.
54.
Liang Ruixi Peng Jun Shen Jianhua 《Annals of Differential Equations》2006,22(4):502-510
The boundedness of the every solution and the asymptotic behavior of all solutions of the nonlinear neutral delay differential equation [x(t) - P(t)x(t - t)]' Q1 (t)f(x{t-σ1))-Q2(t)f(x(t -σ2))=0,t≥t0 are investigated, whereτ,σ1,σ2∈(0,∞), P∈C([t0,∞),R), and Q1,Q2∈C([t0,∞),R), f∈C(R,R). The sufficient conditions obtained improve the existing results in the literatures. 相似文献
55.
56.
一个反应扩散方程的门槛结果 总被引:4,自引:0,他引:4
本文讨论反应扩散方程Cauchy问题解的整体存在性,渐近性质和Blowup问题.其中或者1<q<p<+∞,n=2.得到门槛结果. 相似文献
57.
Michelina Soccio Lara Finelli Nadia Lotti Valentina Siracusa Tiberio A. Ezquerra Andrea Munari 《Journal of Polymer Science.Polymer Physics》2007,45(13):1694-1703
Poly(butylene naphthalate) (PBN), poly(diethylene naphthalate) (PDEN), and poly(thiodiethylene naphthalate) (PTDEN) were synthesized and characterized in terms of chemical structure and molecular weight. The polyesters were examined by TGA, DSC, and DMTA. All the polymers showed a good thermal stability, even though depending on chemical structure. At room temperature they appeared as semicrystalline materials; the effect of the introduction along the PBN polymer chain of ether oxygen atoms or sulfur ones was a lowering in the Tg value, a decrement of Tm, and a decrease of the crystallization rate. Changing in chemical structure also affects the main α absorption associated with the glass transition which moves to lower temperature and whose energetic requirements decrease. The results were explained as due to the presence of highly flexible C? S? C or C? O? C bonds in the polymeric chain. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1694–1703, 2007 相似文献
58.
Stefan Jaschke Claudia Klüppelberg Alexander Lindner 《Journal of multivariate analysis》2004,88(2):252-273
We derive results on the asymptotic behavior of tails and quantiles of quadratic forms of Gaussian vectors. They appear in particular in delta–gamma models in financial risk management approximating portfolio returns. Quantile estimation corresponds to the estimation of the Value-at-Risk, which is a serious problem in high dimension. 相似文献
59.
We study a system of quasilinear equations describing one-dimensional flow of a viscous compressible heat-conducting medium with a nonmonotone state function and mass force. The large-time behavior of solutions is considered for arbitrarily large initial data. In spite of possible nonuniqueness and discontinuity of the stationary solution, we prove L2-stabilization for the stress and heat flux as t → ∞ along with corresponding global energy estimates for them. The new method of proof utilizes a combination of energy type equalities for the stress and heat flux. Consequently, H1-stabilization of the velocity and temperature along with global estimates for their derivatives are valid as well. 相似文献
60.