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71.
A. S. Lobach B. P. Tarasov Yu. M. Shul'ga A. A. Perov A. N. Stepanov 《Russian Chemical Bulletin》1996,45(2):464-465
Fullerene deuteride was obtained by the reaction of deuterium with solid palladium fulleride C60Pd4.9 under fairly mild conditions. The compound was identified by FD-MS, UV-Vis and IR spectroscopies, and TLC.Translated from Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 483–484, February, 1996 相似文献
72.
The stability of Ochratoxin A during its extraction using different extraction techniques has been evaluated. Microwave-assisted extraction and pressurised liquid extraction, in addition to two other reference methods of extraction, i.e. ultrasound-assisted and magnetic stirring-assisted extraction, were evaluated. The effect of extraction temperature using the cited techniques was checked.The results show that Ochratoxin A can be extracted using microwave-assisted extraction at temperatures up to 150 °C without degradation. Pressurised liquid extraction can be used at temperatures up to 100 °C, for extraction times of less than 30 min. Further, both ultrasound-assisted extraction and magnetic stirring extraction can be applied at temperatures up to 65 °C.High-performance liquid chromatography combined with fluorescence detection using a Chromolith RP-18e column at a flow rate of 5 mL min−1 was used to quantify the Ochratoxin A. The retention time for the Ochratoxin A was 1.3 min. The limits of detection (LOD) and of quantification (LOQ) were 0.03 and 0.10 μg L−1, respectively. 相似文献
73.
HPLC-MS/MS技术在中华绒螯蟹硝基呋喃类代谢物残留量检测中的应用 总被引:3,自引:0,他引:3
建立了中华绒螯蟹中硝基呋喃类代谢物残留量的液相色谱-串联质谱检测方法.取均质后的中华绒螯蟹可食部分样品,用盐酸水解组织中蛋白结合代谢物,经2-硝基苯甲醛37℃过夜衍生化,调节pH值至约7.0~7.4后,用乙酸乙酯提取,正己烷净化.选用电喷雾离子源,在正离子、多反应监测方式模式下进行定性,以同位素内标法进行定量.方法的检出限为0.5 μg·kg-1,工作曲线的线性范围为1.25~50.0 μg·L-1.在添加浓度为0.5~10.0 μg·kg-1的范围内,AMOZ、SEM、AHD和AOZ的回收率分别在92.8%~106%、84.5%~94.6%、80.6%~98.6%和88.4%~105%之间,相对标准偏差均小于10%. 相似文献
74.
The knowledge of hydrocarbon/water phase equilibria is important in the design and operation of equipment for petroleum transport and refining and petrochemical plants. The presence of water in a hydrocarbon mixture can affect the product quality and damage the operation equipment due to corrosion and formation of gas hydrates. Tracing the concentration of hydrocarbons in aqueous media is also important for technical purposes like preventing oil spills and for ecological concerns such as predicting the fate of these organic pollutants in the environment. 相似文献
75.
On‐line coupling of LC and ICP‐MS has been used for fractionation and detection of species of Cu, Fe, I, Se and Zn in human serum. It has been shown that anion exchange chromatography provided better separation capability (both intra‐ and inter‐element) than size‐exclusion chromatography. The mobile phases for ion exchange chromatography consisted of Tris–HNO3 buffer and ammonium salt (nitrate, acetate or formate). Formate was found to be the best mobile phase counter ion, enabling good chromatographic separation, and is acceptable for mass spectrometry too. The quantitative evaluation of element concentrations adhering to individual fractions was performed by the peak area normalization method. The repeatability of results ranged from 3 to 15% (depending on the element concentration level) and represented the main part of the result uncertainty. The accuracy of Cu and Zn fraction determinations was confirmed by comparison with the isotope dilution technique. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
76.
E. V. Ermanyuk 《Experiments in fluids》2002,32(2):242-251
This paper presents a study on affine similitude for the force coefficients of an arbitrary body oscillating in a uniformly
stratified fluid. A simple formula is derived that gives a relation between the force coefficients for a body oscillating
in homogeneous and uniformly stratified ideal fluids. In particular, it implies the existence of a universal nondimensional
similitude criterion for a family of affinely similar bodies, namely, the bodies that can be transformed into each other by
vertical dilation of the initial coordinate system. Theoretical results are verified by experiments with a set of spheroids
having different length-to-diameter ratios. The experimental technique for evaluation of the frequency-dependent force coefficients
is based on Fourier analysis of the time-history of damped oscillation tests.
Received: 25 September 2000 / Accepted: 6 July 2001 Published online: 29 November 2001 相似文献
77.
Buffer gas beam coolers may become excellent beam preparation devices for high-resolution mass separation. The small beam
emittance provided makes efficient isobar resolution a realistic goal. In order to fulfill the needs of future facilities
providing high-intensity beams of rare isotopes, it is desirable to increase the beam intensity limit of such devices from
typically several tens of nanoamperes to microamperes. This requires the usage of high-voltage radiofrequencies in a low-pressure
gas environment. A buffer gas beam cooler, dedicated to this purpose, is under development at the NSCL. The study of voltage
breakdowns under such conditions and the design of an electrode system minimizing them is mandatory.
相似文献
78.
79.
简析"静止液体内部压强公式验证"实验的设计策略 总被引:1,自引:1,他引:0
“静止液体内部压强公式验证”在现行教材中有两种实验方法。通过分析实验的设计策略,说明其作用、效果及操作上的困难,指出合理的与不合理诸因素,从而提出改进实验的方法,化难为易,提高实验教学效果。 相似文献
80.
P. Paasche T. Valenzuela D. Biswas C. Angelescu G. Werth 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,18(3):295-300
We have examined experimentally the motional spectrum of an electron cloud confined in a Penning trap. When the axial oscillation
is excited by a radio frequency field the resonance exhibits a double structure. Both components depend differently on the
number of trapped electrons and have different shape and width. We conclude that one of them corresponds to the excitation
of the individual electrons while the other is the center-of-mass mode of the cloud. The threshold behaviour of the center-of-mass
resonance suggests that it is a parametric instability of a Mathieu type equation of motion.
Received 11 July 2001 and Received in final form 12 November 2001 相似文献