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991.
《Physics and Chemistry of Liquids》2012,50(1):111-114
Recent ab initio predictions concerning the metal-insulator (MI) transition in rings of the light alkali atoms, Li and Na, are compared and contrasted with experimental facts concerning diluted Rb and Cs alkalis. The main focus here is on the local coordination number as a function of density as these two heavy alkali metallic fluids are taken along the liquid–vapour coexistence curve towards the critical point, which in these cases coincides with the MI transition. Also recorded are the results of experiments in which Cs chains are observed at large interatomic spacing outside semiconducting substrates of InSb and GaAs. 相似文献
992.
Abil E. Aliev Alex J. Sinclair Shen Zhou John D. Wilden Stephen Caddick Dimitri M. Kullmann Dmitri A. Rusakov 《Journal of Physical Organic Chemistry》2009,22(6):607-612
While developing a synthesis towards tagged dizocilpine (MK‐801) analogues, we observed highly restricted inversion of a nitrogen centre in a number hydroxylamines obtained as key intermediates. These compounds are shown to possess some of the structural elements which are expected to significantly hinder the nitrogen inversion, potentially leading to hydroxylamines with a chiral nitrogen centre. Free energy barriers (ΔG≠) of the nitrogen inversion were estimated to be ca. 22 kcal mol?1 at temperatures near 420 K using variable temperature NMR measurements in DMSO‐d6. Further density functional studies of a number model systems were undertaken in order to better rationalize the measured inversion barriers and follow the role of various structural factors in raising the barrier height of the nitrogen inversion process. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
993.
994.
Several transition metal salts, as solids, were exposed to gaseous ammonia at room temperature in a cell designed to allow measurement of infrared energy absorption at various pressures. For those salts which did form compounds with the ammonia, the new absorption bands are discussed in reference to spectra of amine complexes of known composition. 相似文献
995.
Jessica M. Torres Christopher M. Stafford David Uhrig Bryan D. Vogt 《Journal of Polymer Science.Polymer Physics》2012,50(5):370-377
The modulus and glass transition temperature (Tg) of ultrathin films of polystyrene (PS) with different branching architectures are examined via surface wrinkling and the discontinuity in the thermal expansion as determined from spectroscopic ellipsometry, respectively. Branching of the PS is systematically varied using multifunctional monomers to create comb, centipede, and star architectures with similar molecular masses. The bulk‐like (thick film) Tg for these polymers is 103 ± 2 °C and independent of branching and all films thinner than 40 nm exhibit reductions in Tg. There are subtle differences between the architectures with reductions in Tg for linear (25 °C), centipede (40 °C), comb (9 °C), and 4 armed star (9 °C) PS for ≈ 5 nm films. Interestingly, the room temperature modulus of the thick films is dependent upon the chain architecture with the star and comb polymers being the most compliant (≈2 GPa) whereas the centipede PS is most rigid (≈4 GPa). The comb PS exhibits no thickness dependence in moduli, whereas all other PS architectures examined show a decrease in modulus as the film thickness is decreased below ~40 nm. We hypothesize that the chain conformation leads to the apparent susceptibility of the polymer to reductions in moduli in thin films. These results provide insight into potential origins for thickness dependent properties of polymer thin films. © 2011 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2012 相似文献
996.
In this Letter, self-organization of directed networks is surveyed. Inspired from the results in neural networks research, we propose an asymmetric coupling scheme with simple edge deleting rules. Results show that all-to-all networks can be organized into scale-free networks with feed-forward structures. Corresponding analysis is also given. 相似文献
997.
998.
Consider K ≥ 2 independent copies of the random walk on the symmetric group SN starting from the identity and generated by the products of either independent uniform transpositions or independent uniform neighbor transpositions. At any time $n\in \mathbb{N}$, let Gn be the subgroup of SN generated by the K positions of the chains. In the uniform transposition model, we prove that there is a cut‐off phenomenon at time N ln(N)/(2K) for the non‐existence of fixed point of Gn and for the transitivity of Gn, thus showing that these properties occur before the chains have reached equilibrium. In the uniform neighbor transposition model, a transition for the non‐existence of a fixed point of Gn appears at time of order $N^{1+\frac{2}{K}}$ (at least for K ≥ 3), but there is no cut‐off phenomenon. In the latter model, we recover a cut‐off phenomenon for the non‐existence of a fixed point at a time proportional to N by allowing the number K to be proportional to ln(N). The main tools of the proofs are spectral analysis and coupling techniques. © 2011 Wiley Periodicals, Inc. Random Struct. Alg., 2012 相似文献
999.
Jinghui Li 《Journal of Dispersion Science and Technology》2017,38(12):1738-1743
In this work, we prepared a tertiary amide-based gemini surfactant (DSTAPA), which contained two pH-sensitive tertiary amide head groups. Then the molecule state distribution and self-assembly transition of the surfactant in aqueous solution were investigated under different pH conditions. The DSTAPA molecules were on the states of double cationic (DSTAPAH2+), single cationic (DSTAPAH+), and double tertiary amine groups (DSTAPA) under acidic, neutral, and basic conditions, respectively. With the variation of the molecule states, the sample was water-like below pH of 6.8 and immediately transformed to gel-like fluid between pH of 6.8 and 7.8, then changed to white precipitate with the further increase of pH value. Furthermore, the microstructure and regulation mechanism were investigated by rheological measurements, dynamic light scattering, and cryogenic transmission electron microscopy. The appearance and micelle transitions of the DSTAPA aqueous solution are actually owing to the spherical–worm-like micelle transition, leading to dramatic viscosity increase and hydrogel formation. This transition was completely reversible and repeated for at least three cycles. Finally, a reasonable mechanism of the transition was proposed based on the viewpoints of the molecular states and micelle structures. The DSTAPA aqueous system with pH-reversible property has a great potential application in oil and gas production. 相似文献
1000.