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41.
42.
研究了四元体系CsCl-LaCl3-HCl-H2O(25℃、「HCl」=13%(wt),23%(wt)和CsCl-LaCl3-HAc-H2O(30℃,「HAc」=42%(wt))的平衡态的溶度数据,并给出制了相应的溶度图,共得到了CsCl.LaCl3.4H2O、2CsCl.LaCl3.2H2O和3CsCl.LaCl3.3H2O3种化合物。对得到的新相进行了热分析,X射线粉末衍射及偏光性质的测定,依 相似文献
43.
Vapor pressure,speciation, and chemical activities in highly concentrated sodium borate solutions at 277 and 317°C 总被引:2,自引:0,他引:2
Oleh Weres 《Journal of solution chemistry》1995,24(5):409-438
The system H2O-B2O3-Na2O has been studied experimentally at 277 and 317°C. The activities of water and boric acid have been determined at mole ratios Na/B from 0 to 1.5, and total dissolved solids 3 to 80 weight percent. The activity of boric acid has been fitted to within experimental error using a speciation model with eight complex species. This model is consistent with the model previously published by Mesmer et al. The electrolyte properties of the liquid are modeled using the Pitzer-Simonson model of very concentrated electrolyte solutions. The calculated values of water activity agree with experiment, and the activity of NaOH and pOH have also been calculated. The potassium borate system also was briefly studied at 317°C, and is adequately described by a model with five complex species. The potassium borate liquid is more alkaline at K/B= 1 than a sodium borate liquid at the same mole ratio, but pOH in the two systems is the same at lower mole ratios. 相似文献
44.
丙醇-氯化钠双水相体系萃取分离铂、钯、铑、金中的铱及其吸收光谱分析研究 总被引:12,自引:0,他引:12
提出了一种丙醇-氯化钠双水相体系萃取铱的分离-吸收光谱分析方法,在HCl介质中基于铱生成三氯亚锡酸络阴离子动力学速率与铂、钯、铑、金差异使铱与铂、钯、铑、金分离,其后在KI介质中萃取铱使其与贱金属基体分离,研究了在丙醇萃取相中铱的吸收光谱分析,并应用于实际样品中铱的测定。 相似文献
45.
46.
R. F. Bakeeva L. Yu. Tartykova L. A. Kudryavtseva V. E. Bel'skii N. V. Usol'tseva B. E. Ivanov 《Russian Chemical Bulletin》1992,41(5):817-821
The kinetics of decomposition of p-nitrophenyldimethyl thiophosphate (1) were investigated spectrophotometrically in the n-decylammonium chloride-n-decylamine-water system (DAC-DA-H2O), in which micellar or lamellar liquid-crystalline phases are formed as a function of the concentration of components. It was shown that1 is dealkylated in both phases. An increase in the surface charge density of associates decreases the rate of dealkylation. The activation energy in the lamellar phase is significantly higher than in the micellar phase.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Scientific Center, Russian Academy of Sciences, 420083 Kazan'. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 5, pp. 1042–1048, May, 1992. 相似文献
47.
Simple two-parameter Hückel and Pitzer equations were used for the calculation of the activity coefficients of aqueous hydrochloric acid at 25°C up to a molality of 2.0 mol-kg–1. The data obtained by Harned and Ehlers(12,13) from galvanic cells without liquid junction were used in the analysis and the parameters obtained were compared to those obtained from all reliable data presented in the literature for HCl at this temperature. A good agreement between the parameters was always observed. The activity coefficients obtained by the new equations were compared to those suggested by Robinson and Stokes,(8) Hamer and Wu,(1) and Pitzer and Mayorga,(9) and good agreement was also found. The data from the most important literature data sets for HCl were also predicted using the new activity coefficient equations, and the magnitude of the resulting errors was close to the precision of the measurements, the errors forming an almost random pattern for all data sets. 相似文献
48.
Dimitrakakis E Haberhauer-Troyer C Abe Y Ochsenkühn-Petropoulou M Rosenberg E 《Analytical and bioanalytical chemistry》2004,379(5-6):842-848
The use of solid-phase microextraction (SPME) with gas chromatography coupled to microwave-induced plasma atomic-emission detection (GC–MIP-AED) is described for selenite [Se(IV)] speciation. Aqueous standards were derivatised with sodium tetraethyl- or tetrapropylborate and extracted by SPME. Headspace extraction of the ethyl and propyl derivatives was studied. Relevant experimental conditions were optimised, including conditions for derivatisation and extraction and those of gas chromatographic analysis. The limits of detection achieved for headspace sampling of derivatised Se(IV) were in the low ng mL–1 range for both ethylation and propylation. When the method was applied to analysis of selenite in selenised yeast reference material results were in good agreement with the indicated values. 相似文献
49.
NaAg3S2, a Thioargentate Containing the Anionic Cluster [Ag6S4]2? . Dark-red octahedrally shaped crystals of NaAg3S2 could be obtained by the reaction of NaAg(CN)2 and NaCN in a stream of hydrogen sulfide at 630 K. NaAg3S2 crystallizes cubic, a=12.358(1) Å, space group Fd3 m, Z=16. The structure was determined from four-circle diffractometer data. NaAg3S2 contains the anionic cluster [Ag6S4]2?. The structure can be traced back to the spinel structure typ. An extended Hückel calculation for the cluster anion, which is considered to be isolated, shows weak bonding silver-silver interactions. NaAg3S2 is diamagnetic at room temperature. 相似文献
50.