排序方式: 共有125条查询结果,搜索用时 265 毫秒
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Tsvi Piran 《General Relativity and Gravitation》1997,29(11):1363-1370
The concepts of negative gravitational mass and gravitational repulsion are alien to general relativity. Still, we show here that small negative fluctuations—small dimples in the primordial density field—that act as if they have an effective negative gravitational mass, play a dominant role in shaping our Universe. These initially tiny perturbations repel matter surrounding them, expand and grow to become voids in the galaxy distribution. These voids—regions with a diameter of 40 h-1 Mpc which are almost devoid of galaxies—are the largest objects in the Universe. 相似文献
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氟烷基碘(RfI)在铜存在下与芳烃,C6H5Y(Y=烷基,OCH5,CF3,F,Cl,Br,I)在乙酐中反应得到相应的氟烷基化芳烃(RfC6H4Y)混合物,转化率和产率与所用铜粉量和芳烃上的电子密度有关,带有供电子基的芳烃转化率和产率都较高;反之则低,反应可能是自由基机理,氟烷基自由基能被环己烯和异丙苯所捕获。引发苯乙烯聚合生成含氟聚合物。芳环上的定位效应似乎也支持这一机理。若用DMSO为溶剂则可能是通过氟烷基铜中间体。 相似文献
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本文对五种组成为[Fe(3-EtO-SalAPA)2]ClO4.S的Fe(III)自旋变异晶态配合物进行了磁学和谱学表征, 所有溶剂合物的变温磁化率和EPR数据证示它们的自旋态转变性质均属渐变型, 在110-300K范围内的Mossbauer谱都只显示单一的四极分裂双峰. 实验结果还表明, 在所有晶态配合物中, Fe(III)自旋态的转变速率小于EPR谱学的时间标度(~10^1^0s^-^1), 而大于Mossbauer谱学的时间标度(~10^7s^-^1). 随着溶剂分子体积由C6H5F至o-C5H4Cl2的依次增大, 相应溶剂合物的μeff-T曲线的Tc值向低温方向位移.特别在单卤代苯系列中, 溶剂的分子体积与Tc值呈线性关系, 但氯苯溶剂合物是例外:后者的反常现象主要是由晶格内部的Tc≈185K时伴随发生了与自旋变异协同的一级相变所造成, 这个相变过程已为示差扫描量热测定和Mossbauer中心位移对温度的曲线呈现的不连续性所证实. 相似文献
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将海藻酸钠(SA)与CuCl2.2H2反应得到一种配位聚合物海藻酸酮(Cu-An)。以ESR、电导率、IR和SPS方法对此配位聚合物进行表征,确定了组成与结构:同时研究了甲基丙烯酸甲酯(MMA)在该配位聚合物膜、HSO3^-和水体系催化引发作用下的聚合反应历程。结果表明,配位聚合物的中心离子Cu^2^+与两个海藻酸(An)链节单元上的两个羧羟基氧原子和两个离解氢原子的羧羟基氧原子以共价型配位,配位数为4.MMA在上述的催化引发体系中是按照自由基加聚反应历程进行聚合的,PMMA呈无规结构。Cu-An在催化引发体系中起着催化剂的配位催化作用。 相似文献
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用电子光谱法研究了一种由六个碳原子的脂肪二酰胺链连接两个四苯基卟啉的双核钴(Ⅱ)配合物(Co~2PP~4)在DMF溶液中与双氧的可逆结合作用,测定了反应的Hill系数n=1.84,△G^0(298K)=-12.3kJ·mol^-^1,P~1~/~2=6.8kPa,热力学数据表明Co~2PP~4分子内两个金属卟啉环之间存在着强的协同作用。由双卟啉双钴(Ⅱ)配合物与双氧作用形成的配合物经ESR证实为超氧金属配合物,结合方式属于Co-O~2^-超氧类型。 相似文献
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Richard T. Hammond 《General Relativity and Gravitation》1999,31(2):233-271
A theory of gravitation with torsion that isderived from an antisymmetric second rank tensor isreviewed. A non-symmetric energy momentum tensor isdeveloped and the explicit material action is presented. This is done from a phenomenological point ofview and using the Dirac Lagrangian. The equations ofmotion are derived and it is shown that the source oftorsion is the intrinsic spin of elementary particles. The torsion sector is reduced to a low energy3-vector formulation and the interaction energies arederived. The theory is reformulated in terms of theDirac field, and it is shown that precisely the same interaction energy is predicted. The theory iscompared to the low energy string theory effective fieldlimit and the scalar field is introduced. It is shownhow this field is a mandatory requirement of the theory, and a particular limit is derivedin which the scalar field acts as a strong non-minimalcoupling of the torsion field. Physical predictions arecompared to experiment, including effects in hydrogen and paramagnetic salts. Other physicalmanifestations that are discussed include spin flippingof neutrinos, torsion waves and their power, how thenon-linear Dirac and Schrodinger equations arise from torsion, and the physical origin andcorrect prediction of the magnetic dipole moment ofelementary particles. 相似文献