全文获取类型
收费全文 | 55679篇 |
免费 | 3867篇 |
国内免费 | 6763篇 |
专业分类
化学 | 44313篇 |
晶体学 | 592篇 |
力学 | 952篇 |
综合类 | 822篇 |
数学 | 8196篇 |
物理学 | 11434篇 |
出版年
2023年 | 538篇 |
2022年 | 898篇 |
2021年 | 1913篇 |
2020年 | 1350篇 |
2019年 | 1364篇 |
2018年 | 1055篇 |
2017年 | 1199篇 |
2016年 | 1508篇 |
2015年 | 1549篇 |
2014年 | 2032篇 |
2013年 | 3451篇 |
2012年 | 3362篇 |
2011年 | 2831篇 |
2010年 | 2561篇 |
2009年 | 3252篇 |
2008年 | 3501篇 |
2007年 | 3755篇 |
2006年 | 3076篇 |
2005年 | 2388篇 |
2004年 | 2178篇 |
2003年 | 1947篇 |
2002年 | 4282篇 |
2001年 | 1808篇 |
2000年 | 1360篇 |
1999年 | 1222篇 |
1998年 | 1090篇 |
1997年 | 866篇 |
1996年 | 879篇 |
1995年 | 816篇 |
1994年 | 769篇 |
1993年 | 712篇 |
1992年 | 770篇 |
1991年 | 523篇 |
1990年 | 455篇 |
1989年 | 369篇 |
1988年 | 347篇 |
1987年 | 250篇 |
1986年 | 266篇 |
1985年 | 357篇 |
1984年 | 256篇 |
1983年 | 157篇 |
1982年 | 306篇 |
1981年 | 474篇 |
1980年 | 431篇 |
1979年 | 470篇 |
1978年 | 374篇 |
1977年 | 283篇 |
1976年 | 238篇 |
1974年 | 75篇 |
1973年 | 152篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
The transferability of the first and second order electric moments of localized orbitals have been shown. Some moment characteristics have also been investigated. The standard deviation of first order localized moments is less than 2.0%. The standard deviation of second order electric moment components are larger: although they do not exceed 4.0% for bond orbitals, for lone pair ones they vary about 1.5–10.1%. 相似文献
992.
H. Thielemann 《Fresenius' Journal of Analytical Chemistry》1978,292(3):237
Ohne Zusammenfassung
Separation and identification of the HCH ointment antiskabiosum using ready-made foils for thin-layer chromatography (purity test)
Verwendet wurden Silufol Fertigfolien UV 254 (Herstellerfirma: Sklárny Kavalier, SSR). Sorptionsmittel: Silpearl — weitporiges Silicagel nach Pitra mit Leuchtstoff für UV 254, Unterlage — Aluminiumfolie, Bindemittel — Stärke 相似文献
993.
As an extension of previous reports, the barium carbonate procedure has been optimized in detail for the preparation of apolar columns. The aim was to produce optimum overall column characteristics, and to maintain them unchanged under the prolonged influence of the highest possible temperature. The main parameters under optimization were glass variety, leaching of glass surface with aqueous HCl, and amount of barium carbonate deposited, while deactivation and coating were kept constant. The basic column characteristics were adsorption properties and thermostability of deactivation, acid/base behaviour and separation efficiency. They were determined by a new, quantitative testing procedure. Intense leaching was able to eliminate almost totally the differences between glass varieties and to create a well-defined glass surface. While untreated glass, leached glass, and barium carbonate treated glass showed specific weak points in the respective column quality, the combination of leaching and barium carbonate treatment yielded the highest and most stable quality. Some technical modifications of the preparation procedure are described, including deactivation in the gas phase, and use of pentane as a solvent for static coating. 相似文献
994.
TERESA HŁADOŃ JAN Pawlaczyk BARBARA Szafran 《Journal of inclusion phenomena and macrocyclic chemistry》2000,36(1):1-8
The ibuprofen--cyclodextrin inclusion complex was prepared by theco-precipitation method. The identity of the obtained product was verified by X-ray and thermogravimetric techniques. The effect of -cyclodextrin on the stability of ibuprofen was analysed. 相似文献
995.
W. Zielenkiewicz B. Golankiewicz G. L. Perlovich M. Koźbiał 《Journal of solution chemistry》1999,28(6):731-745
Solubilities of tricyclic analogs of acyclovir have been determined in water at 25, 35, and 45°C and in octanol, water-saturated octanol, and octanol-saturated water at 25°C. Octanol-water partition coefficients were determined at 25°C. Melting temperatures and molar enthalpies of fusion were measured. Activity coefficients in water, octanol, and in aqueous octanol solutions were determined and are discussed. The effect of hydrophilic and hydrophobic substituents in the tricyclic analogs on their thermodynamic properties are discussed. The standard Gibbs energy of transfer between the saturated phases were found to correlate with known values of the melting point of the solvents and the solubilities of the solute. For a number of the compounds examined, correlations between the minimum inhibitory concentration against the herpes simplex virus type 1 (HSV-1) and type 2 (HSV-2), varicella-zoster virus (VZV), thymidine kinase-deficient (TK–) strains of VZV and
were established. Detailed conclusions have been derived concerning the relationships between the structure and the thermodynamic parameters of the compounds examined. 相似文献
996.
The electron capture detector (ECD) response to numerous aromatic hydrocarbons of low electron affinity (EA) is shown to be detrimentally affected by two processes which compete with and typically overwhelm the electron capture reactions of these molecules. It is shown that the effects of these two undesired reactions can be eliminated by the permanent addition of trimethylamine and one of several alkyl monochlorides to the detector make-up gas. These modifications of the detector gas result in greatly increased sensitivity, increased linearity, and increased reproducibility of response. A kinetic model for the ECD responses of low EA resonance capture molecules is developed which appears to explain these improvements. 相似文献
997.
Wojciech Paszkowicz 《Analytica chimica acta》2006,566(1):81-98
Genetic algorithms represent a powerful global-optimisation tool applicable in solving tasks of high complexity in science, technology, medicine, communication, etc. The usual genetic-algorithm calculation scheme is extended here by introduction of a quadratic self-learning operator, which performs a partial local search for randomly selected representatives of the population. This operator is aimed as a minor deterministic contribution to the (stochastic) genetic search. The population representing the trial solutions is split into two equal subpopulations allowed to exhibit different mutation rates (so called asymmetric mutation). The convergence is studied in detail exploiting a crystallographic-test example of indexing of powder diffraction data of orthorhombic lithium copper oxide, varying such parameters as mutation rates and the learning rate. It is shown through the averaged (over the subpopulation) fitness behaviour, how the genetic diversity in the population depends on the mutation rate of the given subpopulation. Conditions and algorithm parameter values favourable for convergence in the framework of proposed approach are discussed using the results for the mentioned example. Further data are studied with a somewhat modified algorithm using periodically varying mutation rates and a problem-specific operator. The chance of finding the global optimum and the convergence speed are observed to be strongly influenced by the effective mutation level and on the self-learning level. The optimal values of these two parameters are about 6 and 5%, respectively. The periodic changes of mutation rate are found to improve the explorative abilities of the algorithm. The results of the study confirm that the applied methodology leads to improvement of the classical genetic algorithm and, therefore, it is expected to be helpful in constructing of algorithms permitting to solve similar tasks of higher complexity. 相似文献
998.
Gejihu De Weiping Qin Jisen Zhang Yan Wang Chunyan Cao Yang Cui 《Journal of solid state chemistry》2006,179(3):955-958
In this work, we used the hydrothermal method to synthesize Eu3+ ion-doped cubic BaF2 nanorods, which is a luminescent material. The clubbed structures were well crystallized and exhibited face-centred cubic structures, as indicated by powder X-ray diffraction, scanning electron microscopy, electron diffraction, and transmission electron microscopy. The luminescent properties were studied, and local symmetry surrounding Eu3+ ions and electronic transition processes included. The results indicated that Eu3+ occupied only one C4ν site in nanorods. 相似文献
999.
1 INTRODUCTION The rational design and synthesis of new metal- organic coordination polymers have generated con- siderable interest in supramolecular chemistry and material science owing to their intriguing structural diversities and potential applications as functional materials[1~3]. Molecular self-assembly has been pro- ved to be an efficient way to construct various inte- resting coordination polymers[4~6]. The coordina- tion covalent bond, hydrogen bond or other mole- cular interact… 相似文献
1000.
Ping ZHENG Wei Lin SUN Zhi Quan SHEN 《中国化学快报》2005,16(10):1413-1416
N-2-Thiazolylacrylamide (NTA) was polymerized by a radical route to obtain the polymer in good yield. The polymer with a pendent heterocyclic group is soluble in common organic solvents, which allow to prepare the corresponding metal complexes with higher loads easily. FTIR, ^1H NMR, elemental analysis, and energy-dispersive X-Ray spectroscopy (EDX) were applied to characterize these materials. The magnetic behavior of Fe(Ⅱ) and Nd(Ⅲ) complexes of poly(N-2-thiazolylacrylamide) was examined by a PPMS-9T magnetometer, exhibiting the characteristics of a soft ferromagnet. It is found that the Nd(Ⅲ) complex has an extremely high relative saturation magnetization of 35 emu/g. 相似文献