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91.
92.
Du J Carl M Bydder M Takahashi A Chung CB Bydder GM 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2010,207(2):304-311
We describe the use of two-dimensional ultrashort echo time (2D UTE) sequences with minimum TEs of 8 μs to image and quantify cortical bone on a clinical 3T scanner. An adiabatic inversion pulse was used for long T(2) water and fat signal suppression. Adiabatic inversion prepared UTE acquisitions with varying TEs were used for T(2) measurement. Saturation recovery UTE acquisitions were used for T(1) measurement. Bone water concentration was measured with the aid of an external reference phantom. UTE techniques were evaluated on cadaveric specimens and healthy volunteers. A signal-to-noise ratio of around 30, contrast-to-noise ratio of around 27/20 between bone and muscle/fat were achieved in tibia in vivo with a nominal voxel size of 0.23 × 0.23 × 6.0 mm(3) in a scan time of 5 min. A mean T(1) of 223 ± 11 ms and mean T(2) of 390 ± 19 μs were found. Mean bone water concentrations of 23.3 ± 1.6% with UTE and 21.7 ± 1.3% with adiabatic inversion prepared UTE sequences were found in tibia in five normal volunteers. The results show that in vivo qualitative and quantitative evaluation of cortical bone is feasible with 2D UTE sequences. 相似文献
93.
Kevin M. Wright Joshua Warner Luca Venturi Robert B. Piggott Simon Donell Brian P. Hills 《Magnetic resonance imaging》2010
Image contrast is calculated by inputting experimental 2D T1–T2 relaxation spectra into the ODIN software interface. The method involves characterising a magnetic resonance imaging pulse sequence with a “relaxation signature” which describes the sensitivity of the sequence to relaxation and is independent of sample parameters. Maximising (or minimising) the overlap between the experimental 2D T1–T2 relaxation spectra and the relaxation signature can then be used to maximise image contrast. The concept is illustrated using relaxation signatures for the echo planar imaging and Turbo spin-echo imaging sequences, together with in-vitro 2D T1–T2 spectra for liver and cartilage. 相似文献
94.
Yan Sen Lin 《Optics Communications》2010,283(17):3305-3309
A method to enhance the relaxation oscillation frequency and carrier bandwidth of a delayed feedback semiconductor laser transmitter is presented using additive optical feedback light. A formula for frequency detuning of the optical dual-feedback is developed to demonstrate that frequency detuning is added with the additive optical feedback light level. The function of the relaxation oscillation frequency of the chaotic laser is theoretically determined to show that it can be broadened by including the delay time and feedback level. Numerical results demonstrate that the bandwidth with the additive optical feedback light can be enhanced 1.7 times more than the bandwidth without it and the relaxation oscillation frequency of the chaotic laser is increased to 1.8 times more than that of the laser without it. The current can enhance the relaxation oscillation frequency and bandwidth of the transmitter more efficiently. 相似文献
95.
The phonon induced mechanisms of relaxation/decoherence in quantum dots are analysed. A non-perturbative technique - a modification of the Davydov transformation appropriate to the localised particles is applied for solving the electron-phonon eigenvalue problem in a quantum dot at magnetic field presence. The decay rates for polaron relaxation via the anharmonicity induced channel are analysed in details. In particular, it is indicated that previous, of perturbative type, estimations of the anharminicity induced relaxation rates were too severe and after including the coherence effects they are of, at least, one order longer. The process of exciton dressing with phonons is also analysed as the unavoidable source of picosecond scale decoherence in optically driven nanostructures. A break-down of an instant Pauli spin blocking mechanism and a large enhancement of the Fröhlich constant for confined electrons are also addressed. 相似文献
96.
《Journal of computational and graphical statistics》2013,22(2):283-309
A simple and yet powerful method is presented to estimate nonlinearly and nonparametrically the components of additive models using wavelets. The estimator enjoys the good statistical and computational properties of the Waveshrink scatterplot smoother and it can be efficiently computed using the block coordinate relaxation optimization technique. A rule for the automatic selection of the smoothing parameters, suitable for data mining of large datasets, is derived. The wavelet-based method is then extended to estimate generalized additive models. A primal-dual log-barrier interior point algorithm is proposed to solve the corresponding convex programming problem. Based on an asymptotic analysis, a rule for selecting the smoothing parameters is derived, enabling the estimator to be fully automated in practice. We illustrate the finite sample property with a Gaussian and a Poisson simulation. 相似文献
97.
W. Medycki 《Phase Transitions》2013,86(9-10):867-872
Spin-lattice relaxation time T 1 is determined for protons in three polycrystals (CH3NH3)5Bi2Cl11, (CD3NH3)5Bi2Cl11 and (CH3ND3)5Bi2Cl11. The temperature dependence of the relaxation times obtained for (CH3NH3)5Bi2Cl11 and (CD3NH3)5Bi2Cl11 are interpreted as a result of correlated motions of the three-proton groups of the monomethylammonium cation. 2H NMR lines of (CD3NH3)3Sb2Br9 have been recorded between 5 K and 291 K using solid echo method. The 2H NMR line shape analysis shows that characteristic shape of tunnelling methyl group appears at about 25 K and coming down with temperature up to 5 K is more distinct. From theoretical calculation, it has been found that in the quadrupolar constants is 161.3 kHz and tunnelling frequency is above 3 MHz. 相似文献
98.
Heavy oil (bitumen) is characterized by its high viscosity and density, which is a major obstacle to both well logging and recovery. Due to the lost information of T2 relaxation time shorter than echo spacing (TE) and interference of water signal, estimation of heavy oil properties from NMR T2 measurements is usually problematic. In this work, a new method has been developed to overcome the echo spacing restriction of NMR spectrometer during the application to heavy oil (bitumen). A FID measurement supplemented the start of CPMG. Constrained by its initial magnetization (M0) estimated from the FID and assuming log normal distribution for bitumen, the corrected T2 relaxation time of bitumen sample can be obtained from the interpretation of CPMG data. This new method successfully overcomes the TE restriction of the NMR spectrometer and is nearly independent on the TE applied in the measurement. This method was applied to the measurement at elevated temperatures (8-90 degrees C). Due to the significant signal-loss within the dead time of FID, the directly extrapolated M0 of bitumen at relatively lower temperatures (<60 degrees C) was found to be underestimated. However, resulting from the remarkably lowered viscosity, the extrapolated M0 of bitumen at over 60 degrees C can be reasonably assumed to be the real value. In this manner, based on the extrapolation at higher temperatures (> or = 60 degrees C), the M0 value of bitumen at lower temperatures (<60 degrees C) can be corrected by Curie's Law. Consequently, some important petrophysical properties of bitumen, such as hydrogen index (HI), fluid content and viscosity were evaluated by using corrected T2. 相似文献
99.
Determining NMR flow propagator moments in porous rocks without the influence of relaxation 总被引:1,自引:1,他引:0
Mitchell J Graf von der Schulenburg DA Holland DJ Fordham EJ Johns ML Gladden LF 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2008,193(2):218-225
Flow propagators, used for the study of advective motion of brine solution in porous carbonate and sandstone rocks, have been obtained without the influence of Nuclear Magnetic Resonance (NMR) relaxation times, T1 and T2. These spin relaxation mechanisms normally result in a loss of signal that varies depending on the displacement ζ of the flowing spins, thereby preventing the acquisition of quantitative propagator data. The full relaxation behaviour of the system under flow needs to be characterised to enable the implementation of a true quantitative measurement. Two-dimensional NMR correlations of ζ − T2 and T1 − T2 are used in combination to provide the flow propagators without relaxation weighting. T1 − ζ correlations cannot be used due to the loss of T1 information during the displacement observation time Δ. Here the moments of the propagators are extracted by statistical analysis of the full propagator shape. The measured displacements (first moments) are seen to correlate with the expected mean displacements for long observation times Δ. The higher order moments of the propagators determined by this method indicate those obtained previously using a correction were overestimated. 相似文献
100.
The L2,3-M2,3V resonant Auger electron spectroscopy (RAES) spectrum of Ti metal measured by Le Fêvre et al. [P. Le Fêvre, J. Danger, H. Magnan, D. Chandesris, J. Jupille, S. Bourgeois, M.-A. Arrio, R. Gotter, A. Verdini, A. Morgante, Phys. Rev. B69 (2004) 155421] is analyzed in the light of relaxation and decay of the resonantly excited L2,3-hole states. The relaxation time of the resonantly excited L2,3-hole state to the fully relaxed (screened) one is much shorter than the L2,3-hole Auger decay time, whereas the participant Coster–Kronig (CK) decay time of the resonantly excited L2-hole state to the fully relaxed L3-hole state at the L2 resonance is as short as the relaxation time of the resonantly excited L2-hole state to the fully relaxed one. The excited electron is predominantly either rapidly decoupled from the L2,3-hole decay or annihilated by the participant CK decay. Thus, near the L2,3 edges the L2,3-M2,3V RAES spectral peak appears at constant kinetic energy. The L2,3-M2,3V RAES spectrum shows a normal L2,3-M2,3V Auger decay profile not modulated by the density of empty d states probed by the resonant excitation. Not only the relaxation time but also the participant CK decay time depends on photon energy because they depend on the density of empty d states probed by the resonant excitation. As a result, the L2,3 X-ray absorption spectroscopy spectral line broadening depends on photon energy. 相似文献