全文获取类型
收费全文 | 894篇 |
免费 | 24篇 |
国内免费 | 29篇 |
专业分类
化学 | 734篇 |
力学 | 10篇 |
综合类 | 4篇 |
数学 | 40篇 |
物理学 | 159篇 |
出版年
2023年 | 13篇 |
2022年 | 31篇 |
2021年 | 51篇 |
2020年 | 17篇 |
2019年 | 30篇 |
2018年 | 32篇 |
2017年 | 34篇 |
2016年 | 36篇 |
2015年 | 34篇 |
2014年 | 25篇 |
2013年 | 47篇 |
2012年 | 39篇 |
2011年 | 39篇 |
2010年 | 29篇 |
2009年 | 54篇 |
2008年 | 50篇 |
2007年 | 48篇 |
2006年 | 35篇 |
2005年 | 34篇 |
2004年 | 47篇 |
2003年 | 27篇 |
2002年 | 22篇 |
2001年 | 16篇 |
2000年 | 19篇 |
1999年 | 21篇 |
1998年 | 18篇 |
1997年 | 21篇 |
1996年 | 9篇 |
1995年 | 12篇 |
1994年 | 7篇 |
1993年 | 7篇 |
1992年 | 5篇 |
1991年 | 8篇 |
1990年 | 4篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1987年 | 4篇 |
1986年 | 5篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1982年 | 4篇 |
1981年 | 1篇 |
1979年 | 2篇 |
1966年 | 1篇 |
排序方式: 共有947条查询结果,搜索用时 109 毫秒
11.
12.
13.
Anders Thygesen Jette Oddershede Hans Lilholt Anne Belinda Thomsen Kenny Ståhl 《Cellulose (London, England)》2005,12(6):563-576
A comparative study of cellulose crystallinity based on the sample crystallinity and the cellulose content in plant fibres
was performed for samples of different origin. Strong acid hydrolysis was found superior to agricultural fibre analysis and
comprehensive plant fibre analysis for a consistent determination of the cellulose content. Crystallinity determinations were
based on X-ray powder diffraction methods using side-loaded samples in reflection (Bragg-Brentano) mode. Rietveld refinements
based on the recently published crystal structure of cellulose Iβ followed by integration of the crystalline and amorphous
(background) parts were performed. This was shown to be straightforward to use and in many ways advantageous to traditional
crystallinity determinations using the Segal or the Ruland–Vonk methods. The determined cellulose crystallinities were 90–100 g/100 g
cellulose in plant-based fibres and 60–70 g/100 g cellulose in wood based fibres. These findings are significant in relation
to strong fibre composites and bio-ethanol production. 相似文献
14.
Y. Kamino 《Radiation Physics and Chemistry》1998,52(1-6):469-473
A 10MeV 25KW plus class electron LINAC was developed for sterilisation of medical devices. The LINAC composed of a standing wave type single cavity prebuncher and a 2m electro-plated travelling wave guide uses a 5MW 2856MHz pulse klystron as an RF source and provides 25KW beam power at the Ti alloy beam window stably after the energy analysing magnet with 10MeV plus-minus 1 MeV energy slit. The practical maximum beam power reached 29 KW and this demonstrated the LINAC as one of the most powerful S-band electron LINACs in the world. The control of the LINAC is fully automated and the “One-Button Operation” is realised, which is valuable for easy operation as a plant system. 2 systems have been delivered and are being operated stably. 相似文献
15.
A new extraction method for ginsenosides from ginseng roots, ginseng leaves and ginseng drug preparations by Sep-Pak C18 cartridges has been studied. Ginsenoside extraction by Sep-Pak cartridges is a rapid, efficient, reproducible method. In addition, the extracts were analyzed by high performance thin layer chromatography (HPTLC) and reverse phase high performance liquid chromatography (HPLC). The major components of ginseng saponins were effectively separated using an ODS-120T column. 相似文献
16.
植物育种途径改善人类的铁,锌营养 总被引:7,自引:1,他引:7
概括了铁、锌与人体健康的关系,铁、锌的食物来源及生物有效性,并简要地论述了通过植物育种改善人类铁、锌营养的农业效应、经济效益以及有关这方面的研究进展。 相似文献
17.
An X-ray fluorescence (XRF) method for the rapid and non-destructive analysis of 30 non-organic elements in plant leaves over five orders of magnitude concentration from several percentage of dry weight to sub-milligram per kilogram, is described. There is a growing need for a simple method of monitoring non-organic trace elements in plant material, especially those which accumulate in soils with application of fertilisers, both inorganic and biosolids. Earlier attempts to use XRF for the analysis of plant material suffered from sensitivity loss due to the high background of organic matrices caused by scattering of the X-ray source. We overcome this by using polarised X-ray sources in a Cartesian geometrical arrangement with sample and energy dispersive detector (EDPXRF), a configuration which can achieve an order of magnitude reduction in background compared with unpolarised sources. Further sensitivity gains are made using a high power tube as a source of primary X-rays and for some analytes employing secondary targets for near-monochromatic excitation. Sample preparation is simple involving only pulverising and briquetting of dried samples. Accuracy is evaluated by comparing data obtained for the suite of NIST plant leaf samples (NIST 1515 apple leaves, NIST 1547 peach leaves, NIST 1570a spinach leaves, NIST 1573a tomato leaves and NIST 1575a pine needles) and tobacco leaf standards CTA-OTL-1 and CTA-VTL-2. The data compare well over the whole concentration range and the method provides a rapid analytical tool for monitoring potentially toxic trace elements in all types of foliage with adequate sensitivity for many purposes. 相似文献
18.
19.
The use of hydride generation coupled with axial view inductively couple plasma atomic emission spectrometry was presented for the determination of selenium in plant samples. The chemical factors affecting potentially the hydride generation efficiency (hydrochloric acid, sodium borohydride and sodium hydroxide concentrations) were assessed through investigation of chemical interference, accuracy and repeatability. The accuracy of measurements was not affected by elements present in high concentration in the plant matrix (K, Ca, Mg, and P). No interference was also observed with transition metals. Using a real sample (maize) with standard additions, decreases of recoveries were sometimes observed for 0.1% (m/v) NaOH, and attained 13.8% in the most unfavourable case. The final accuracy of the method was verified by using two certified reference materials: CRM 402 (white clover) and CRM 279 (sea lettuce). No statistically significant differences were obtained between the measured concentrations and the certified values. The optimized method was found sensitive (detection limit 0.15 μg l−1), reliable and repeatable (R.S.D. between 1.3% and 4.0%). 相似文献
20.
Four myrosinase (β-thioglucosidase EC. 3.2.3.1) and seven disaccharase (β-fructofuranosidase, EC. 3.2.1.26) isoenzymes were isolated from turnip leaves. The most active enzymes were isolated in pure
form. Myrosinase and disaccharase mol wt was 62.0 × 103 and 69.5 × 103 dalton, respectively, on the basis of gel filtration on Sephadex G-200.
Myrosinase pH profile showed high activity between pH 5 and 7 with the optimum at pH 5.5. The purified enzyme was heat-stable
for 60 min at 30°C with only loss of 24% of activity. Its activity is strongly inhibited (100%) by Pb2+, Ba2+, Cu2+ and Ca2+ ions, and activated (70%) by EDTA at 0.04M. The pure enzyme failed to hydrolyze amylose, glycogen, lactose, maltose, and
sucrose. TheK
m andV
max values of myrosinase using sinigrin as specific substrate was 0.045 mM and 2.5 U, respectively.
The maximal activity of disaccharase enzyme was obtained at pH 4–5 and 35–37°C. The enzyme was heat-stable at 30°C for 30
min with only 10% loss of its activity. Its activity is strongly activated (70–240%) by Ca2+, Ba2+, Cu2+, and EDTA at 0.01M. The enzyme activity is specific to the disaccharide sucrose and failed to hydrolyze other disaccharides (maltose and lactose).
TheK
m andV
max of disaccharase were 0.123 mM and 3.33 U, respectively. 相似文献