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561.
综述了近年来各种核壳材料的合成方法,包括聚合法layer-hy-layer(LbL)自组装技术、原位反应法等。并简要介绍了空心材料的制备及核壳材料的应用。 相似文献
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Polyelectrolyte porous membranes (PPMs) belong to the most interesting classes of materials, because the synergy of tunable pore sizes and charge nature of polyelectrolyte endow them with wide-ranging practical applications. However, owing to the water solubility and ionic nature of the polyelectrolytes, traditional polyelectrolytes are difficult to use in scalable preparation of high-quality PPMs through the well-developed industrial methods. Poly(ionic liquid)s (PIL) are a subclass of functional polyelectrolytes bearing ionic liquid groups in their repeating unites, inheriting the advantages of ionic liquids (ILs) and macromolecular architecture features. In recent years, along with rapid development of PIL materials chemistry, considerable and significant developments involving the novel preparation methods, and structure-property-function relationships of PPMs have been made. In this review, we highlight the latest discovery and proceedings of PPMs, particularly the advancements in how to tailor structures and properties of PPMs by rational structure design of PILs. The formation mechanisms of various PPMs were also discussed in detail from the viewpoint of PILs molecular structures. A future perspective of the challenges and promising potential of PPMs is cast on the basis of these achievements. We expect that these analyses and deductions will be useful for the design of useful PPMs and serve as a source of inspiration for the design of future multifunctional PPMs. 相似文献
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《Arabian Journal of Chemistry》2023,16(4):104603
In this work, an acylhydrazone derivative (QN62) was developed via the one-step condensation of 6-hydroxy-2-naphthoic hydrazide with quinoline-8-carboxaldehyde. The structure of the QN62 compound was characterized by 1H NMR, 13C NMR, HR-MS (ESI), and X-ray crystallography. As a dual-functional turn-on fluorescence chemosensor, QN62 exhibited rapid recognition for Zn2+ in DMSO-H2O (4:1, v/v) and Mg2+ in ethanol-H2O (9:1, v/v). The enhancement in fluorescence detection was associated with the coordination reaction between QN62 and the target ions, which promoted intramolecular charge transfer and prevented the CN isomerization process. Simultaneously, a rapid color change from colorless to yellowish-green or yellow under UV light (365 nm) was easily visible to the naked eye. Under optimal conditions, the limit of detection and limit of quantification were 32.3 nM and 97.8 nM for Zn2+ and 16.1 nM and 48.9 nM for Mg2+, respectively. The recognition mechanism was reasonably speculated based on analysis of the Job’s plot, HR-MS, 1H NMR, and density functional theoretical calculations. Utilizing silica-gel plates fabricated from the QN62 chemosensor, the visual and rapid identification of Zn2+ and Mg2+ was successfully achieved, which could provide a convenient approach for on-site detection in environmental fields. The QN62 chemosensor could also quantify trace amounts of Zn2+ and Mg2+ in water samples. Furthermore, the cell imaging experiments indicated that QN62 could effectively sense intracellular Zn2+ and Mg2+, providing potential applications in biological systems. 相似文献