全文获取类型
收费全文 | 20574篇 |
免费 | 3273篇 |
国内免费 | 1858篇 |
专业分类
化学 | 14318篇 |
晶体学 | 525篇 |
力学 | 850篇 |
综合类 | 171篇 |
数学 | 688篇 |
物理学 | 9153篇 |
出版年
2024年 | 16篇 |
2023年 | 135篇 |
2022年 | 284篇 |
2021年 | 414篇 |
2020年 | 574篇 |
2019年 | 577篇 |
2018年 | 579篇 |
2017年 | 710篇 |
2016年 | 920篇 |
2015年 | 859篇 |
2014年 | 903篇 |
2013年 | 2198篇 |
2012年 | 1230篇 |
2011年 | 1244篇 |
2010年 | 1051篇 |
2009年 | 1126篇 |
2008年 | 1184篇 |
2007年 | 1190篇 |
2006年 | 1152篇 |
2005年 | 1018篇 |
2004年 | 1017篇 |
2003年 | 891篇 |
2002年 | 981篇 |
2001年 | 678篇 |
2000年 | 686篇 |
1999年 | 575篇 |
1998年 | 489篇 |
1997年 | 399篇 |
1996年 | 323篇 |
1995年 | 381篇 |
1994年 | 286篇 |
1993年 | 247篇 |
1992年 | 229篇 |
1991年 | 167篇 |
1990年 | 147篇 |
1989年 | 111篇 |
1988年 | 119篇 |
1987年 | 103篇 |
1986年 | 99篇 |
1985年 | 82篇 |
1984年 | 80篇 |
1983年 | 36篇 |
1982年 | 56篇 |
1981年 | 30篇 |
1980年 | 31篇 |
1979年 | 37篇 |
1978年 | 12篇 |
1977年 | 7篇 |
1976年 | 7篇 |
1973年 | 16篇 |
排序方式: 共有10000条查询结果,搜索用时 416 毫秒
991.
The one-pot condensation of N-methylhomoveratrylamine with acrolein followed by in situ reductive amination with 3,4-dimethoxyaniline to give an unsymmetrical propane 1,3-diamine in excellent yield is described. 相似文献
992.
Structurally varied vicinal dibromides have been synthesized in high yield and good purity through highly stereoselective anti‐addition of bromine across the olefinic linkages using dioxane dibromide (DD) under solvent‐free conditions. 相似文献
993.
Novel cinchonine ammonium salt derivatives have been prepared by 1,3‐dipolar cycloaddition. Their chiral catalytic efficacy was investigated in the asymmetric alkylation of N‐diphenylmethyleneglycine t‐butyl ester in the water phase. As the special structure of the catalyst, its asymmetric alkylation catalytic behavior both in organic solvents and in water is satisfactory, which is environmentally friendly. 相似文献
994.
A semiempirical method has been used to study the electronic structures of some π-bonded purely organic materials that are either known or proposed to have multiplet ground states. These materials are the precursors of organic ferromagnets. Narrow energy bands formed from the radical π-orbitals of these materials are necessary for the π-electrons to be unpaired. Favorable topological arrangements of atoms in these materials are needed to enable the spins of these electrons to align parallel, and hence yield macroscopic ferromagnetic ordering. Following ideas based on these studies, a new model for a possible organic ferromagnet is proposed and studied. 相似文献
995.
The availability of state of art GPGPU cards can play a promising role in accelerating the calculations of computer generated holograms (CGH) where one of the main problems of generating such holograms is the need for massive amount of calculations. Both CUDA and Matlab can be used alone to fulfill this purpose but using both at the same time gives a number of benefits. This paper is dedicated to present a performance study of applying Fermi-Architecture CUDA-enabled GPGPU card for speeding up the calculations of binary detour phase holograms using both Matlab and CUDA programming. 相似文献
996.
Recently, many studies have been started in search for materials which show a photoinduced phase transition (PIPT). In this work, we review two systems as typical examples of PIPT accompanied with changes in magnetic characteristics; (1) organo-metal complex [Fe(2-pic)3]Cl2 EtOH (2-pic = 2-amino-methyl-pyridine) and (2) III-V based magnetic semiconductors (In1-x , Mn x )As. In the former case, we show several nonlinear characteristics in dynamical process of photoinduced spin state transition from low-spin to high-spin states. In the latter one, photocarrier-induced ferromagnetic order has been observed by both magnetic and transport measurements. 相似文献
997.
Sander Van Smaalen 《Phase Transitions》2013,86(1-4):169-174
The application of superspace groups to short-period superstructures is considered. For niobium tri-sulfide this is worked out in detail. It is shown that in that case the superspace group provides more symmetry then given by the space group of the supercell. Its consequences for the structure, the diffraction pattern and tensor-properties are discussed. 相似文献
998.
999.
Rujie Wang Xiaoming Yan Xuemei Wu Gaohong He Lin Du Zhengwen Hu Ming Tan 《Journal of Polymer Science.Polymer Physics》2014,52(16):1107-1117
Modification of proton conductive channels (PCCs) in Nafion has been achieved with the assistance of 3, 4‐dimethylbenzaldehyde (DMBA). During annealing, ionic clusters develop from small isolated spheres (1.72 nm) to wide continuous channels (5.15 nm), and the crystallinity of Nafion/DMBA membranes is also improved from 17% to 32% as shown by X‐ray diffraction. Molecular dynamic simulation reveals that hydrogen bonding and hydrophobic interaction between DMBA and Nafion work synergistically to achieve better phase separation. The morphology–property relationship shows that, versus various PCCs width, the corresponding proton conductivities vary greatly from 0.079 to 0.139 S/cm at 80 °C. By carefully tuning the width of PCCs, the proton conductivity shows an improvement of 22–34% as compared with pristine Nafion. A significant enhancement on the maximum power density is achieved for the membrane electrode assembly on Nafion/DMBA‐8h (as high as 1018 mW/cm?2), yielding an enhancement of 39% on pristine Nafion‐8h (730 mW/cm?2). © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2014 52, 1107–1117 相似文献
1000.
在纤维素三(3,5-二甲基苯基氨基甲酸酯)(Chiralcel OD-H)和Pirkle型(R, R)-Whelk-O1手性柱上对手性氨基酚1-(α-氨基苄基)-2-萘酚(Betti 碱)及其衍生物1-(α-苄氨基苄基)-2-萘酚和1-(α-哌啶基苄基)-2-萘酚对映体分离进行了研究,分别考察了在正己烷流动相中,碱性添加剂、醇类添加剂的种类和浓度对手性拆分的影响。结果表明:溶质在Chiralcel OD-H柱上的分离效果好,而在(R, R)-Whelk-O1手性柱上只有1-(α-苄氨基苄基)-2-萘酚部分分离。研究了空间立体结构因素对手性分离的影响,初步探讨和比较了溶质在这2种手性柱上的手性识别机理。发现对(R, R)-Whelk-O1柱,溶质与固定相之间的吸引作用很小,而对于Chiralcel OD-H柱,溶质在手性空腔中的空间适应性很可能是手性识别的关键。 相似文献