全文获取类型
收费全文 | 7112篇 |
免费 | 269篇 |
国内免费 | 439篇 |
专业分类
化学 | 3186篇 |
晶体学 | 51篇 |
力学 | 151篇 |
综合类 | 6篇 |
数学 | 133篇 |
物理学 | 4293篇 |
出版年
2024年 | 4篇 |
2023年 | 72篇 |
2022年 | 78篇 |
2021年 | 88篇 |
2020年 | 150篇 |
2019年 | 128篇 |
2018年 | 152篇 |
2017年 | 121篇 |
2016年 | 239篇 |
2015年 | 206篇 |
2014年 | 259篇 |
2013年 | 384篇 |
2012年 | 811篇 |
2011年 | 781篇 |
2010年 | 568篇 |
2009年 | 632篇 |
2008年 | 489篇 |
2007年 | 581篇 |
2006年 | 327篇 |
2005年 | 247篇 |
2004年 | 228篇 |
2003年 | 173篇 |
2002年 | 210篇 |
2001年 | 113篇 |
2000年 | 120篇 |
1999年 | 117篇 |
1998年 | 120篇 |
1997年 | 49篇 |
1996年 | 44篇 |
1995年 | 44篇 |
1994年 | 27篇 |
1993年 | 36篇 |
1992年 | 19篇 |
1991年 | 18篇 |
1990年 | 32篇 |
1989年 | 19篇 |
1988年 | 18篇 |
1987年 | 12篇 |
1986年 | 15篇 |
1985年 | 14篇 |
1984年 | 9篇 |
1982年 | 12篇 |
1981年 | 10篇 |
1980年 | 7篇 |
1979年 | 12篇 |
1978年 | 3篇 |
1976年 | 4篇 |
1975年 | 3篇 |
1974年 | 4篇 |
1973年 | 5篇 |
排序方式: 共有7820条查询结果,搜索用时 15 毫秒
111.
Fernando Ribas Prado Claude Giessner-Prettre Alberte Pullman James F. Hinton Dennis Harpool Ken R. Metz 《Theoretical chemistry accounts》1981,59(1):55-69
The magnetic shielding constants of the different atoms of formamide, hydrated formamide and N-methylformamide are calculated by anab initio method. For the protons of formamide the measured differences between their chemical shifts are correctly reproduced by theory, provided that the molecular geometry used as input is carefully chosen. The differences between the values of the magnetic shielding constants calculated for formamide and hydrated formamide show that intermolecular hydrogen bonding produces variations of chemical shifts for all the atoms of the molecule except the formyl proton. The calculated chemical shift variations between formamide and N-methylformamide are compared to the experimental values and discussed in relation with different hydrogen bonding possibilities of the two molecules. The calculation of the contact term of the spin-spin coupling constants of formamide and hydrated formamide shows that in most cases the measured trends are satisfactorily reproduced and that the variations of these terms upon hydration are less than 3%. 相似文献
112.
Jacques Curély 《Monatshefte für Chemie / Chemical Monthly》2005,136(6):987-1011
Summary. The problem of direct exchange is examined in the simplest cases (formal coupling of two electrons initially isolated and hydrogen molecule). Then we consider the general case of a solid characterized by weak overlaps between the atomic orbitals of first-nearest neighbours so that the involved electrons are quasi-localized. We recall the physical origin of spin-orbit coupling. Its influence on direct exchange allows one to revisit Hunds rules and to express phenomenological Hamiltonians describing anisotropic couplings as well as the antisymmetrical Dzialoshinski-Moriya coupling. 相似文献
113.
原位沉析法制备磁性氧化铁羟基磷灰石/壳聚糖棒材 总被引:3,自引:0,他引:3
首先通过化学沉淀法制备磁性氧化铁羟基磷灰石(Fe3O4/HA),然后以壳聚糖(CS)为基体,利用原位沉析法将Fe3O4/HA与CS复合,制得磁性Fe3O4/HA/CS复合材料.经XRD、粒径分布和PPMS测试,结果表明了Fe3O4/HA复合物的生成.系统研究了磁性Fe3O4/HA/CS棒材力学性能的影响因素,最终确定Fe3O4与HA质量比为3∶17,磁性Fe3O4/HA与CS质量比为9∶91时,棒材的力学性能最优,弯曲强度可达到87.0 MPa,弯曲模量1.57 GPa. 相似文献
114.
The interaction between precipitated silica and chloroprene rubber (CR) was investigated using a nuclear magnetic resonance (NMR) technique. The results reveal that the silanol groups on silica surface could chemically react with CR. Crosslinking of CR is therefore possible in the presence of silica at high temperature. The effects of silica and ethylene thiourea (ETU) loadings on properties of the silica-filled CR were thereafter investigated. With increasing silica loading, the compound viscosity increases considerably due to the dilution effect. As silica could act as a curative for CR, increasing silica loading results in both faster cure rate and increased crosslink density. The optimum tensile strength is found at approximately 30 phr of silica loading. The results also show that silica loading has little effect on most aging properties, except the relative modulus in which it increases rapidly with increasing silica loading due to the post curing effect. Similar to the effect of silica loading, the compound viscosity, cure rate and crosslink density are all increased with increasing ETU loading. The tensile strength is, on the other hand, slightly affected by ETU loading. Exception is found at high loading where the tensile strength drops noticeably. Interestingly, aging resistance of the vulcanizate is found to improve with the addition of ETU. Explanation is given by the hindrance capability of ETU to post curing. 相似文献
115.
Vukadin M. Leovac Vladimir Divjaković Ana F. Petrović Nikolai V. Gerbeleu 《Monatshefte für Chemie / Chemical Monthly》1989,120(3):181-186
Summary The reaction of warmDMF solutions of Cu(II) perchlorate, 5-nitrosalicylaldehyde S-methylisothiosemicarbazone (H2
L) and piperidine (Pip) yielded the paramagnetic (eff=2.19 B.M.) Cu(L)Pip complex, whereL is the dianionic form of H2
L, formed as a result of deprotonation of the phenolic hydroxyl and NH2 group. Crystal data of the complex are: monoclinic P21,a=11.902(4),b=6.765(3),c=11.343(4)Å; =112.92°,V=841.20(8)Å3,M=400.9,Z=2,d
0=1.60 gcm–3,d
c
=1.58 gcm–3,F(000)=424. The structure was refined to a residualR=0.047. The copper(II) ion is coordinated in a square-planar arrangement by the piperidine nitrogen and the NNO set of donor atoms ofL.
Komplexe der Übergangsmetalle mit Thiosemicarbazid-Liganden, IV. Synthese und molekulare Struktur von 5-Nitrosalicylaldehyd-S-methylisothiosemicarbazonato-piperidin-kupfer(II)
Zusammenfassung Durch die Reaktion in warmenDMF-Lösungen von Cu(II) Perchlorat, 5-Nitrosalicylaldehyd-S-methylisothiosemicarbazon (H2 L) und Piperidin (Pip) wurde ein paramagnetischer Komplex (eff=2.19 B.M.) Cu(L)Pip erhalten, wobeiL nach doppelter Deprotonierung (NH2- und Phenolhydroxyl-Gruppe) als dianionische Form von H2 L vorliegt. Die kristallographischen Daten des Komplexes sind: monokline Raumgruppe P21,a=11.902(4),b=6.765(3),c=11.343(4)Å, =112.92°;V=841.20Å3,M=400.9,Z=2,d 0=1.60 gcm–3,d c =1.58 gcm–3,F(000)=424. Die struktur wurde bis zu einemR-Wert von 0.047 verfeinert. Die Koordination des Kupfers wird quadratisch-planar über den Piperidin-Stickstoff und die NNO-Donorhülle der Chelatliganden gebildet.相似文献
116.
U(Ⅳ)配合物UNa2(pdc)3·6H2O的合成、结构及磁性研究 总被引:1,自引:4,他引:1
合成了一种含有+4价铀的配合物UNa2(pdc)3·6H2O(H2pdc=吡啶-2,6-二羧酸), 并详细研究了其晶体结构和磁学性质. 晶体属于单斜晶系, P21/n空间群, 晶胞参数a=1.0205(2) nm, b=2.2221(4) nm, c=1.2537(3) nm, β=94.98(3)°, V=2.8323(10) nm3, Z=4. 化合物的中心铀原子为九配位, π-π相互作用和氢键使得该化合物形成了三维立体结构. 相似文献
117.
The novel applications of molybdenum disulfide in recent research were reviewed, such as in lubricant, catalyst and photoelectrochemical solar cells. Recently, we found that LiMoS2 is a good candidate for new anode materials for lithium ion batteries with high lithium storage capacity.Here, the anode material LiMoS2 was synthesized by a hydrothermal method at 150℃ and the electrochemical characterization as an anode material for lithium ion batteries was examined.put in Teflon-lined stainless steel autoclaves of capacity 40 mL. Distilled water was used to fill the autoclaves to 70 % of the total volume. The autoclaves were maintained at 150℃ for 24 h and then cooled naturally. The resulting dark-gray powders were filled and washed with distilled water,diluted hydrochloric acid and ethanol, successively. The final products were dried at 80℃ for 24 h.The powder X-ray diffraction pattern showed the prepared LiMoS2 was amorphous structure. A test cell using LiMoS2 as the active material was discharged and charged between 3 and 0.01 V with respect to Li metal at a constant current density of C/5 (that is, one lithium per formula unit in 5 hours). During the first discharge, the potential rapidly drops to reach a large plateau at 2.2 V, then slowly drops to the other plateau at 0.8 V, and then continuously decreases down to 0.01V. There is only a plateau at 1.35 V in the subsequent discharge curves. The plateaus of charge potential appear at about 1.9 V.The irreversible loss was 41% in the first cycle. The ratio of discharge and charge is more than 99%in the subsequent cycles. Moreover, the ratio of discharge and charge almost reaches 100% after thedemonstrated that LiMoS2 has a very high capacity and a good cycle-ability as an anode material forlithium ion batteries. 相似文献
118.
丁苯、丁腈基聚氨酯的形态与性能 总被引:2,自引:0,他引:2
用示差扫描量热法 (DSC)、红外分光光度计 (FTIR)和原子力显微镜 (AFM)研究了端羟基聚丁二烯 苯乙烯共聚物 (HTBS)、端羟基聚丁二烯 丙烯腈共聚物 (HTBN)和端羟基聚丁二烯 (HTPB)与甲苯二异氰酸酯、1 ,4 丁二醇构成的溶液法聚二烯烃基聚氨酯 (PU)的形态结构 .结果表明HTPB和HTBS基PU的相分离程度很大 ,而HTBN基PU的相分离程度小 .这可能归因于HTBS软段的极性低 ,不能与硬段形成氢键 ,而HTBN软段中的腈基具有很强的极性 ,且可以与硬段形成氢键作用 ,增加了软硬段间的相容性 ,相分离程度明显降低 .AFM表明HTBN PU随着硬段含量提高 ,表面粗糙度增大 ,由软段为连续相逐渐过渡到双连续结构 .在硬段含量 6 3%时 ,HTBN和HTPB基PU均呈双连续结构 ,而HTBS PU中硬段为连续相 .HTBN PU软段的相区尺寸在1 2nm左右 ,表面粗糙度较大 ,HPBS PU软段的相区尺寸在 1 1nm左右 ,表面粗糙度最小 ,HTPB PU存在 1 4nm和 5 0nm大小不等的软段相区尺寸 .力学性能表明 ,在软段中引入苯乙烯和丙烯腈结构 ,可使聚氨酯抗张强度分别提高 1 5和 2倍 ,模量和断裂伸长率也明显提高 相似文献
119.
The electrical and magnetic properties of the tetragonal phase SmCuOSe are reported as a function of the temperature. The optical properties were studied by means of diffuse reflectance spectrum in the UV-Vis range. The electrical resistivity measurements as well as diffuse reflectance spectrum show that SmCuOSe is a semiconductor with an optical band gap (Eg) of 2.6 eV. In this phase, Cu is at its monovalent oxidation state and, as such, it does not contribute to the total magnetic moment, whereas Sm is in its 3+ oxidation state, with a large VanVleck contribution due to the admixture of the fundamental state with higher energy levels. 相似文献
120.
The synthesis of magnetic vesicles is described. The vesicles are constituted by didodecyldimethylammonium bromide and have a diameter of about 1 m. An aqueous magnetic fluid, constituted by charged magnetic nanoparticles dispersed in water without surfactant, is encapsulated in the vesicle with a volume fraction in particles that may range up to 10%. The first step of the encapsulation is the synthesis of a multiple emulsion the intermediate oily phase being evaporated to obtain the DDAB bilayer. The magnetic vesicles thus synthesized align and change shape when a magnetic field is applied. 相似文献