复合连接材料LCC/SDC的制备及低温烧结研究

采用微波辅助配合物燃烧法分别制备了La_0.8Ca_0.2CrO_3-δ(LCC)与Sm_0.2Ce_0.8O_2-δ(SDC)两种原料,并按设定比例将两种粉体混合以制备复合连接材料。用X射线衍射(XRD)分别对粉体和烧结体的物相进行分析,用Archimedes排水法测量体积密度并计算烧结品的相对密度,采用扫描电镜(SEM)对烧结体的微观结构进行表征,采用四端探针法测量电导率,用热膨胀仪     

区组长为奇素数的自反MD设计

本文利用差方法对自反MD设计SCMD(4mp,p,1)的存在性给出了构造性证明,这里p为奇素数,m为正整数．     

Low-Complexity Chase Decoding of Reed–Solomon Codes Using Channel Evaluation

A novel time-varying channel adaptive low-complexity chase (LCC) algorithm with low redundancy is proposed, where only the necessary number of test vectors (TVs) are generated and key equations are calculated according to the channel evaluation to reduce the decoding complexity. The algorithm evaluates the error symbol numbers by counting the number of unreliable bits of the received code sequence and dynamically adjusts the decoding parameters, which can reduce a large number of redundant calculations in the decoding process. We provide a simplified multiplicity assignment (MA) scheme and its architecture. Moreover, a multi-functional block that can implement polynomial selection, Chien search and the Forney algorithm (PCF) is provided. On this basis, a high-efficiency LCC decoder with adaptive error-correcting capability is proposed. Compared with the state-of-the-art LCC (TV = 16) decoding, the number of TVs of our decoder was reduced by 50.4% without loss of the frame error rate (FER) performance. The hardware implementation results show that the proposed decoder achieved 81.6% reduced average latency and 150% increased throughput compared to the state-of-the-art LCC decoder.     

(Ce0.8Sm0.2O2-δ/Y2O3:ZrO2)N超晶格电解质薄膜的制备及表征

采用脉冲激光沉积技术(PLD), 在MgO单晶基底上, 依次沉积氧化钐掺杂的氧化铈(Ce_0.8Sm_0.2O_2-δ, SDC)和钇稳定氧化锆(8 mol%Y₂O₃:ZrO₂, YSZ)制备了五种(SDC/YSZ)_N (N=3, 5, 10, 20, 30) 超晶格电解质薄膜. 利用X射线衍射(XRD)、高分辨透射电子显微镜(HR-TEM)和交流阻抗对其形貌、相结构和电学性能进行了表征. 结果显示, (SDC/YSZ)_N超晶格电解质薄膜之间形成了明显的界面和较好的超晶格结构; 薄膜表面颗粒生长均匀、致密、平滑, 在薄膜的界面处没有元素相互扩散也未出现裂纹, 外延生长良好; 电导率随着(SDC/YSZ)_N超晶格电解质界面数的增加而增加, 而活化能则随之减少, 是较为理想的低温固体氧化物燃料电池电解质.     

THEORETICAL APPROACHES TO PROTEIN STRUCTURE-FUNCTION ANALYSIS (Ⅰ)——DIRECTED PERTURBATION CONFORMATIONAL ANALYSIS

A new computational technique called directed perturbation conformational analysis has been developed for use in protein model building and structure-function studies. Designed to perform an efficient local search of a macromolecular potential energy surface, the algorithm can be used to locate multiple energy minimum conformers via low energy transition state structures from a single starting or trial structure. The algorithm contains developments to stabilize transition state optimizations for systems described by many degrees of freedom displaying anharmonic potential energy surfaces. It has been found to be efficient in the generation of alternative equilibrium structures from a given trial structure when compared with those generated from a standard molecular dynamics simulation of N-acetyl, N'-methyl-deca-L-alaninamide.     

复合阴极材料La1-xSrxCuO3-δ-SDC的制备及电学性能

合成具有单相正交钙钛矿结构的La1-xSrxCuO3-δ(x=0.15, 0.2, 0.3, 0.4)系列样品, 碘量滴定法实验结果表明, 随着Sr掺入量的增加, Cu3+离子的含量逐渐增加. 电学性能研究结果表明, La0.7Sr0.3CuO3-δ电导率最高, 与La0.6Sr0.4CoO3-δ相比, La0.7Sr0.3CuO3-δ具有更好的电化学性能, 可作为一种新的中温固体氧化物燃料电池(IT-SOFC)阴极材料. 将La0.7Sr0.3CuO3-δ与不同质量比的中温电解质Ce0.85Sm0.15O2-δ(SDC) 固相混合, 制备复合阴极材料, 电化学性能测试结果表明, 掺入适量的SDC有利于降低La0.7Sr0.3CuO3-δ电极的极化, 获得性能更优越的IT-SOFC阴极材料, 提高在中温区单电池的输出功率.     

用于辉光放电清洗的LCC谐振变换器仿真

针对辉光放电清洗系统中气体击穿之后对电源的恒流要求,提出用LCC谐振变换器的新方案,以改进辉光放电清洗电源方案,增加电源方案储备。利用软件工具选取参数范围、辅助理解拓扑特性以及验证方案。分析了LCC传递函数中主要参数品质因数QL和串并联电容比A对电路增益以及谐振器件应力的影响,设计了合理的参数取值。根据参数取值,利用MATLAB仿真表明,电源的闭环仿真输出达到额定值,LCC拓扑能满足辉光放电清洗电源的参数要求。LCC谐振变换器的电流归一化曲线表现出良好的恒流特性,适合设计成电流源。     

LCC谐振变换器的电路建模与参数设计

对用于高压场合的LCC谐振变换器进行了分析和研究,采用基波近似法推导等效模型,建立了谐振电路的大信号模型和等效模型,对LCC谐振变换器的稳态特性进行分析,采用了一种以输入阻抗角为限定条件的参数设计方法,该方法可以实现谐振变换器零电压开关的同时兼顾谐振电流对效率的影响。在大信号模型的基础上,建立了小信号模型,得到输出电压与输入占空比之间的传递函数,从而建立闭环系统,实现电压的宽范围输出。通过Simulink仿真验证了所设计的LCC谐振变换器可实现全负载范围的零电压开关(ZVS),说明了设计方法的可行性。     

基于VE理论的LCC与直觉模糊TOPSIS法的项目成本方案分析

将价值工程运用到全寿命周期成本分析中,计算方案的动态成本.通过解决传统层次分析法难以解决的模糊环境中的综合评价问题,提出直觉模糊层次分析法并求得各方案的功能系数,然后与方案LCC得到价值系数,以此为依据进行方案评选.为了使方案评选结果更加科学合理,利用直觉模糊TOPSIS法进行对比分析与验证.结合某住宅项目,得到两种评价结果的一致性,证明方法对于成本方案的评选是有效的.     

Characterization of carbon nanotubes and analytical methods for their determination in environmental and biological samples: A review

In the present paper, a critical overview of the most commonly used techniques for the characterization and the determination of carbon nanotubes (CNTs) is given on the basis of 170 references (2000–2014). The analytical techniques used for CNT characterization (including microscopic and diffraction, spectroscopic, thermal and separation techniques) are classified, described, and illustrated with applied examples. Furthermore, the performance of sampling procedures as well as the available methods for the determination of CNTs in real biological and environmental samples are reviewed and discussed according to their analytical characteristics. In addition, future trends and perspectives in this field of work are critically presented.