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41.
42.
Francesco Malatesta Giacomo Carrara Maria Perla Colombini Ambrogio Giacomelli 《Journal of solution chemistry》1993,22(8):733-749
The activity coefficients of Co(en)3Cl3 and K2SO4 were measured by means of a cell with ion-exchange liquid membranes following the method described in paper I. The results prove that this method is even more valuable with multicharged salts than with 1-1 electrolytes. The values obtained are precise and reliable down to dilution limits never before accessible, e.g., 4×10–5 mol-kg–1 in Co(en)3Cl3. High dilution levels are of particular importance when dealing with highly charged electrolytes since the trend at higher concentrations often leads to errors both in extrapolation to infinite dilution and in the absolute activity coefficients. As an application, the activity coefficients of [Co(en)3]2(SO4)3-suspected to be wrongly evaluated in past literature-were measured, and their values at low concentrations were actually lower than those quoted before. 相似文献
43.
In the context of the density functional theory of the local electron density the valence and differential density distribution in crystalline sulfates of M2SO4 (M is Li, Rb, and Cs) and double sulfates of MLiSO4 were calculated using the pseudopotential method in the basis set of numerical atomic pseudo-orbitals. It is shown that in lithium sulfate crystallographically inequivalent oxygen atoms are in different charge states and have a different force of chemical bonding with sulfur. Anions are bonded to each other through lithium atoms that form tetrahedral complexes with oxygen. In rubidium sulfates the electron clouds of the anions overlap and chain structures form. Chemical bonding between the anion and the cation has an ionic nature. These features of the electron structure manifest themselves in double sulfates, where LiO4 complexes that link the anionic chains also form, and heavy metals serve as cations. 相似文献
44.
The effects of sodium dodecyl sulfate on extracellular lipase produced byCandida lipolytica have been studied. The microorganism was grown in culture medium containing different sodium dodecyl sulfate concentrations
added to the culture at different intervals of growth. The extracellular lipase activity was not detected when the treated
culture supernatants were directly tested in Yeast Mold Agar-Triolein-Rhodamine plates, regardless of surfactant addition
time and concentrations. However, after ammonium sulfate precipitation and dialysis, the extracellular lipase activity could
be recovered. Therefore, the surfactant, under the experimental conditions used here, does not seem to be able to inhibit
lipase production, but it does inhibit the enzyme activity because of its presence in the mixture of the reaction. 相似文献
45.
Various types of sodium cellulose sulfate (SCS), dissolved in a 1M LiCl solution, were investigated by alternating current (AC)polarography. The SCS samples differed in the degree of substitution (DS), thedistribution of substituents within the anhydroglucose unit (AGU), and alongthechain, due to the method of synthesis. The goal was to study theelectrosorptionbehavior, characterized by the shape of the desorption wave in the polarogram,as a function of the chemical structure of the SCS samples. The shape of thedesorption wave reflects domains of different substitution. A superimpositionofparameters like DS and pattern of substitution on the electrosorption behaviorwas observed. The AC polarography method described can be used as a tool todistinguish between an even or uneven distribution of substituents along thecellulose chain. 相似文献
46.
47.
Methyl methacrylate and butyl methacrylate were polymerized in oil-in-water microemulsions that were stabilized by sodium dodecyl sulphate (SDS). A poly(N-acetylethylenimine) (PNAEI) macromer was also included in the recipe, as a cosurfactant and a comonomer. Polymerizations were initiated by UV-irradiation. The average diameters of latex particles, obtained by STM, were in the range of 17-200 nm. The experimental data evidenced that the particle size was mainly dependent on the SDS/PNAEI ratio. Polymerization yields were around 75-85%. The synthesized copolymers have viscosity average molecular weights in the range of 2.1-2.4×106 and glass transition temperatures of 38.0-43.5°C, lower than those obtained without using PNAEI. The investigation by means of FTIR and 1H-NMR techniques revealed that PNAEI was incorporated into the nanoparticles. 相似文献
48.
研究了烷基硫酸钠纯度,烷基碳链分布对甲基丙烯酸甲酯种子乳液聚合反应的影响。结果表明,烷基硫酸钠中乙醇不溶物含量的增加,可提高MMA乳液聚合反应速度,在采用K2S2O8-NaHSO3-Cu^2+三元氧化-还原引发体系的MMA乳液聚合中,Fe^2+降低反应速率,而Fe^3+则提高聚合反应速率; 相似文献
49.
以不同沉淀剂和铝盐与SnCl4共沉淀制备了Sn/Al2O3催化剂.考察了催化剂在富氧条件下催化丙烯选择性还原NO的性能,借助于X射线衍射(XRD)、扫描电镜(SEM)、N2吸附-脱附、吡啶吸附红外光谱(Py-IR)和程序升温还原(TPR)等方法研究了催化剂性能与结构的关系.发现以NH3.H2O和NH4HCO3为沉淀剂、NH4Al(SO4)2为铝盐制备的Sn/Al2O3催化剂催化活性最高,NO转化率达90.9%,最佳催化活性温度为350℃.该催化剂的比表面积为254 m2/g,孔体积为0.878 cm3/g,孔径分布曲线在3~8 nm出现双峰,Sn物种主要以晶态SnO2存在,且表面Lewis酸酸量增加. 相似文献
50.