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81.
原位红外光谱研究镧对负载钯催化剂上甲醇车尾气氧化机理的影响 总被引:1,自引:0,他引:1
在色谱微反装置上考察了负载Pd催化剂的甲醇深度氧化性能.结果表明,在γ氧化铝载体中,添加镧对负载Pd催化剂催化活性和选择性影响较大,甲醇氧化含氧中间物含量大大降低.利用insituFTIR技术测定了镧改性后的负载Pd催化剂表面的吸附物种和表面的程序升温反应,对负载Pd催化剂甲醇深度氧化反应机理进行了探讨. 相似文献
82.
环烷酸铅和烷基水杨酸铅的微波原位合成及其摩擦学性能 总被引:3,自引:0,他引:3
在液体石蜡中采用微波技术原位合成了油溶性环烷酸铅(LN)和十二烷基水杨酸铅(LAS),在高速低负荷(r=1500±10rpm,P=196-392N)和低速高负荷(r=300±10rpm,P=800N)两种条件下,用四球摩擦磨损试验对LN,LAS和对应的羧酸进行了摩擦学性能评价,用往复式摩试验机考察了LN和LAS抗磨减摩性能,结果表明:LN具有良好的抗磨减磨性能和中等的极压性能,且各项摩擦学性能指标均好于LAS。为弄清其作用机理,从分子结构分析了产生摩擦学性能差异的原因,并用SEM及XPS研究了磨斑表面,结果发现:摩擦过程中,LN和LAS都能在摩擦副表面形成吸附膜且部分吸附膜发生摩擦化学反应产生了铅氧化物转化膜,但所形成的吸附膜和转化膜厚度不同。 相似文献
83.
Variable-temperature in-situ FTIR spectroscopy has been used as the primary tool to investigate the effects of temperature (10 to 50 C ) on formaldehyde dissociative adsorption and electro-oxidation on the Ru (0001) electrode in perchloric acid solution, and the results were interpreted in terms of the surface chemistry of the Ru (0001) electrode and compared to those obtained during our previous studies on the adsorption of CO under the same conditions. It was found that formaldehyde did undergo dissociative adsorption, even at -200 mV vs. Ag/AgCl, to form linear (COL) and 3-fold-hollow(COH) binding CO adsorbates. In contrast to the adsorption of .CO, it was found that increasing the temperature to 50℃ markedly increased the amount of CO adsorbates formed on the Ru(0001) surface from the adsorption of formaldehyde. On increasing the potential, the electrooxidation of the CO adsorbates to CO2 took place via reaction with the active (1×1)-O oxide. A significant increase in the surface reactivity was observed on the RuO2(100) phase formed at higher potentials. Formic acid was detected as a partial oxidation product during formaldehyde electro-oxidation. The data obtained at 50℃are markedly different from those collected at 10 and 25℃ in terms of the amount of both CO2 and formic acid formed and the adsorbed COL and COH species observed. These results were rationalized by the thermal effects on both the loosening of the CO adlayer and the activation of surface oxide on increasing the temperature. 相似文献
84.
Guoying Xin Bin Sun Wei Wang Liping Zhu Wenhua Wu Meifang Zhu Yanmo Chen Hans-Jurgen P. Adler 《Macromolecular Symposia》2007,254(1):173-179
Summary: The tetrabutylorthotitanate (TBOT) was hydrolyzed by H2O produced during the esterification of pure terephthalic acid (PTA) and ethylene glycol (EG), and the bis(2-hydroxyethyl) terephthalate (BHET)/titanium compound nanocomposite was in-situ formed. The effect of TBOT on the esterification and its product property has been investigated. The results show that the butyl alcohol from the hydrolysis of TBOT is almost distilled out with H2O and there has no effect on the chemical structure of BHET caused by the introducing of TBOT. A kind of novel titanium compound is manufactured during the esterification under the existence of TBOT, which shows slice-like morphology from SEM micrographs and special XRD pattern with new diffraction peaks between 2-Θ = 6.9° and 10.2°. It is found that the BHET/titanium compound nanocomposite can act as the catalyst of polymerization of poly(ethylene terephthalate) (PET). The PET resins synthesized by in-situ formed catalyst have almost the same physicochemical properties with the commerced resins and have good spinnability. 相似文献
85.
原位红外光谱法是一种新兴的动态研究方法。该方法具有原位实时监控和红外光谱精确分析物质化学结构的优点,能够实时跟踪材料在不同温度下的化学变化,测定材料的微观结构与温度的关系。采用原位漫反射红外光谱研究了炸药1,3,5,7-四硝基-1,3,5,7-四氮杂环辛烷(HMX)分别在每min 5, 10, 20和40 ℃四种不同升温速率下的热分解行为。研究结果表明:在5 ℃·min-1升温速率下,断裂的HMX环发生分子内结合,在10, 20和40 ℃·min-1升温速率下,断裂的HMX发生分子间成环,形成稳定的八元环结构。随着温度的升高,C—N键的断裂数率远高于N—N键的断裂速率。随着升温速率的增加,C—N键的起始分解温度增加,表明增加升温速率会引起HMX分解的滞后。检测到HMX的分解所释放出CO2, N2O, CO, NO, HCHO, HONO, NO2和HCN共八种气体,升温速率的变化未改变HMX的分解机理。 相似文献
86.
原位复合法制备含铽(Ⅲ)配合物光学树脂及其荧光性质的研究 总被引:5,自引:1,他引:4
稀土元素因其独特的电子结构而具有光、电、磁、激光等特性,被誉为新材料的宝库,尤其是稀土配合物具有的Antenna效应,使发光强度明显增强.含稀土的高分子材料既具有稀土离子的发光性能,又具有高分子材料质量轻、抗冲击力强和易加工成型等优点,从而引起广泛的关注.我们曾用直接掺杂法制备含稀土配合物的光学树脂,但因稀土配合物与树脂的亲和性较小,难以均匀地. 相似文献
87.
Abstract A systematic survey of the quality status of the main aquifers in rural areas of Catalonia (Spain) regarding pesticide pollution has been carried out. A total number of 139 wells, distributed among 13 different hydrogeological units have been sampled and analyzed by GC-MS and GC-ECD, during the period 1997—98. Pesticides monitored were selected among triazine herbicides, organochlorine and organophosphorus insecticides. A positive presence of pesticides has been detected in 84.2% of the samples analyzed, 23.7% of them exceeding the requirements of the EU drinking water Directive (98/83/CE). Organochlorine insecticides were present in 62.6% of the samples, triazines in 49% and organophosphorus insecticides in 28.8%. The results obtained have been interpreted by Principal Component Analysis. 相似文献
88.
Lijian Jin Qiuju Qin Prof. Lihui Dong Shaoqing Liu Shangzhi Xie Jinkai Lu Aihao Xu Jiaxing Liu Hao Liu Yinchao Yao Xueyan Hou Prof. Minguang Fan 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(60):14947-14963
A series of MOFs with a 6-connected spn topology were synthesized (MOF-808-(Zr, Hf), PCN-777-(Zr, Hf), MOF-818-(Zr, Hf)). Through the in situ DRIFTS of NH3 adsorption-desorption, we found that the activated catalyst mainly contains Lewis acid sites. The effects of different organic ligands on the Lewis acid of the Zr6 cluster were analyzed by XPS and NH3-TPD, and the relative Lewis acidity of the same metal was obtained: PCN-777>MOF-808>MOF-818. In the Py-FTIR results, we confirmed that MOF-818 has a higher acid site density. In the activity test, MOFs with mesoporous structure showed better catalytic activity under normal temperature and pressure. Among them, MOF-818 can still maintain a high degree of crystallinity after catalysis. Finally, we use density functional theory to propose the mechanism of the cycloaddition reaction of carbon dioxide and styrene oxide. The results show that the metal is coordinated with styrene oxide and halogens attack the β carbon of the epoxide. 相似文献
89.
Surface-enhanced Raman scattering(SERS) is applied to detect the concentration of carbendzim(CBZ) in tea leaves. Au colloid is selected and used for active surfaces, and the extraction conditions are optimized in the experiment. The linearity range for the SERS intensity and the concentration of CBZ is found to be0.5 to 8 mg kgà1. The detection limit for CBZ is 0.1 mg kgà1and its recovery in tea samples is 72.3%. The detection results for CBZ using this method are compared with those of HPLC, and no obvious difference can be found. In addition, by dripping the condensed Au colloid on the tea leaves, the proposed SERS approach could be used to the in-situ determination of the half life period of CBZ on tea leaves. 相似文献
90.
多铁性材料BiFeO3(BFO)由于具有潜在的磁电耦合效应而备受关注,但纯相陶瓷的制备始终是一个难点,部分原因在于对其反应烧结相变规律的认识尚不充分。高温原位拉曼光谱技术(HT-Raman)是表征复杂的固体相变及反应的有力手段。首次利用HT-Raman,研究了不同配比(1∶1, 1.03∶1和1.05∶1)的Bi2O3-Fe2O3在不同升降温速率(10和100℃·min-1)下的反应烧结相变过程,以及降温时反应产物的收缩效应。结果表明:Bi2O3-Fe2O3反应烧结生成BiFeO3的过程中,会产生中间过渡相Bi2Fe4O9和Bi25FeO39∶Bi2O3-Fe2O3配比为1.03∶1、升降温速率较快时,产物中杂相含量最少,可见Bi过量及较快的升降温速率能有效抑制杂相的生成。降温过程中,发现BFO的A1-1峰位随着温度降低发生蓝移,且二者呈良好的线性关系,这说明降温过程中BFO仅因温度变化产生晶格收缩,并没有结构相变。此外,还利用二维X射线衍射(2D-XRD)及背散射电子衍射(EBSD),表征了烧结产物的相组成及形貌。XRD结果也显示Bi过量时杂相含量较少,与拉曼结果一致。结合2D-XRD和EBSD的结果可知, Bi过量时烧结产物晶粒尺寸较大且均一,可见快速升降温有利于晶粒的成核与生长。研究结果可帮助进一步认清反应烧结规律,并指导纯相BiFeO3基陶瓷的制备。 相似文献