SiCp/Y112铝基复合材料制备工艺及性能

3种不同铸造工艺条件下铝基复合材料的微观组织,并对其硬度进行了测定.研究表明:与全液态铸造法和半固态铸造法相比,搅熔铸造制备的SiCp/Y112铝基复合材料,其增强相SiC颗粒分布均匀,气孔率较少.是一种较理想的金属基复合材料制备工艺.未增强的Y112基体铝合金的维氏硬度高于其半固态坯料的维氏硬度;而SiCp/Y112铝基复合材料的维氏硬度明显高于基体的维氏硬度,并随着SiC颗粒的体积分数的增加其复合材料的维氏硬度不断提高.     

Optical bistability of planar metal/dielectric nonlinear nanostructures

We study theoretically a nonlinear response of the planar metal/dielectric nanostructures constituted from periodical array of ultra thin silver layers and the layers of Kerr-like nonlinear dielectric. We predict hysteresis-type dependences of the components of the tensor of effective dielectric permittivity on the field intensity allowing the change in material transmission properties from transparent to opaque and back at extremely low intensities of the light. It makes possible to control the light by light in all-optical nanoscale devices and circuits.     

Catalysis by Ir(III), Rh(III) and Pd(II) metal ions in the oxidation of organic compounds with H2O2

Catalytic activities of three transition metals, as iridium (III) chloride, rhodium (III) chloride and palladium (II) chloride, were compared in the oxidation of six aromatic aldehydes (benzaldehyde, p‐chloro benzaldehyde, p‐nitro benzaldehyde, m‐nitro benzaldehyde, p‐methoxy benzaldehyde and cinnamaldehyde), two hydrocarbons (viz. (anthracene and phenanthrene)) and one aromatic and one cyclic alcohol (cyclohexanol and benzyl alcohol) by 50% H₂O₂. The presence of traces (substrate: catalyst ratio equal to 1:62500 to 1:1961) of the chlorides of iridium(III), rhodium(III) and palladium(II) catalyze these oxidations, resulting in good to excellent yields. It was observed that in most of the cases palladium(II) chloride is the most efficient catalyst. Conditions for the highest and most economical yields were obtained. Deviation from the optimum conditions decreases the yields. Oxidation in aromatic aldehydes is selective at the aldehydeic group only and other groups remain unaffected. This new, simple and economical method, which is environmentally safe, also requires less time. Reactive species of catalysts, existing in the reaction mixture are also discussed. Copyright © 2007 John Wiley & Sons, Ltd.     

A new theory of regular functions of a quaternionic variable

In this paper we develop the fundamental elements and results of a new theory of regular functions of one quaternionic variable. The theory we describe follows a classical idea of Cullen, but we use a more geometric formulation to show that it is possible to build a rather complete theory. Our theory allows us to extend some important results for polynomials in the quaternionic variable to the case of power series.     

复杂像散椭圆光束的轨道角动量的实验研究

提出一种直接测量光束的轨道角动量的方法，其原理是把具有轨道角动量的光束照射到一个金属靶上，使其在光束的角动量作用下发生转动. 通过测量靶转动的角度来计算光束的角动量值. 对几种不同参数的光束的轨道角动量进行了测量，获得了轨道角动量与光束参数之间的关系，实验结果与理论分析较好地符合. 关键词： 复杂像散椭圆光束 轨道角动量 测量     

Study to improve the quality of a Mexican straight run gasoil over NiMo/γ-Al2O3 catalysts

Four NiMo catalyst supported on Al₂O₃ with different textural properties have been studied in the hydrodesulfurization (HDS), hydrodenitrogenation (HDN) and hydrodearomatization (HDA) of a Mexican straight run gasoil (SRGO). All reactions were carried out at three different temperatures 613, 633, and 653 K. Alumina supports were analysed by pyridine FTIR-TPD and nitrogen physisorption in order to determine their surface acidity and textural properties, respectively. TPR studies of the NiMo catalysts were analysed to correlate their hydrogenating properties. Metallic particles were characterized (after sulfidation) using transmission electron microscopy (TEM). Catalytic activities are discussed in relation to the physicochemical properties of NiMo catalysts. The importance of textural properties on coke deposition has been emphasized. The results of catalytic activity of these materials varied depending on dispersed MoS particles and pore distribution in final catalysts. The optimum pore diameter was found around 80 Å for HDS and HDN.     

有关力学谱和内耗工作的综合与回顾

本文广泛地收集了有关内耗，力学谱，超声衰减方面的专著及会议文集。反映了20世纪在此领域的英文，俄文出版的书籍。也列出了历次国际会议及前苏联，乌克兰，中国的国内会议。文中包括了点缺陷，电，声子，位错，晶界，电畴等诸方面在内的内耗与力学谱工作。     

(2+1)维广义Nizhnik-Novikov-Veselov系统的新严格解和复合波激发

利用拓展的Riccati方程映射法与变量分离法，得到了(2+1)维广义Nizhnik-Novikov-Veselov(GNNV)系统新的含有两个任意函数的相当广义的变量分离严格解.根据其中的周期波解，找到了该系统的复合波，即在周期波背景下的孤立波，并简要讨论了其演化行为. 关键词： GNNV系统 拓展Riccati映射 周期波解 孤立波     

重稀土高氯酸盐甲基苯甲酰甲基亚砜配合物的合成及Tb3+的发光

合成了重稀土高氯酸盐甲基苯甲酰甲基亚砜配合物RE(ClO4)3·L5·C2H5OH(RE=Gd,Tb,Dy,Tm,Yb;L=C6H5COCH2SOCH3).经元素分析、稀土络合滴定、摩尔电导及热重分析确定了配合物的组成,测定了配体及配合物的IR谱、1H NMR及铽配合物的磷光光谱、荧光激发和发射光谱,根据荧光发射光谱数据计算了铽配合物的各能级值.     

非对称三态叠加多模泛函叠加态光场的高次压缩——广义电场分量的不等幂次和压缩效应研究

多模真空态|{0j}〉q与两个空间强度分布特征不同的多模复共轭泛函相干态|{f(j a)*(x,y,z)}〉q和|{f(j b)*(x,y,z)}〉q的线性叠加组成的三态叠加多模泛函叠加态光场|ψ(f3)〉q,利用多模压缩态理论,研究了态|ψ(f3)〉q中广义电场分量的不等幂次高次和(H)压缩特性.结果表明:在一定的条件下,态|ψ(f3)〉q的广义电场分量可呈现出周期性变化的任意奇数次和任意偶数次的不等幂次高次H压缩效应;光场的经典振幅和经典初始相位的任意非对称空间分布特征对其压缩程度和压缩深度等压缩特性将产生直接的影响.