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41.
For LiYF4:Ce3+, LiLuF4:Ce3+ and LuF3:Ce3+ crystals UV/visible emission and time-resolved VUV/UV excitation spectra were recorded at liquid helium temperature with spectral resolution of 0.1 nm for excitation spectra and better than 0.3 nm for emission spectra. Well resolved fine structures due to zero-phonon lines were clearly observed in both excitation and emission spectra for LiYF4:Ce3+ and LiLuF4:Ce3+. For LuF3:Ce3+ crystal no fine structure was detected in the spectra even at the highest spectral resolution. Under the host excitation, the fine structure for high-energy emission band of Ce3+ (5d-2F5/2) in LiLuF4:Ce3+ becomes well pronounced because of weaker reabsorption effect, as compared to Ce3+ 4f-5d absorption, due to small penetration depth for exciting radiation. As a result the crystal-field splitting for 2F7/2 and 2F5/2 levels of Ce3+ in LiLuF4 crystal was measured. First observation of zero-phonon lines at ∼81,550 and ∼82,900 cm−1 as well as vibronic side bands due to interconfigurational 4f14-4f135d transitions in Lu3+ is reported for excitation spectrum of LiLuF4:Ce3+. 相似文献
42.
Guanshi Qin Tatsuya Yamashita Yusuke Arai Yasutake Ohishi 《Optics Communications》2007,279(2):298-302
We demonstrate a 22 dB all-fiber amplifier at 546 nm using Er3+-doped fluoride fiber by forward upconversion pumping of a 974 nm laser diode. The gain saturation effects and the power conversion efficiency of this amplifier are investigated in detail based on gain characteristics and numerical simulations. 相似文献
43.
A rapid, sensitive and selective method is described for the determination of traces of fluoride in real samples based on the integration of retention and fluorescence detection (λex = 335 nm, λem 405 nm) of a ternary complex [zirconium(IV)-Calcein Blue-fluoride) using a conventional flow cell packed with an anion-exchange resin. A study of a large number of experimental variables (flow-injection configuration, type of support, eluting carrier, sample pH, etc.) allowed the development of an optimized, highly selective determination of fluoride with an analytical concentration range of 1–40 ng ml?1 (r.s.d. 1%) with a sampling frequency of 30 h?1. A critical comparison with a probe sensor using the same chemical system showed the described flow-through sensor to be clearly superior. 相似文献
44.
M. Yamaga T. Inoue S. Yabashi M. Honda J.-P. R. Wells K. Shimamura 《辐射效应与固体损伤》2013,168(6-12):977-982
Electron paramagnetic resonance (EPR) spectra of Ce 3+ in LiLuF 4 (LLF) and LiSr 0.8 Ca 0.2 AlF 6 (LSCAF) observed at low temperatures (<20 v K) show that the Ce 3+ centers have tetragonal and pseudo-trigonal symmetry with ( g , g )=(2.751, 1.467) and (2.14, 0.80), respectively. The EPR lines of Ce 3+ in LSCAF are inhomogeneously broadened by different Ce 3+ configurations which correspond to the random occupation of the second nearest neighbor cation sites by Ca 2+ and Sr 2+ and/or charge compensators. These EPR results indicate that the Ce 3+ centers in LLF and LSCAF are associated with substitution of Ce 3+ for Lu 3+ with eight-fold coordination and Sr 2+ /Ca 2+ with six-fold coordination, respectively. Fourier transform infrared absorption has been used to measure transitions between the 2 F 5/2 ground state and the 2 F 7/2 multiplet of Ce 3+ in LLF at 10 v K. The optical absorption and luminescence of Ce 3+ :LLF and Ce 3+ :LSCAF in the UV range are strongly polarized. The energy levels and polarization dependence of the optical transitions can be accounted for in terms of the crystal field potential experienced by the Ce 3+ ions under the action of the different point group symmetries. 相似文献
45.
This work is a critical review of the chemical-physical properties of the fluoride salts of interest in the Molten Salt Reactor project. In total five salt compositions are discussed. Two of them are choices for coolant applications (based on LiF-BeF2 and NaF-NaBF4 systems) one is considered as a heat transfer salt (LiF-NaF-KF system) whereas the other two are the main candidates for the fuels in non-moderated breeder and thermal breeder reactors, respectively (LiF-ThF4 and LiF-BeF2-ThF4 systems). For all the systems the phase diagrams are presented with the emphasis on the melting behaviour and the vapour pressure. Heat capacity, density, viscosity and thermal conductivity, as well as the solubility for actinides in case of the fuels are presented also. 相似文献
46.
Periodic current oscillations during anodic dissolution of monocrystalline p-Si(100) in buffered ammonium fluoride solutions (0.1 mol dm−3 fluoride, pH 4.5) were investigated using a flow cell in order to eliminate mass transport limitations. The flow cell was designed to permit simultaneous in-situ ellipsometry, impedance and potential modulated microwave reflectivity measurements. Analysis of the ellipsometric response showed that the current oscillations are accompanied by a synchronous variation of the overall oxide thickness with an amplitude of 4.5±0.1 nm. Analysis of the relationship between the total oxide thickness and the current during the oscillation cycle shows that to a first approximation the rate of chemical dissolution of anodic oxide remains constant. Oscillations of the electrode admittance and potential modulated microwave reflectivity were also measured. The imaginary component of the admittance is related to the oscillation in thickness of a narrow inner region of ‘dry’ oxide and to changes in the accumulation capacitance. The oscillation in the potential modulated microwave reflectivity is interpreted in terms of the changes in the density of holes accumulated at the p-Si SiO2 interface. 相似文献
47.
This study investigated the variations in human plasma fluoride concentrations ([F]) and sought to determine the causes. Five subjects (27-33 years old) received a low-F diet during the 5 days of the study. Plasma samples and urine were collected every 3 h from 8 a.m. to 8 p.m. F, PTH, Ca and P were analyzed with the electrode, by chemiluminescence, AAS and colorimetry, respectively. A trend for the plasma [F] was found. The peak [F], 0.55 ± 0.11 μmol L−1, occurred at 11 a.m. and the lowest [F], 0.50 ± 0.06 μmol L−1 occurred between 5 and 8 p.m. Plasma [F] were positively correlated with urinary F excretion rates and with serum PTH levels, but not with the Ca or P levels. Serum PTH levels were positively correlated with urinary F excretion rates and negatively correlated with plasma Ca. The results suggest that the renal system seems to control the daily fluctuations in plasma [F]. 相似文献
48.
A new highly sensitive colorimetric receptor 1 for fluoride based on anthracene-9,10-dicarbaldehyde bis-p-nitrophenylhydrazone was designed, synthesized and characterized. Experiments showed that the receptor 1 can selectively recognize the fluoride in DMSO and even in 95/5 DMSO/H2O (v/v) mixtures. The ability of recognition and the bond between receptor 1 and anions were determined using visual inspection, UV-vis and fluorescence analyses. In addition, 1H NMR experiments were carried out to explore the nature of interaction between receptor 1 and fluoride. Finally, analytical application and detection of fluoride in toothpaste have been studied. 相似文献
49.
M. Rajeswara Rao 《Tetrahedron》2010,66(9):1728-1162
3,5-Bis(trimethylsilylethynyl)-4,4-difluoro-8-(4-tolyl)-4-bora-3a,4a-diaza-s-indacene [BODIPY(CCTMS)2] has been synthesized by coupling of 3,5-dibromo-4,4-difluoro-8-(4-tolyl)-4-bora-3a,4a-diaza-s-indacene with trimethylsilylacetylene under pd(0) coupling conditions. The BODIPY(CCTMS)2 was used as a selective colourimetric and fluorescent chemodosimeter for fluoride ion, following the F− ion induced cleavage of trimethylsilyl group, the protecting group of ethyne functionality by monitoring the changes in UV-vis and fluorescence properties. The dosimeter BODIPY(CCTMS)2 display clear changes in colour, absorption and emission bands selectively for F− ion over other anions such as Cl−, Br−, I−, ClO4− and HPO42−. 相似文献
50.
Al(III)- and Zr(IV)-salophens of novel structures were tested as anion-selective ionophores. It was shown that these compounds are highly selective to fluoride and give selectivity greatly deviating from classical Hofmeister pattern, when doped into the polymeric membrane of ion-selective electrode (ISE). The following selectivity sequence has been recorded for both ionophores: F− > ClO4− > SCN− > NO3− ≈ Br− ≈ Cl−. The results of potentiometric and spectrophotometric measurements allow to conclude that the nature and structure of salophen ligands influence stability of ISE working parameters. An increase in salophen ligands lipophilicity results in prolongation of the ISE lifetime, most likely due to slower ionophore decomposition caused by the hydrolysis of imine bonds in salophen structure. Ion-selective electrodes (ISEs) with the most successful Al(III)-salophen exhibited a stable, fast and near-Nernstian fluoride response and a functional lifetime near 3 weeks and selectivity coefficients with as follows: −2.8 (Y− = Br−), −2.7 (Cl−), −2.8 (NO3−), −1.5 (SCN−), −1.3 (ClO4−), which is better than for other ones based on Zr(IV)- and Al(III)-salophens and salens described to date. 相似文献