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131.
《Angewandte Chemie (International ed. in English)》2017,56(15):4261-4265
A supramolecular complex was constructed by encapsulation of a 3O2 molecule inside an open‐cage C60 derivative. Its single‐crystal X‐ray diffraction analysis revealed the presence of the 3O2 at the center of the fullerene cage. The CV measurements suggested that unprecedented dehydrogenation was promoted by the encapsulated 3O2 after two‐electron reduction. The ESR measurements displayed the triplet character as well as the anisotropy of the 3O2. Additionally, the SQUID measurements also demonstrated the paramagnetic behavior above 3 K without an antiferromagnetic transition. Upon photoirradiation with visible light, three phosphorescent bands at the NIR region were observed, arising from the exited 1O2 generated by self‐sensitization with the outer cage, whose lifetimes were not affected by the environments. These studies confirmed that the complex is a crystalline triplet system with incompatible “high spin density” but “small interspin interaction” properties. 相似文献
132.
Y. Xiang S. J. Xiong F. Y. Hong 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2008,47(2):257-260
A bipartite quantum state (for two systems in any dimensions) can be
decomposed as a superposition of many components. For a
superposition of more than two components we prove that there is a
bound of the entanglement of the superposition state which can be
expressed according to entanglements of its component states.
Especially, if the component states are mutually bi-orthogonal, the
entanglement of the superposition state can be exactly given in
terms of the entanglements of the states being superposed. 相似文献
133.
E. Santos 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2008,46(3):531-536
A recent experiment by Brida et al. [Eur. Phys. J. D 44, 547 (2007)] is analyzed with the conclusion that the results disagree with standard quantum predictions but fit a simple
local hidden variables model. New experiments are proposed which might throw new light on the anomaly. 相似文献
134.
G. G. Fedoruk 《Journal of Applied Spectroscopy》2002,69(2):161-182
The application of transient nutations in EPR spectroscopy of condensed media is considered. The main methods of formation and observation of transient nutations are presented. The laws governing this phenomenon in twolevel and multilevel spin systems and also in inhomogeneous broadening of EPR lines are described. Recent advances in the use of transient nutations to separate overlapping spectra, identify quantum numbers and quantum transitions, investigate the kinetics of photoinduced paramagnetic centers, and determine relaxation times for a wide range of crystalline and disordered media are presented. 相似文献
135.
Chzhan M Kuppusamy P Samouilov A He G Zweier JL 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1999,137(2):373-378
There has been a need for development of microwave resonator designs optimized to provide high sensitivity and high stability for EPR spectroscopy and imaging measurements of in vivo systems. The design and construction of a novel reentrant resonator with transversely oriented electric field (TERR) and rectangular sample opening cross section for EPR spectroscopy and imaging of in vivo biological samples, such as the whole body of mice and rats, is described. This design with its transversely oriented capacitive element enables wide and simple setting of the center frequency by trimming the dimensions of the capacitive plate over the range 100-900 MHz with unloaded Q values of approximately 1100 at 750 MHz, while the mechanical adjustment mechanism allows smooth continuous frequency tuning in the range +/-50 MHz. This orientation of the capacitive element limits the electric field based loss of resonator Q observed with large lossy samples, and it facilitates the use of capacitive coupling. Both microwave performance data and EPR measurements of aqueous samples demonstrate high sensitivity and stability of the design, which make it well suited for in vivo applications. 相似文献
136.
In the fluorinated La2CuO4−x
prepared using a solid state reaction with NH4HF2 as a fluorinating agent at 550 K at ambient pressure, superconductivity was detected by microwave and EPR techniques with
aT
c of 35 K. 相似文献
137.
Sidabras JW Mett RR Hyde JS 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2005,172(2):333-341
This paper builds on the work of Mett and Hyde [J. Magn. Reson. 165 (2003) 137]. Various aqueous flat-cell geometries in the perpendicular orientation have been studied using Ansoft High Frequency Structure Simulator (version 9.0, Pittsburgh, PA) and Computer Simulation Technology Microwave Studio (version 5.0, Wellesley Hills, MA). The analytic theory of Mett and Hyde has been refined to predict optimum dimensions of multiple sample cell structures including the effect of the sample holder dielectric properties and the interaction of the cells with each other on EPR signal strength. From these calculations and simulations we propose a practical multiple cell sample structure for use in commercial rectangular TE102 cavities that yields 2.0-2.3 times higher sensitivity relative to a single flat-cell in the nodal orientation. We also describe a modified TE102 resonator design with square rather than cylindrical sample-access stacks that is predicted to give a factor of 2.2-2.7 enhancement in EPR signal strength of a single flat-cell in the nodal orientation. These signal enhancements are predicted with sample holders fabricated from polytetrafluoroethylene. Additional improvement in EPR signal of up to 75% can be achieved by using sample holder materials with lower dielectric constants. 相似文献
138.
Lang J Sloop DJ Lin TS 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2005,176(2):4731-256
We report a new technique to map the orientational anisotropy of paramagnetic systems without physically changing the crystal orientations in near zero-field (NZF) pulsed EPR experiments. By implementing three sets of orthogonal coils around the sample, we are ble to create a magnetic vector up to 2 mT in any three-dimensional orientation in space. In NZF region, the hyperfine tensor elements are comparable to the electronic Zeeman interaction energy, thus very rich spectral patterns can be obtained by "dialing" in a magnetic field vector without moving the sample. The technique further allows us to examine the site symmetry of organic crystals and powdered solids doped with chromophores which can be photo-excited to the triplet state by laser light. The technique is exemplified in the study of pentacene in p-terphenyl crystals. 相似文献
139.
Narkowicz R Suter D Stonies R 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2005,175(2):275-284
EPR resonators on the basis of standing-wave cavities are optimised for large samples. For small samples it is possible to design different resonators that have much better power handling properties and higher sensitivity. Other parameters being equal, the sensitivity of the resonator can be increased by minimising its size and thus increasing the filling factor. Like in NMR, it is possible to use lumped elements; coils can confine the microwave field to volumes that are much smaller than the wavelength. We discuss the design and evaluation of EPR resonators on the basis of planar microcoils. Our test resonators, which operate at a frequency of 14 GHz, have excellent microwave efficiency factors, achieving 24 ns pi/2 EPR pulses with an input power of 17 mW. The sensitivity tests with DPPH samples resulted in the sensitivity value 2.3 x 10(9) spins.G(-1) Hz(-1/2) at 300 K. 相似文献
140.
S. A. Mikhnov 《Journal of Applied Spectroscopy》2004,71(5):757-759
It has been found that the phase shift min in the synchronous detection block that ensures the minimum amplitude of the EPR lines of ruby, diphenylpicrylhydrazyl, and MnSO4·5H2O, depends on the amplitude of the modulationH
m of a stationary magnetic field. The dependence of min on H
m is explained by the inertial nature of the recovery of the stationary states of paramagnetic centers on a change in the magnetic field strength. 相似文献