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991.
A novel application of an electrochemical biosensor is here employed as analytical method for the detection and presumptive identification of antimicrobial drug residues in milk. The measurement was based on carbon dioxide production rate in relation to inhibition of microbial grow (Escherichia coli ATCC 11303). In this pilot study quinolone and tetracycline residues have been taken into consideration because use of these last in livestock production has been identified as area of particular concern. The experimental approach and analytical method developed appear adequate for the purpose, and compared to older screening methods as, for example, the microbial inhibition assays and immunoassays, offers the advantages of (i) very short analysis time (about 120 min); (ii) smaller sample amount (approximately 0.5 mL); (iii) no sample treatment (iv) good precision; and (v) the possibility of following, in a continuous manner, the inhibition process. Moreover, sensitivity of electrochemical biosensor system is resulted very high considering that for all quinolones and tetracyclines investigated it has been possible detect a residue concentration below or equal to 25 μg L−1. Under this point of view, it must be considered that the maximum residue limits fixed by UE for quinolones and tetracyclines in milk are, at present, all higher of this concentration. 相似文献
992.
《Electroanalysis》2006,18(5):433-439
This paper presents the results of investigation on selectivity of the sulfur dioxide amperometric sensor with Nafion membrane in the presence of carbon monoxide and nitrogen dioxide as the interferents. There have been compared selectivity coefficients, for the sensors containing the following internal electrolytes: solution of sulfuric acid (concentration 5 mol dm?3) in pure water (A) and solution of sulfuric acid (concentration 5 mol dm?3) in mixed solvent dimethylsulfoxide‐water with an DMSO: H2O mole ratio of 1 : 2 (B). Values of the selectivity coefficients have been calculated based on the calibration curves. Analysis of both calibration curves and selectivity coefficients plays a significant role in optimization of a working point of a particular sensor. The investigated sensor operates in a three‐electrode system, where the working and counter electrodes are vacuum sublimation deposited on the membrane surface. 相似文献
993.
提出了一种用硅双结型色敏器件测量色温的方法.在合理的测控电路下,硅双结型色敏器件的电流对数比与实验灯泡的色温值呈良好的单值对应,经单片机处理后可以得到分段线性关系.通过对电流对数比与波长随线的数据拟合,结果表明,用硅双结型色敏器件测量色温,其测量温度可以到10^4K以上,精度可以达到10K.本文的方法与传统方法相比减少了工作量,降低了费用,具有通用性和实用价值. 相似文献
994.
The field of the rapid characterization of products by HS-MS is reviewed. The general principle of HS-MS systems consists of introducing volatile components present in the HS of a sample without prior chromatographic separation into the ionization chamber of a mass spectrometer. The spectrum resulting from simultaneous ionization and fragmentation of the mixture of molecules introduced constitutes a “fingerprint” that is characteristic of the product being analyzed. Exploitation of this spectral information allows one determine the composition of the sample. 相似文献
995.
John A. Mikroyannidis Helena Hlídkov Drahomír Výprachtický Vra Cimrov 《Journal of polymer science. Part A, Polymer chemistry》2005,43(14):3079-3090
Three new poly(p‐phenylenevinylene)‐based polymers containing two 1,3,4‐oxadiazole moieties in the main chain per repeat unit were synthesized by Heck coupling. A single, double, or triple bond was introduced between the oxadiazoles to provide a means for modifying the polymer properties. The polymers were readily soluble in common organic solvents and showed Tg values lower than 50 °C. The color of the emissive light in both the solid state and the solution could be tuned by a change in the nature of the bond between the oxadiazole rings. The polymers emitted ultraviolet‐green light in solution with a photoluminescence (PL) emission maximum at 345–483 nm and blue‐green light at 458–542 nm in thin films. The PL quantum yields in solution were 0.36–0.43. The electrochemical properties are affected by the nature of the bond between the oxadiazoles as well. In polymers with a single bond between the oxadiazoles, a lower ionization potential was observed than in polymers with a double or triple bond. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 3079–3090, 2005 相似文献
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998.
《Electroanalysis》2006,18(16):1614-1619
Tape casting is a feasible method for preparing ceramic tapes with different electrical and magnetic properties for multilayer ceramic devices. This paper describes the tape casting process for the preparation of a new kind of self‐standing carbon electrodes (SSCE) using different ratios of graphite and the organic additives generally used in the non‐aqueous tape casting process. 相似文献
999.
植物生理信息采集处理系统研究 总被引:1,自引:0,他引:1
王成 《新疆大学学报(理工版)》2003,20(3):308-313
以虚拟仪器理论为基础研制的植物生理信息采集处理系统.应用了传感器技术、自动测量技术、微计算机软硬件技术及数据的数学处理方法.植物生理信息采集处理系统由传感器、信号调理电路、数据采集卡、通用计算机和数据采集软件、数据处理软件构成,实现了植物生理信息多通道数据的实时自动采集和处理功能.系统具有测量集成、植株活体无损测量、信息数字化、全自动记录、用数据库管理数据等特点. 相似文献
1000.