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41.
Toshiaki Sunazuka Masaki Handa Tatsuya Shirahata Kazuhiko Otoguro Satoshi ōmura 《Tetrahedron》2004,60(36):7845-7859
In the current studies, we used the Kakisawa-Kashman modification of the Mosher NMR method to determine the complete absolute stereochemistry of arisugacins. We also report the convergent total synthesis of (+)-arisugacins A and B by a sequence including (i) ruthenium complex-catalyzed asymmetric reduction of the cyclohexenone derivative; (ii) stereoselective construction of the arisugacin skeleton by a Knoevenagel-type reaction of an α,β-unsaturated aldehyde derivative with production of a 4-hydroxy-2-pyrone derivative as a key reaction; and (iii) stereoselective dihydroxylation to give the diol derivative, followed by deoxygenation. Accordingly, we defined the absolute structures of arisugacins A and B as 4a-(R),6a-(R),12a-(R), and 12b-(S). Finally, we characterized the bioactivities of the synthetic intermediates to understand the structure-activity relationships of the arisugacins. 相似文献
42.
Xiaoping YangChristopher R. Lowe 《Tetrahedron letters》2003,44(7):1359-1362
In this report, the stepwise synthesis of a novel rigid and functionalised macrocycle 2 based on triazine and phenylenediamine linkers, is presented. Poor recognition of the macrocycle 2 for its substrates is observed, which shows experimentally that for the meltriazine based-calix[6]arene system, the binding ability of the melamine moiety gets more benefit from the ring flexibility derived from a xylenediamine linker 1 than from a phenylenediamine linker 2. 相似文献
43.
Nada F. Atta 《European Polymer Journal》2005,41(12):3018-3025
Polymeric films derived from thioflavin S were electrosynthesized on mild steel and silver electrodes in sulfuric acid and lithium perchlorate-containing aqueous solutions. The introduction of thioflavin S in an acidic solution protected the surface of steel from corrosion. The electrochemical behavior of the steel coated with a layer of poly(thioflavin) was examined by electrochemical impedance spectroscopy. The films exhibited a capacitive behavior and were semi-conductive in nature. Infra red reflectance measurements of the polymer films at the steel surface showed that the polymer structure retained the aromatic structure of the benzene and thiazole rings with the distinction of a nitrogen quinone vibrational band. Surface morphology of the polymer film was examined with scanning electron microscopy. The films are yellow, compact and dense when electrochemically formed onto steel surfaces when compared to a blue rather porous when formed onto silver electrode. The mechanism of electropolymerization of thioflavin is given and found similar to that of aniline with the possibility of metal chelation with the sulfur and/or nitrogen in the thiazole ring. 相似文献
44.
AISI 304 Stainless Steel is widely used in different industrial fields because of its mechanical and corrosion properties.
However, its tendency to corrosion in presence of halide ions limits the applications. One strategy to improve the corrosion
resistance is the use of coatings barriers containing corrosion inhibitors in their formulation. The lanthanides present attractive
green and corrosion properties for the substitution of chromates, which are the most common substances used as corrosion protection.
However, these compounds are highly toxic, and an intense effort is being undertaken to replace them. Cerium is a good alternative
because of its relatively low cost and abundance. It fulfils the basics requirements for being considered an alternative inhibitor:
the ions form insoluble hydroxides and they present low toxicity. Inorganic and hybrid sol-gel coatings have been developed
to increase the corrosion resistance of metals and they provide an excellent vehicle for the incorporation of secondary phases
including particles and metal ions as cerium ions.
The aim of this work was to study the influence of the incorporation of cerium ions in hybrid silica sol-gel coatings deposited
on AISI 304 stainless steel as substrate as a potential replacement of chromate treatments. This system should combine the
barrier protection effect of silica coating with the corrosion inhibitor effect of the cerium ions inside the coatings. After
7 days of immersion in NaCl, coated substrates showed lower current densities than the bare steel, although the coatings produced
from Ce (III) salts experience a slight weakening in time and those obtained from Ce (IV) chemicals evidence an enhance in
the coating performance, probably due to the plugging of corrosion products in the defective areas of the film. 相似文献
45.
The reaction of 2,5-diamino-4-benzylamino-pyrimidin-6(III)-one (6) with benzoyl isothiocyanate furnished 2-amino-4-benzylamino-5-[1-(3-benzoylthioureido)]-pyrimidin-6(1H)-one (7) in good yield. The title compound I was synthesized from compound 7 via a cyclodesulfurative reaction with DCC in DMF at 80°C directly to form 8-benzoylamino-9-benzylguanine (9) which was subsequently treated with 1 N sodium hydroxide. 相似文献
46.
In our experiment, three groups of seedlings of SDP Pharbitis nil cv. violet were sepa-rately treated with three different photoperiods (1,16 h dark period--SD; 2, continuous illumi-nation--CL; 3, 16 h dark treatment with 10 min white light in the middle of the dark period--NB). By analysing proteins in the cotyledons from three groups with 2-D PAGE, we found nodifference in protein pattern between the three groups at 0 or 8 h after photoperiodic treatments.At 24 h after the treatments, a specific protein(MW:19 kD; pI: 4.5)appeared only in the cotyledonsof the seedlings which endured SD. This protein disappeared at 72 h after SD. ActinomycinD could inhibit flowering and the specific protein occurrence when applied to cotyledonsprior to SD, but it had no inhibition effect on flowering as well as the specific proteinoccurrence when applied to cotyledons after SD. Chloroamphenicol, a protein synthesisinhibitor, inhibited flowering when applied to cotyledons prior to or immediately after SD,but it did not i 相似文献
47.
以 5 甲氧基 (或氯 ) 2 巯基苯并咪唑 ( 1)为原料 ,经缩合和还原得到 5 甲氧基 (或氯 ) 2 ( 4 氨基苯硫基 )苯并咪唑 ( 3 ) ,再与异硫氰酸烃基酯反应得到取代硫脲 4,最后与卤代烃反应得到 12个新的S 烃基 1 烃基 3 [4 ( 5 甲氧基 (或氯 )苯并咪唑 2 巯基 )苯基 ]异硫脲化合物 5 .其结构经IR ,1 HNMR ,MS及元素分析确证 .初步的药理试验表明 ,12个目标化合物的iNOS抑制活性均强于阳性对照药氨基胍 相似文献
48.
定标粒子理论计算非水溶液的盐效应常数 总被引:1,自引:0,他引:1
本文应用定标粒子理论计算了非电解质溶质在盐(NaI、或KI)和环丁砜组成的非水电解质溶液中溶解度的盐效应常数。硬球作用项采用Masterton-Lee的方法。软球作用项采用胡英等的径向分布函数处理方法, 并考虑进了偶极-偶极、偶极-诱导偶极、电荷-偶极和电荷-诱导偶极等相互作用。分子的硬球直径σ和能量参数∈/k由经验方程计算。由理论值和实验结果比较得出: 当σ_2取0.563 nm、离子半径取电子密度标度时, 理论值与实验值符合得较好。 相似文献
49.
《Arabian Journal of Chemistry》2020,13(9):7183-7198
The extraction of Zea mays hairs (Z. mays) was carried out by soxhlet and ultrasound techniques and through three solvents. Phytochemical tests and quantitative analysis of total phenols content (TPC) and flavonoids content (FC) for all extracts were also determined. The antioxidant activity, for different fractions, was determined by using three methods; DPPH, FRAP and TAC. All extracts were rich in polyphenols and the analysis of TPC and FC showed that the hydro-ethanolic extract obtained by ultrasound was characterized by a significant amount of TPC and FC. The n-butanolic fraction was rich in FC and also had a very high antioxidant capacity. On the other hand, the inhibiting effect of hydro-ethanolic extract, n-butanolic fraction and standard (flavone) on mild steel corrosion in 1 M HCl solution was investigated by electrochemical measurements. The polarization curves along with EIS diagrams indicated that flavone was the major molecule responsible for inhibition and acted as mixed-type inhibitor with predominant control of cathodic reaction. The antioxidant activity of BF was well correlated to corrosion inhibition efficiency. 相似文献
50.
The corrosion of printed circuit boards can be effectively prevented with a polyurethane conformal coating. In this study, the protective performance of PU coating was investigated systematically through electrochemical measurements and simulated exposure/immersion tests. Some fungi tests were also included. All experimental results show that a polyurethane coating effectively inhibits corrosion on printed circuit boards. The optimal thickness of the coating film should be about 60 μm. Long-term exposure tests showed that this coating material could preserve the reliability of the investigated printed circuit boards for more than 400 days in a 90% relative humidity environment at 25°C. 相似文献