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121.
Separation of complex sugar mixtures on a hydrolytically stable bidentate urea‐type stationary phase for hydrophilic interaction near ultra high performance liquid chromatography 下载免费PDF全文
Dorina Kotoni Alessia Ciogli Claudio Villani David S. Bell Francesco Gasparrini 《Journal of separation science》2014,37(5):527-535
A stationary phase bearing both bridged bis‐ureido and free amino groups (USP‐HILIC‐NH2–2.5SP) for high‐speed hydrophilic interaction liquid chromatography separations was prepared using a one‐pot two‐step procedure starting from 2.5 μm totally porous silica particles. Highly polar compounds, such as polyols, hydroxybenzoic acids, and sugars, were successfully analyzed in shorter times and with higher peak efficiency, when compared to results obtained with a bidentate urea‐type column packed with 5 μm particles. Increased sugarophilicity and better peak shape were attested for the USP‐HILIC‐NH2–2.5SP column (100 × 3.2 mm id) when compared with two commercially available UHPLC columns, namely an acquity BEH amide packed with totally porous 1.7 μm microparticles and a HILIC Kinetex column packed with core–shell 2.6 μm particles. Finally, the new column was employed in the separation of complex mixture of sugars (mono‐, di‐, and oligosaccharides) and in the analysis of beer samples. The resulting chromatograms showed good selectivity and overall resolution, while the catalyzing effect of the free amino moieties resulted in excellent peak shapes and in the absence of split peaks due to sugar anomerization phenomena. 相似文献
122.
123.
《Arabian Journal of Chemistry》2022,15(9):104035
In this study, we used the Span 80 to enhance solvent extraction process, and we explored the mechanism. The results indicated different solvents would obtain different oil recovery, and toluene showed the optimal oil recovery, and the n-heptane showed the lowest oil recovery. The complex solvents could improve oil recovery. Toluene could make the heavy oil show the lowest viscosity (89.6 Pa.S), and n-heptane make the heavy oil show the highest viscosity (176.3 Pa.S). Complex solvents could decrease the heavy oil viscosities. The higher C/H was, the higher heavy oil recovery was, and when the asphaltene and resins content increase, the C/H would increase. The C/H showed the highest value (9.09, by toluene) and the lowest value (8.15). In this study, Span 80 could increase heavy oil C/H ratio, decrease heavy oil viscosity. Span 80 could make the sands surface more hydrophilic, and then the solvent loss would decrease. The oil recovery was high after 10 times recycle use. 相似文献
124.
J. B. Satinover D. Sornette 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,60(3):369-384
Human beings like to believe they are in control of their
destiny. This ubiquitous trait seems to increase motivation and persistence,
and is probably evolutionarily adaptive [J.D. Taylor, S.E. Brown, Psych. Bull. 103, 193 (1988); A. Bandura,
Self-efficacy: the exercise of control (WH Freeman, New
York, 1997)]. But how good really is our
ability to control? How successful is our track record in these areas? There
is little understanding of when and under what circumstances we may
over-estimate [E. Langer, J. Pers. Soc. Psych. 7, 185 (1975)] or even lose our ability to control and optimize outcomes,
especially when they are the result of aggregations of individual
optimization processes. Here, we demonstrate analytically using the theory
of Markov Chains and by numerical simulations in two classes of games, the
Time-Horizon Minority Game [M.L. Hart, P. Jefferies, N.F. Johnson, Phys. A 311, 275 (2002)] and the Parrondo Game
[J.M.R. Parrondo, G.P. Harmer, D. Abbott, Phys. Rev. Lett.
85, 5226 (2000); J.M.R. Parrondo, How to cheat a bad mathematician (ISI, Italy, 1996)], that agents
who optimize their strategy based on past information may actually perform
worse than non-optimizing agents. In other words, low-entropy (more
informative) strategies under-perform high-entropy (or random) strategies.
This provides a precise definition of the “illusion of control” in certain
set-ups a priori defined to emphasize the importance of optimization.
An erratum to this article is available at . 相似文献
125.
The topology of interbank payment flows 总被引:1,自引:0,他引:1
We explore the network topology of the interbank payments transferred between commercial banks over the Fedwire® Funds Service. We find that the network has both a low average path length and low connectivity. The network includes a tightly connected core of banks to which most other banks connect. The degree distribution is scale free over a substantial range. We find that the properties of the network changed considerably in the immediate aftermath of the events of September 11, 2001. 相似文献
126.
127.
The susceptible-infected-susceptible (SIS) epidemics in a scale-free network in which each node is a square lattice itself is investigated through large-scale computer simulations. The model combines a local contact process among individuals in a node (or city) with stochastic long-range infections due to people traveling between cities interconnected by the national transportation scale-free network. A nonzero epidemic threshold is found and it is approached with a power-law behavior by the density of infected individuals, as observed in the small-world network of Watts and Strogatz. Also, the epidemic propagation follows a 1/f, hierarchical dynamics from the highly connected square lattices to the smaller degree nodes in outbreaks with sizes distributed accordingly a Gaussian function. 相似文献
128.
We study complex Lagrangian submanifolds of a compact hyper-Kähler manifold and prove two results: (a) that an involution of a hyper-Kähler manifold which is antiholomorphic with respect to one complex structure and which acts non-trivially on the corresponding symplectic form always has a fixed point locus which is complex Lagrangian with respect to one of the other complex structures, and (b) there exist Lagrangian submanifolds which are complex with respect to one complex structure and are not the fixed point locus of any involution which is anti-holomorphic with respect to one of the other complex structures. 相似文献
129.
We give a complete classification of Lagrangian immersions of homogeneous 3-manifolds (the Berger spheres, the Heisenberg group , the universal covering of the Lie group and the Lie group ) in 3-dimensional complex space forms. As a corollary, we get a new characterization of the Berger sphere in complex projective space. 相似文献
130.