松花粉中胆碱的提取及测定研究

探讨了松花粉中胆碱提取条件,用雷纳克铵盐分光光度法在波长526nm处测定了松花粉中胆碱含量,胆碱在0-0.5mg·mL-1范围内线性关系良好,方法稳定、可靠.     

Microstructures of Choline Amino Acid based Biocompatible Ionic Liquids

Bio-compatible ionic liquids (Bio-ILs) represent a class of solvents with peculiar properties and exhibit huge potential for their applications in different fields of chemistry. Ever since they were discovered, researchers have used bio-ILs in diverse fields such as biomass dissolution, CO₂ sequestration, and biodegradation of pesticides. This review highlights the ongoing research studies focused on elucidating the microscopic structure of bio-ILs based on cholinium cation ([Ch]⁺) and amino acid ([AA]⁻) anions using the state-of-the-art and classical molecular dynamics (MD) simulations. The microscopic structure associated with these green ILs guides their suitability for specific applications. ILs of this class differ in the side chain of the amino acid anions, and varying the side chain significantly affects the structure of these ILs and thus helps in tuning the efficiency of biomass dissolution. This review demonstrates the central role of the side chain on the morphology of choline amino acid ([Ch][AA]) bio-ILs. The seemingly matured field of bio-ILs and their employment in various applications still holds significant potential, and the insights on their microscopic structure would steer the field of target specific application of these green ILs.