LSI用环氧塑封料研制与中试

本文叙述了ＬＳＩ用环氧塑封料研究与中试的主要成果、技术要点及成果应用。     

A charge-transfer host system composed of a chiral 1,1′-bi-2-naphthol cluster and benzylviologen

Chiral charge-transfer (CT) complexes composed of a chiral 1,1′-bi-2-naphthol cluster as the electron donor and 1,1′-dibenzyl-4,4′-bipyridinium dichloride as the electron acceptor serve as a host system for molecular recognition. CT complexes that include guest alcohols show different diffuse reflectance spectra (DRS) depending on the included guest.     

Langevin study of neutron emission in the reactions 16O+181Ta and 19F+178Hf

The pre-scission neutrons measured in the reactions 16O+181Ta and 19F+178Hf are studied via a Langevin equation coupled with a statistical decay model.We find that because of the mass asymmetry of different entrance channels,the spin distributions of compound nuclei would be different,consequently,the measured neutrons in these two reactions would also different.This means that the entrance channel will affect the particle emission in the fission process of hot nuclei.     

Studies on Enantioselective Effect of Chiral Titanate Reagents on the Synthesis of Substituted Benzhydrols

Chiral titanate reagents were prepared for inducing asymmetric syntheses of substituted benzhydrols from Grignard reagents and aldehydes. The solvents, reaction temperature and exchange of reactants by crossing experiments were investigated. Favorable attack of the nucleophile upon the aromatic aldehydes' prochiral face was proposed, the absolute configurations of the synthesized benzhydrols were suggested, and a preliminary reaction mechanism was described.     

Three limit theorems for vacancy in multivariate coverage problems

Three limit theorems describing asymptotic distribution of vacancy in general multivariate coverage problems are proved, in which nk-dimensional spheres are distributed within a k-dimensional unit cube according to a density f. The first result (a central limit theorem) describes the case where the proportion of vacancy converges to a fixed constant lying between 0 and 1. The last two results treat the case where the proportion of vacancy tends to 1 as n → ∞. Results of this nature have hitherto been available only for restricted k and/or for f equal to the uniform density.     

Convexity properties,moment inequalities and asymptotic exponential approximations for delay distributions in G1/G/1 systems

Pollaczek distributions pervade the class of delay distibutions in G1/G/1 systems with concave service time distributions. When the service time distribution has finite support and the delay distribution is absolutely continuous on (0, ∞), one can find a distribution with a pure exponential tail that satisfies the corresponding Wiener-Hopf integral equation except for values of the argument that belong to the support in question or to a translate thereof. Again for an exponentially decaying delay distribution, one can formulate sufficient moment inequalities which ensure the existence of asymptotic upper and lower bounds derived from M/D/1 and M/M/1 delay distributions which agree with the former in terms of the first two moments.     

Thermodynamic properties of the SU(2)f chiral quark–loop soliton

We consider a chiral one-loop hedgehog soliton of the bosonized SU(2)_f Nambu & Jona-Lasinio model which is embedded in a hot medium of constituent quarks. Energy and radius of the soliton are determined in self-consistent mean-field approximation. Quasi-classical corrections to the soliton energy are derived by means of the pushing and cranking approaches. The corresponding inertial parameters are evaluated. It is shown that the inertial mass is equivalent to the total internal energy of the soliton. Corrected nucleon and δ isobar masses are calculated in dependence on temperature and density of the medium. As a result of the self-consistently determined internal structure of the soliton the scaling between constituent quark mass, soliton mass and radius is noticeably disturbed. Received: 26 September 1997     

Solid state reactions of nitrogenous heterocyclic compounds (II)

Solid state Michael addition reaction of indole with α, β-unsaturated carbonyl compounds was carried out, by which a series of compounds containing three different heterocyclic groups binding to one carbon atom were ob-tained. In the presence of Lewis acid, indole could undergo the solid state condensation reaction with aromatic ketones and aldehydes or quinones. The solid state reaction showed higher selectivity and yield than solution reaction. The structures of products were identified by IR,¹H NMR, MS. elemental analysis and X-ray crystal analysis. The reac-tion mechanism was also proposed. Project supported by the National Natural Science Foundation of China