全文获取类型
收费全文 | 3926篇 |
免费 | 955篇 |
国内免费 | 597篇 |
专业分类
化学 | 3958篇 |
晶体学 | 66篇 |
力学 | 78篇 |
综合类 | 31篇 |
数学 | 600篇 |
物理学 | 745篇 |
出版年
2024年 | 3篇 |
2023年 | 52篇 |
2022年 | 67篇 |
2021年 | 73篇 |
2020年 | 89篇 |
2019年 | 102篇 |
2018年 | 71篇 |
2017年 | 104篇 |
2016年 | 128篇 |
2015年 | 421篇 |
2014年 | 459篇 |
2013年 | 195篇 |
2012年 | 200篇 |
2011年 | 267篇 |
2010年 | 214篇 |
2009年 | 326篇 |
2008年 | 304篇 |
2007年 | 269篇 |
2006年 | 264篇 |
2005年 | 203篇 |
2004年 | 245篇 |
2003年 | 204篇 |
2002年 | 161篇 |
2001年 | 120篇 |
2000年 | 103篇 |
1999年 | 86篇 |
1998年 | 81篇 |
1997年 | 96篇 |
1996年 | 87篇 |
1995年 | 94篇 |
1994年 | 76篇 |
1993年 | 54篇 |
1992年 | 43篇 |
1991年 | 36篇 |
1990年 | 34篇 |
1989年 | 22篇 |
1988年 | 14篇 |
1987年 | 11篇 |
1986年 | 15篇 |
1985年 | 8篇 |
1984年 | 9篇 |
1983年 | 4篇 |
1982年 | 5篇 |
1981年 | 6篇 |
1980年 | 15篇 |
1979年 | 10篇 |
1978年 | 10篇 |
1977年 | 9篇 |
1975年 | 3篇 |
1974年 | 3篇 |
排序方式: 共有5478条查询结果,搜索用时 78 毫秒
51.
Microcolumns containing 8-hydroxyquinoline azo-immobilized on controlled pore glass were incorporated in a field sampler for on-site collection, isolation and preconcentration of trace metal ions in waters of the Okavango Delta, Botswana. Sequestered trace metal ions were recovered by elution with 0.5 ml of 1.5 M nitric acid, and determined by graphite furnace atomic absorption spectrometry (GFAAS). This sampling and enrichment method minimizes sample contamination, and collection of large volumes of water samples for transporting, over long distances, to analytical laboratories is avoided.Data reported comprise one of the initial surveys on trace metal ion concentrations in waters of the Okavango Delta, Botswana. In waters with more efficient mixing, dissolved metal ion concentrations found were generally low with slightly elevated levels of manganese (7-19 μg l−1), zinc (2.7-4.8 μg l−1), nickel (0.2-2.5 μg l−1) and copper (0.3-2.1 μg l−1). For each trace metal ion, concentration levels seem to reflect zones of varying water conveyance, and show no obvious temporal and spatial variations apart from a slight increment from the inlet in the upper Delta to the outlets in the lower Delta. 相似文献
52.
核酸-8-羟基喹啉-钪(Ⅲ)体系的荧光特性及其分析应用 总被引:7,自引:0,他引:7
在PH 6.8~8.8的酸度范围内,小牛胸腺脱氧核糖核酸(ctDNA),鱼精子脱氧核糖 核酸(fsDNA)以及酵母核糖核酸(yRNA)分别与8-羟基喹啉(8-HQL)和Sc(Ⅲ)形成的三元 体系受 264~270 nm紫外光激发将发出 490~496 nm的荧光。与 Sc(Ⅲ)和 8-HQL 二元络合 物相比,三元体系的荧光量子产率增大,荧光寿命增长,最大发射波长紫移约 10 nm。6个合 成样品的分析结果表明,利用 Sc(Ⅲ)/8-HQL能十分灵敏的测定脱氧核糖核酸。 相似文献
53.
Composite membranes were prepared by (a) infiltrating NAFION with SiO2-P2O5-ZrO2 sol, and (b) recasting a film using NAFION solution containing SiO2-P2O5-ZrO2 sol. The membranes were characterized by Differential Thermal Analysis and ac-impedance spectroscopy as a function of relative humidity. The influences of the heat treatment (80°C–150°C) and cleaning on the electrical properties were investigated. The incorporation of SiO2-P2O5-ZrO2 gels into NAFION lead to improvements in its thermal stability and proton conductivity. 相似文献
54.
55.
56.
Host-guest complexes of cucubit[8]uril with phenanthrolines and some methyl derivatives 总被引:1,自引:0,他引:1
DAY Anthony I 《中国科学B辑(英文版)》2005,48(4):305-314
Cucurbituril a molecular container (or host) has a rigid hollow interior cavity which is large enough to accommodate, one or more, smaller molecules (or guests). The cavity is accessible through two carbonyl portal openings. Molecules or guests enter the … 相似文献
57.
58.
Ab initio calculations on vinyldifluoroborane yield a -contribution of 23 kJ/mol (5.5 kcal/mol) mainly due to the C=C bond and not to the lone pairs of the fluorine atoms. The rotational barrier was also determined. The force field calculations favour the interpretation of the bond structure derived from the theab initio results. 相似文献
59.
以4-甲基苯磺酸作催化剂、用三乙胺调节pH值约为9的条件下, 由5-甲酰基-8-羟基喹啉和5-氨基-8-羟基喹啉合成了新的5,7′-(亚甲胺基)-二-8-羟基喹啉, 利用IR, UV, 1H NMR, MS确认了分子结构, 比较研究了其光致发光特性, 运用Gaussian 98量子化学程序包, 采用B3LYP密度泛函(DFT)的方法, 在6-31G(d,p)水平上对分子的几何构型进行结构优化; 并对目标化合物的稳定结构通过计算预测其振动光谱, 计算结果与实验值基本相符. 相似文献
60.
Aggregated aromatic molecule--cyclodextrin-precipitant complexes exhibit long-lived phosphorescence at room temperature in water after the chemical binding of oxygen. The temperature dependences of the phosphorescence lifetimes of naphthalene-h8, naphthalene-de, and phenanthrene in the aggregates were measured. For example, the phosphorescence lifetimes of naphthalene-d8 aggregated with -cyclodextrin and cyclohexane are equal to 25.1, 17.6, and 6.8 s at 77, 276, and 347 K, respectively, and that of phenanthrene aggregated with isooctane and -cyclodextrin are 3.24, 3.06, and 1.26 s at 268, 274, and 335 K, respectively. The temperature dependences of the phosphorescence lifetimes at room temperature are determined by the rate constants of the radiative and nonradiative transitions from the triplet state of an aromatic molecule.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2225–2228, September, 1996. 相似文献