Phase behaviors of ionic liquids attributed to the dual ionic and organic nature

Ionic liquids (ILs), also known as room-temperature molten salts, are solely composed of ions with melting points usually below 100 °C. Because of their low volatility and vast amounts of species, ILs can serve as ‘green solvents' and ‘designer solvents' to meet the requirements of various applications by fine-tuning their molecular structures. A good understanding of the phase behaviors of ILs is certainly fundamentally important in terms of their wide applications. This review intends to summarize the major conclusions so far drawn on phase behaviors of ILs by computational, theoretical, and experimental studies, illustrating the intrinsic relationship between their dual ionic and organic nature and the crystalline phases, nanoscale segregation liquid phase, IL crystal phases, as well as phase behaviors of their mixture with small organic molecules.     

Stress gradient versus strain gradient constitutive models within elasticity

A stress gradient elasticity theory is developed which is based on the Eringen method to address nonlocal elasticity by means of differential equations. By suitable thermodynamics arguments (involving the free enthalpy instead of the free internal energy), the restrictions on the related constitutive equations are determined, which include the well-known Eringen stress gradient constitutive equations, as well as the associated (so far uncertain) boundary conditions. The proposed theory exhibits complementary characters with respect to the analogous strain gradient elasticity theory. The associated boundary-value problem is shown to admit a unique solution characterized by a Hellinger–Reissner type variational principle. The main differences between the Eringen stress gradient model and the concomitant Aifantis strain gradient model are pointed out. A rigorous formulation of the stress gradient Euler–Bernoulli beam is provided; the response of this beam model is discussed as for its sensitivity to the stress gradient effects and compared with the analogous strain gradient beam model.     

Semi-permeable crack analysis in a 2D magnetoelectroelastic medium based on the EMPS model

For a crack in a magnetoelectroelastic plane under the electrically and magnetically semi-permeable boundary condition, we derive the non-linear analytical solution of the strip electric–magnetic polarization saturation (EMPS) model. Using the extended dislocation theory and integral equation method, we obtain the electric and magnetic yielding zones, as well as the field intensity factor and local J-integral. Adapting an iterative method, numerical examples were performed to analyze the effect of different boundary conditions and the electric–magnetic saturated properties on the electric displacement and magnetic induction in the crack cavity, electric and magnetic yielding zones, stress intensity factor and local J-integral.     

Vibrational analysis of carbon nanocones under different boundary conditions: An analytical approach

The purpose of this study is to analytically investigate the free vibration of carbon nanocones (CNCs) under different types of boundary conditions. The Donnell shell theory and nonlocal elasticity are used to derive the governing equations of motion. The analytical Galerkin method together with beam mode shapes as weighting functions is employed to solve the problem. Making use of the beam modal functions enables us to examine the role of boundary condition in the vibrational behavior of CNCs. The effects of boundary conditions, semivertex angle and nonlocal parameter on the response of CNCs are explored.     

Boundary integral equations for 2D elasticity and its application in discrete dislocation dynamics simulation in finite body: 1. General theory

A unified approach, originating from Cauchy integral theorem, is presented to derive boundary integral equations for two dimensional elasticity problems. Several sets of boundary integral equations are derived and their relations are revealed. Explicit expressions for materials with different symmetry planes are listed. Special attention is given to the formulation that is based on the tractions and the tangential derivatives of displacements along solid boundary, since its integral kernels have the weakest singularities. The formulation is further extended to include singular points, such as dislocations and line forces, in a finite body, so that the singular stress field can be directly obtained from solving the integral equations on the external boundary, without involving the linear superposition technique that was often used in the literature. Its application in simulating discrete dislocation motion in a finite solid body is discussed.     

An enhanced treatment of boundary conditions in implicit smoothed particle hydrodynamics简

In this work, an enhanced treatment of the solid boundaries is proposed for smoothed particle hydrodynamics with implicit time integration scheme （Implicit SPH）. Three types of virtual particles, i.e., boundary particles, image particles and mirror particles, are used to impose boundary conditions. Boundary particles are fixed on the solid boundary, and each boundary particle is associated with two fixed image particles inside the fluid domain and two fixed mirror particles outside the fluid domain. The image particles take the flow properties through fluid particles with moving least squares （MLS） interpolation and the properties of mirror particles can be obtained by the corresponding image particles. A repulsive force is also applied for boundary particles to prevent fluid particles from unphysical penetra- tion through solid boundaries. The new boundary treatment method has been validated with five numerical examples. All the numerical results show that Implicit SPH with this new boundary-treatment method can obtain accurate results for non-Newtonian fluids as well as Newtonian fluids, and this method is suitable for complex solid boundaries and can be easily extended to 3D problems.     

Singularities of Bernoulli Free Boundaries

In this article we show that, for a large class of Bernoulli problems, a free boundary which is symmetric with respect to a vertical line through an isolated singular point must necessarily have a corner at that point, and we give a formula for the contained angle. The assumptions used admit the possibility of other singular points, even uncountably many, on the free boundary. This result is an extension of the first Stokes conjecture in the theory of hydrodynamic waves. We also show that, even in the presence of singularities, a geometrically simple Bernoulli free boundary is necessarily symmetric.     

Remarks on Boundary Layer Expansions

A systematic mathematical methodology for derivation of boundary layer expansions is presented. An explicit calculation of boundary layer sizes is given and proved to be coordinates system independent. It relies on asymptotic properties of symbols of operators. Several examples, including the quasigeostrophic model, are discussed.