全文获取类型
收费全文 | 5629篇 |
免费 | 454篇 |
国内免费 | 617篇 |
专业分类
化学 | 3488篇 |
晶体学 | 60篇 |
力学 | 44篇 |
综合类 | 8篇 |
数学 | 122篇 |
物理学 | 2978篇 |
出版年
2024年 | 10篇 |
2023年 | 66篇 |
2022年 | 66篇 |
2021年 | 75篇 |
2020年 | 154篇 |
2019年 | 119篇 |
2018年 | 87篇 |
2017年 | 105篇 |
2016年 | 151篇 |
2015年 | 132篇 |
2014年 | 159篇 |
2013年 | 329篇 |
2012年 | 313篇 |
2011年 | 325篇 |
2010年 | 282篇 |
2009年 | 362篇 |
2008年 | 324篇 |
2007年 | 475篇 |
2006年 | 347篇 |
2005年 | 240篇 |
2004年 | 271篇 |
2003年 | 289篇 |
2002年 | 232篇 |
2001年 | 275篇 |
2000年 | 213篇 |
1999年 | 203篇 |
1998年 | 156篇 |
1997年 | 165篇 |
1996年 | 129篇 |
1995年 | 125篇 |
1994年 | 92篇 |
1993年 | 87篇 |
1992年 | 65篇 |
1991年 | 72篇 |
1990年 | 44篇 |
1989年 | 23篇 |
1988年 | 19篇 |
1987年 | 9篇 |
1986年 | 8篇 |
1985年 | 11篇 |
1984年 | 11篇 |
1983年 | 9篇 |
1982年 | 12篇 |
1981年 | 6篇 |
1980年 | 6篇 |
1979年 | 7篇 |
1978年 | 10篇 |
1977年 | 5篇 |
1974年 | 4篇 |
1973年 | 8篇 |
排序方式: 共有6700条查询结果,搜索用时 93 毫秒
61.
62.
S. F. Chekmarev R. Mitri V. Bonaci-Koutecký 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,24(1-3):45-48
The ab initio molecular
dynamics (AIMD) [1] is combined with the heuristic, successive
confinement method of surveying a potential energy surface (PES)
[2], thereby offering a framework for the simulation study of
kinetics and equilibrium properties of metallic clusters. This
approach is applied to the study of Au4,
a cluster possessing a simple but specific PES, which consists
of very shallow and deep basins and due to this presents a
challenge to the conventional AIMD methods. Among other things,
the probabilities of the transitions between isomers have been
found, and on this basis, both the time-dependent and
equilibrium populations of the isomers have been calculated for
the conditions typical of the NeNePo experiments [3] in the
femtosecond pump-probe spectroscopy. 相似文献
63.
Scanning probe microscopy characterization of gold-chemisorbed poplar plastocyanin mutants 总被引:1,自引:0,他引:1
L. Andolfi B. Bonanni G. W. Canters M. Ph. Verbeet S. Cannistraro 《Surface science》2003,530(3):181-194
Two poplar plastocyanin mutants adsorbed onto gold electrodes have been characterized at single molecule level by scanning probe microscopy. Immobilization of the two redox metalloprotein mutants on Au(1 1 1) surface was achieved by either a disulphide bridge (PCSS) or a single thiol (PCSH), both the anchoring groups having been introduced by site-directed mutagenesis. Scanning tunneling microscopy (STM) and atomic force microscopy (AFM) analysis gives evidence of a stable and robust binding of both mutants to gold. The lateral dimensions, as estimated by STM, and the height above the gold substrate, as evaluated by AFM, of the two mutants well agree with crystallographic sizes. A narrower height distribution is observed for PCSS compared to PCSH, corresponding to a more homogeneous orientation of the former mutant adsorbed onto gold. Major differences between the mutants are observed by electrochemical STM. In particular, the image contrast of adsorbed PCSS is affected by tuning the external electrochemical potential to the redox levels of the mutant, consistent with some involvement of copper active site in the tunneling process. On the contrary, no contrast variation is observed in electrochemical STM of adsorbed PCSH. Moreover, scanning tunneling spectroscopy experiments reveal asymmetric I–V characteristics for single PCSS proteins, reminiscent of a rectifying-like behaviour, whereas an almost symmetric I–V relation is observed for PCSH. 相似文献
64.
Conventionally, surface roughness is predominantly determined through the use of stylus instruments. However, there are certain limitations involved in the method, particularly when a test specimen, such as a silicon wafer, has a smooth mirror-like surface. Hence, it is necessary to explore alternative non-contact techniques. Light scattering has recently been gaining popularity as an optical technique to provide prompt and precise inspection of surface roughness. In this paper, the total integrated scattering (TIS) model is modified to retrieve parameters on surface micro-topography through light scattering. The applicability of the proposed modified TIS model is studied and compared with an atomic force microscope. Experimental results obtained show that the proposed technique is highly accurate for measuring surface roughness in the nanometer range. 相似文献
65.
Michaël Lejeune Andrea Valsesia Martin Kormunda Pascal Colpo François Rossi 《Surface science》2005,583(1):L142
In this work, chemically and topographically nanopatterned surfaces were produced by a top-down processing approach for biosensing devices. The nanopatterning was the result of the combination of plasma polymerisation (pp) of biofunctional materials and colloidal lithography techniques. The morphological and chemical properties induced by the plasma deposition-etching treatment were characterised by optical method combining ellipsometry and Fourier Transform Infrared spectroscopy studies. This method supported by atomic force microscopy measurements, allowed the full optical characterization of each step of the top-down process. The optical characterization of the end-up nanopatterned samples demonstrated that the chosen process is able to produce well-defined nanostructured surfaces with controlled chemical and morphological properties. 相似文献
66.
67.
Banach frames and atomic decompositions are sequences that have basis-like properties but which need not be bases. In particular, they allow elements of a Banach space to be written as linear combinations of the frame or atomic decomposition elements in a stable manner. In this paper we prove several functional — analytic properties of these decompositions, and show how these properties apply to Gabor and wavelet systems. We first prove that frames and atomic decompositions are stable under small perturbations. This is inspired by corresponding classical perturbation results for bases, including the Paley — Wiener basis stability criteria and the perturbation theorem el kato. We introduce new and weaker conditions which ensure the desired stability. We then prove quality properties of atomic decompositions and consider some consequences for Hilbert frames. Finally, we demonstrate how our results apply in the practical case of Gabor systems in weighted L2 spaces. Such systems can form atomic decompositions for L2w(IR), but cannot form Hilbert frames but L2w(IR) unless the weight is trivial. 相似文献
68.
D.A. Mazón-Montijo M. Quevedo-López H.N. Alshareef R. Ramírez-Bon 《Applied Surface Science》2007,254(2):499-505
We study the initial growth stages of CdS thin films deposited by an ammonia-free chemical bath deposition process. This ammonia-free process is more environmentally benign because it reduces potential ammonia release to the environment due to its high volatility. Instead of ammonia, sodium citrate was used as the complexing agent. We used atomic force microscopy (AFM), Rutherford backscattering (RBS) and X-ray photoelectron spectroscopy (XPS) to investigate the morphological and chemical modifications at the substrate surface during the first initial stages of the CdS deposition process. Additionally, X-ray diffraction (XRD) and optical transmission spectroscopy measurements were carried out to compliment the study. XPS results show that the first nucleation centers are composed by Cd(OH)2 which agglomerate in patterns of bands, as demonstrated by AFM results. It is also observed that the conversion to CdS (by anionic exchange) of the first nucleus begins before the substrate surface is completely covered by a homogenous film. 相似文献
69.
The Lombardo–Imbihl–Fink (LFI) ODE model of the NO+NH3 reaction on a Pt(1 0 0) surface shows stable relaxation oscillations with very sharp transitions for temperatures T between 404 and 433 K. Here we study numerically the effect of linear diffusive coupling of these oscillators in one spatial dimension. Depending on the parameters and initial conditions we find a rich variety of spatio-temporal patterns which we group into four main regimes: bulk oscillations (BOs), standing waves (SW), phase clusters (PC), and phase waves (PW). Two key ingredients for SW and PC are identified, namely the relaxation type of the ODE oscillations and a nonlocal (and nonglobal) coupling due to relatively fast diffusion of the kinetically slaved variables NH3 and H. In particular, the latter replaces the global coupling through the gas phase used to obtain SW and PC in models of related surface reactions. The PW exist only under the assumption of (relatively) slow diffusion of NH3 and H. 相似文献
70.