海冰动力学数值模拟中改进的PIC方法

为了准确地模拟海冰的动力过程,需要建立精确有效的数值方法。本文结合质点网格法(PIC)和光滑质点流体动力学方法(SPH)发展了一种改进的PIC方法。该方法在欧拉坐标下对海冰动量方程进行差分计算,在拉格朗日坐标下进行海冰质点位移、厚度和密集度计算,并采用Gauss函数进行欧拉网格点与拉格朗日质点间海冰参数的交互插值。采用改进的PIC方法对规则区域内的海冰堆积过程进行了数值试验,对渤海海冰的动力过程进行了72小时数值模拟。计算结果均表明改进的PIC方法具有计算量小,计算结果平稳精确的优点,可很好地适用于海冰动力作用过程的数值模拟。     

An on-line solid phase extraction-liquid chromatography tandem mass spectrometry method for the determination of perfluoroalkyl substances in the Antarctic ice core samples

An on-line solid phase extraction-high performance liquid chromatography-tandemmass spectrometry method for the analysis of perfluoroalkyl substances (PFASs) in water samples was developed. The optimal analytical conditions were obtained through the optimization of the extraction efficiency of online solid phase extraction column, sample loading rate and loading volume, and the concentration of ammonium acetate in mobile phase. Under the optimal condition, the analytical method displayed good linearity (r² > 0.99) for 12 PFASs (C5-C14 perfluoroalkyl carboxylic acids and C6/C8 perfluoroalkyl sulfonic acids) over a concentration range of 0.5-100 ng/L. The limits of quantitation for samples were between 0.025 ng/L and 0.5 ng/L and the relative standard deviations (RSD) of five consecutive analyses were less than 10% for 1 ng/L standard solution. Satisfactory results were obtained using this analytical method for the analysis of perfluoroalkyl substances in Antarctic ice core samples. The recoveries of all perfluoroalkyl substances were in a range of 73%-117% when the sampleswere spiked with standards at the concentrations of 2.5 ng/L and 25 ng/L.     

Micro‐ and Nano‐Liquid Phases Coexistent with Ice as Separation and Reaction Media.

Ice has a variety of scientifically interesting features, some of which have not been reasonably interpreted despite substantial efforts by researchers. Most chemical studies of ice have focused on the elucidation of its physicochemical nature and its roles in the natural environment. Ice often contains impurities, such as salts, and in such cases, a liquid phase coexists with solid ice over a wide temperature range. This impure ice also acts as a cryoreactor, governing the circulation of chemical species of environmental importance. Reactions and phenomena occurring in this liquid phase show features different from those seen in normal bulk aqueous solutions. In the present account, we discuss the chemical characteristics of the liquid phase that develops in a frozen aqueous phase and show how novel analytical systems can be designed based on he features of the liquid phase which are predictable in some cases but unpredictable in others.     

Variation in the wave resistance of an amphibian air-cushion vehicle moving over a broken-ice field

The nonstationary rectilinear motion of an amphibian air-cushion vehicle (AACV) on a water surface covered with finely broken ice is considered for various modes of velocity variation. The influence of the water depth, flotation parameters, and mode of motion on the wave resistance of the vehicle is analyzed. Maneuvering methods for increasing or decreasing the wave resistance of AACVs are proposed. __________ Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 48, No. 1, pp. 97–102, January–February, 2007.     

Mathematical Modeling for One New Method of Breaking Ice Cover

The spatial problem of determining the stress-strain state of an ice plate of finite thickness broken by a patented method is solved using the theory of small elastoplastic strains and a proven numerical method. __________ Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 47, No. 2, pp. 139–146, March–April, 2006.     

斜面结构冰荷载的动荷效应

利用改进的刚性梁模型进行了斜面结构冰荷载的动荷效应，推导了冰力的动荷系统，算例得到了与模型试验值和数值解相近的结果，依据分析对试验观察到的规律给出了理论上的证明和定性的解释，给出了准静态冰力条件的判别式。     

Motion of a system of seismic sources over ice on a body of water under the action of a pulse

The vertical motion of a system of two identical seismic sources and a spring truck tractor on ice under the action of a shock pulse from the seismic sources is studied to estimate the strength of ice. It is shown that during the pulse time, the interaction of the masses of the seismic sources and the tractor is small and the compressibility effect of the liquid can be ignored. Calculations show that for the seismic sources, the dynamic load far exceeds the static load and for the tractor, the static load is maximal. __________ Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 48, No. 2, pp. 147–155, March–April, 2007.     

Role of nonlocal exchange in molecular crystals: The case of two proton‐ordered phases of ice

We present a periodic density functional theory investigation of twoproton‐ordered phases of ice. Their equilibrium lattice parameters,relative stabilities, formation energies, and densities of states havebeen evaluated. Nine exchange‐correlation functionals, representativeof the generalized gradient approximation (GGA), global hybrids,range‐separated hybrids, meta‐GGA, and hybrid meta‐GGA families havebeen taken into account, considering two oxygen basis sets. Althoughthe hydrogen‐bond network of ice is well reproduced at the B3LYP,M06‐L, or LC‐ wPBE levels, formation energies are only correctlyevaluated with the two former functionals. Band gaps on the other handare only quantitatively reproduced at the B3LYP level. These resultsindicate that this last functional, a de facto reference formolecular calculations, gives in average the most accurate results forthe considered ice properties. © 2011 Wiley Periodicals, Inc. J Comput Chem, 2011     

The superhydrophobicity of polymer surfaces: Recent developments

Superhydrophobicity is the extreme water repellence of highly textured surfaces. The field of superhydrophobicity research has reached a stage where huge numbers of candidate treatments have been proposed and jumps have been made in theoretically describing them. There now seems to be a move to more practical concerns and to considering the demands of individual applications instead of more general cases. With these developments, polymeric surfaces with their huge variety of properties have come to the fore and are fast becoming the material of choice for designing, developing, and producing superhydrophobic surfaces. © 2011 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 49: 1203–1217, 2011