全文获取类型
收费全文 | 11992篇 |
免费 | 1384篇 |
国内免费 | 1068篇 |
专业分类
化学 | 8787篇 |
晶体学 | 216篇 |
力学 | 237篇 |
综合类 | 64篇 |
数学 | 2825篇 |
物理学 | 2315篇 |
出版年
2023年 | 86篇 |
2022年 | 110篇 |
2021年 | 170篇 |
2020年 | 256篇 |
2019年 | 290篇 |
2018年 | 249篇 |
2017年 | 285篇 |
2016年 | 309篇 |
2015年 | 570篇 |
2014年 | 671篇 |
2013年 | 538篇 |
2012年 | 505篇 |
2011年 | 643篇 |
2010年 | 501篇 |
2009年 | 799篇 |
2008年 | 692篇 |
2007年 | 702篇 |
2006年 | 625篇 |
2005年 | 597篇 |
2004年 | 742篇 |
2003年 | 649篇 |
2002年 | 582篇 |
2001年 | 430篇 |
2000年 | 374篇 |
1999年 | 297篇 |
1998年 | 244篇 |
1997年 | 255篇 |
1996年 | 274篇 |
1995年 | 238篇 |
1994年 | 269篇 |
1993年 | 206篇 |
1992年 | 177篇 |
1991年 | 120篇 |
1990年 | 92篇 |
1989年 | 83篇 |
1988年 | 66篇 |
1987年 | 82篇 |
1986年 | 71篇 |
1985年 | 62篇 |
1984年 | 54篇 |
1983年 | 16篇 |
1982年 | 44篇 |
1981年 | 55篇 |
1980年 | 62篇 |
1979年 | 75篇 |
1978年 | 60篇 |
1977年 | 60篇 |
1976年 | 42篇 |
1974年 | 18篇 |
1973年 | 19篇 |
排序方式: 共有10000条查询结果,搜索用时 328 毫秒
61.
62.
The Newton filtration and d-determination of bifurcation problems related to C~0 contact equivalence
SU Dan & ZHANG Dunmu School of Mathematics Statistics Wuhan University Wuhan China 《中国科学A辑(英文版)》2006,49(5)
In this paper, from the Newton filtration's point of view, we construct the singular Riemannian metric and use the method in singular theory to study the bifurcation problems, and give the sufficient condition of d-determination of bifurcation problems with respect to C0 contact equivalence. The special cases of the main result in this paper are the results of Sun Weizhi and Zou Jiancheng. 相似文献
63.
Koichi Itoh Takeji Takui 《Proceedings of the Japan Academy. Series B, Physical and biological sciences》2004,80(2):29
This review paper deals with an overview of molecule-based magnetism as a rapidly developing interdisciplinary field, topological symmetry rule as the first principle of spin alignment in organic open-shell systems in the ground state, the proposal of organic through-bond 1D and 2D ferro- and superparamagnets and the detection of the first organic high-spin molecule, m-phenylenebis(phenylmethylene) in the quintet ground state (S = 2), followed by extended organic high-spin systems with π-conjugation such as aromatic hydrocarbons having S = 3, 4, 5. The paper also describes a theoretical approach to the understanding of electronic spin structures of organic high-spin molecules by invoking both Heisenberg and Hubbard model Hamiltonians, weakly interacting intramolecular high-spin systems from both experimental and theoretical sides, the spin density distribution of the first organic high-spin molecule in terms of electron- nuclear multiple resonance spectroscopy and the detection and characterization of ionic high-spin hydrocarbons, emphasizing the establishment of high spin chemistry underlying organic molecular magnetism. 相似文献
64.
The Gaussian property of the Brownian bridge is characterized as an application of Ramachandran's theorem in terms of the independence of the random variables that appear in the Karhunen-Loéve expansion of the process. A reference about the construction of the Brownian bridge by means of functional transformations is also included. 相似文献
65.
P. Macko D. Romanini O.V. Naumenko A. Jenouvrier A. Campargue 《Journal of Molecular Spectroscopy》2004,227(1):90-108
The absorption spectrum of natural water vapour around 1.5 μm has been recorded with a typical sensitivity of 5 × 10−10 cm−1 by using a CW-cavity ring down spectroscopy set up based on fibred DFB lasers. A series of 31 DFB lasers has allowed a full coverage of the 6130.8-6748.5 cm−1 (1.63-1.48 μm) region corresponding to the H transparency band of the atmosphere. The line parameters (wavenumber and intensity) of a total of 5190 lines, including 4247 lines of water vapor, were derived by a one by one fit of the lines to a Voigt profile. Different isotopologues of water (H216O, H218O, H217O, and HD16O) present in natural abundance in the sample contribute to the spectrum. For the main isotopologue, H216O, 2130 lines were measured with line intensities as weak as 10−29 cm/molecule while only 926 lines (including a proportion of 30% inaccurate calculated lines) with a minimum intensity of 3 × 10−27 cm/molecule are provided by the HITRAN and GEISA databases. Our comparison in the whole 5750-7965 cm−1 region, has also evidenced that an error in the process of conversion of the intensity units from cm−2/atm to cm−1/(molecule × cm−2) at 296 K, has led to H216O line intensities values listed in the HITRAN-2000 database, systematically 8 % below the original FTS values. The rovibrational assignment was performed on the basis of the ab initio calculations by Schwenke and Partridge with a subsequent refinement and validation using the Ritz combination principle together with all previously measured water transitions relevant to this study. This procedure allowed determining 172, 139, 71, and 115 new energy levels for the H216O, H218O, H217O, and HD16O isotopologues, respectively. The results are compared with the available databases and discussed in regard of previous investigations by Fourier transform spectroscopy. The spectrum analysis has showed that most of the transitions which cannot be assigned to water are very weak and are due to impurities such as carbon dioxide and ammonia, leaving only about 3% of the observed transitions unassigned. The interest of a detailed knowledge of water absorption for trace detectors developed in the 1.5 μm range is underlined: for instance HDO contributes significantly to the considered spectrum while no HDO line parameters are provided by the HITRAN database. 相似文献
66.
We prove that the tolerance lattice TolA of an algebra A from a congruence modular variety V is 0-1 modular and satisfies the general disjointness property. If V is congruence distributive, then the lattice Tol A is pseudocomplemented. If V admits a majority term, then Tol A is 0-modular.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
67.
The optical nonlinearities of Cu(mpo)2 [formula = C10H8N2CuO2S2] complex have firstly been investigated by using the Z-scan technique with a nanosecond-pulsed Nd:YAG laser at its second harmonic (532 nm) radiation. The nonlinear optical absorption and refraction coefficients of Cu(mpo)2 have been measured with the different on-axial peak irradiances I
0 at the waist ranging from 0.48 to 5.66 GW/cm2. The nonlinear transmittance characteristics exhibit the near resonant two-photon absorption (TPA) at 532 nm and are explained by a population redistribution model. The nonlinear absorption originates from the near resonant TPA while the mechanism of the nonlinear refraction is the near resonant TPA transition enhancement. The linear increasing dependences of the optical nonlinearities on the incident irradiance arise from the population redistribution due to the near resonant TPA. 相似文献
68.
研究了钍与5-(对羧基苯偶氮)-8-羟基喹啉(5-CPAHQ)的显色反应条件:在阳离子表面活性剂十六烷基三甲基溴化铵(CTMAB)存在下,pH4.4-5.4缓冲介质中,形成稳定的橙红色络合物,最大吸收波长为490nm,ε=1.10×105L·mol-1·cm-1,钍在0-9μg/25mL范围内符合比尔定律。用TBP萃淋树脂分离,该方法可用于测定矿石中的微量钍。 相似文献
69.
Isosteric derivatives and analogues of the 7-keto-8-aminopelargonic acid (KAPA), 7,8-diaminopelargonic acid (DAPA) and desthiobiotin (DTB) vitamer intermediates involved in the biosynthetic pathway of biotin were prepared and evaluated as potential herbicides. The most active compound was desmethyl-KAPA which displayed a GR50 (concentration of the active compound that causes a 50% growth inhibition) value of 8 ppm, where values <50 ppm are considered herbicidal. Other KAPA analogs where the terminal Me group was replaced by bulkier substituents such as Et, i-Pr and HOCH2 showed moderate activity. 相似文献
70.
《The European Physical Journal A - Hadrons and Nuclei》2003,17(2):241-244
The helicity dependence of the γ
p↦pη reaction has been measured for the first time at a center-of-mass angle θ*
η = 70° in the photon energy range from 780 MeV to 790 MeV. The experiment, performed at the Mainz microtron MAMI, used a 4π-detector
system, a circularly polarized, tagged photon beam, and a longitudinally polarized frozen-spin target. The helicity 3/2 cross-section
is found to be small and the results for helicity 1/2 agree with predictions from the MAID analysis.
Received: 19 December 2002 / Accepted: 10 March 2003 / Published online: 20 May 2003 相似文献