A Facile Synthesis of α-Phenylthio-α,β-Unsatuated Esters

α-phenylthio-α，β-unsaturated esters 6 were synthesized by Witting reaction of 3.which were prepared by a phenylsulfenyllation-trans-ylidation reaction.     

ROBUST GLOBAL EXPONENTIAL STABILITY OF UNCERTAIN IMPULSIVE SYSTEMS

By using the quasi-Lyapunov function, some sufficient conditions of global exponential stability for impulsive systems are established, which is the basis for the following discussion. Then, by employing Riccati inequality and Hamilton-Jacobi inequality approach, some sufficient conditions of robust exponential stability for uncertain linear/nonlinear impulsive systems are derived, respectively. Finally, some examples are given to illustrate the applications of the theory.     

液体CO2在毛细管内的质量流量及临界流实验研究

本文进行了液体CO2在长度为0.5～5.9 m,内径为0.7 mm和2.0 mm,入出口压差为2.2 MPa和2.5 MPa的毛细管内的质量流量及临界流的实验研究.实验结果表明液体CO2在毛细管中的质量流量随毛细管内径、入出口压差的增大而增大,随长度的增加而逐渐减小;结果同时表明液体CO2在毛细管中产生了临界流现象,临界流随毛细管内径的增大而增大.在实验基础上回归出了适用于本实验条件的液体CO2在毛细管内的质量流量经验关联式,具有一定的工程指导意义.     

Synthesis and Crystal Structure of a Coordination Polymer {[Co(phth)(phen)(H2O)]·(C2H5OH)}n

The coordination polymer {[Co(phth)(phen)(H2O)]·(C2H5OH)}n (phth = phthalate, phen = 1,10-phenanthroline) with formula C22H20CoN2O6 (Mr = 467.33) was synthesized by the solvothermal method under low temperature, and its crystal structure was determined by singlecrystal X-ray diffraction. The complex belongs to monoclinic system, space group P21/n with a =12.7352(16), b = 8.8125(11), c = 18.677(2) (A), β = 102.633(2)°, V = 2045.3(4) (A)3, Z = 4, Dc =1.518 g/cm3,μ = 0.882 mm-1, F(000) = 964, S = 1.053, the final R = 0.0401 and wR = 0.0984 for 3135 observed reflections (I ＞ 2σ(I)). Single-crystal X-ray analysis revealed that the Co(Ⅱ) ion is six-coordinated. The cobalt complex forms a one-dimensional chain structure via phthalate bridging ligand. In the cobalt complex, a 3D network structure is formed by π-π stacking interaction of 1,10-phenanthroline as well as intermolecular hydrogen bonding interactions.     

What Is Its Real Existing Form?——Theoretical and Experimental Studies on 2-Mercaptobenzothiazole

1 INTRODUCTION The study of heterocyclic molecules with aroma- tic rings and their absorptions on metals is of con- siderable importance from both theoretical and te- chnological points of view. These molecules are in- teresting because of their applications as corrosion inhibitors and flotation collectors, and their abilities to form self-assembly layers[1]. 2-Mercaptobenzo- thiazole (C7H5NS2, in the following MBT) is an important heterocyclic molecule, which can be used as corrosion …     

KrF激光诱导BrC2F4Br+C2H4反应

激光诱导化学合成是一有兴趣的课题。不久前已报导了红外激光诱导调聚反应的结果。由于红外激光的加热特性,在许多情况下导致选择性与量子产率的矛盾。因紫外光反应的低温特性,有可能获得较高的选择性。但普通光源是宽带光源,对一个以平方断链为主的链反应,过强的吸收不利于链长的提高,而弱吸收又使反应速度太慢。为此,激光光源是满足最佳吸收的合宜光源。在使用了昂贵的激光光源后,经济上的合理性主要取决于链长     

X射线衍射研究N2+注入Si

本文首先给出了180keV的N₂⁺注入Si的X射线衍射(XRD)分布,然后用Levenberg-Marquardt最优化方法模拟实验曲线。根据XRD运动学理论,在我们给出的试探胁变函数和多层模型的基础上,用自编程序计算给出了晶格胁变随注入深度、剂量和退火温度的变化。最后我们对实验和计算结果进行了初步的分析讨论。 关键词：