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991.
Polycrystal Li2B4O7 (LBO) doped with Cu and In was prepared and then sintered at different temperatures. X-ray diffraction (XRD) was applied
to get the parameters of the LBO structure, thermoluminescence (TL) and optically stimulated luminescence (OSL) were measured,
and a second-order exponential decay model was fitted to the OSL decay curves. The results indicate that the original number
of OSL traps that have captured electroncs is linearly related with the sum of TL decay during the OSL process. Mean decay
constant of OSL is related to the sintered temperature. The possible reason is that the sintered temperature affects the crystal
sizes of the polycrystal, and consequently affects the stimulating lights’s intensity and the photoionization cross-section
of the electrons, which have been captured by the traps.
__________
Translated from Acta Scientiarum Naturalium Universitatis Sunyatseni, 2005, 44(4) (in Chinese) 相似文献
992.
Victor A.?ZammitEmail author Nigel T.?Price Vicky N.?Jackson Byun-Sung?Park 《Monatshefte für Chemie / Chemical Monthly》2005,136(8):1299-1309
Summary. Carnitine acyltransferases catalyse equilibria between acyl-CoA esters and the respective acylcarnitines. Therefore, they act not only as pathway enzymes, but also as modulators of acyl-CoA concentrations within individual sub-cellular compartments. Because acyl-CoA esters are potent biologically active metabolites, carnitine acyltransferase activities are potentially able to affect a diverse range of physiological processes, ranging from insulin secretion, to appetite control, and insulin sensitivity of tissues. The distinctive subcellular distributions of the different types of carnitine acyltransferases also enables them to participate in the transfer of acyl moieties across intracellular membranes, and of particular acylcarnitine esters across the plasma membrane and into the plasma. Pharmacological strategies that make use of these properties to improve cell function are discussed. 相似文献
993.
Ryan R. Burton 《Tetrahedron letters》2006,47(40):7185-7189
Ruthenium-catalyzed [2+2] cycloadditions between C1-substituted 7-oxanorbornadienes and alkynes were investigated. Most of the cycloadditions occurred smoothly at 65 °C, giving the cyclobutene cycloadducts in moderate to good yields. The C1 substituent showed strong effect on the regioselectivity (up to 110:1) of the cycloadditions. 相似文献
994.
非水层状液晶的稳定性与相行为 总被引:3,自引:1,他引:3
水体系层状液晶已研究较久,非水层状液晶则是近十年来才得到发展。本文以层状液晶的相行为和~2H NMR测量,研究并比较了非水层状液晶十二烷基硫酸钠/正癸醇溶剂以甘油或甲酰胺为溶剂时体系的结构与稳定性。 表面活性剂十二烷基硫酸钠(BDH,简写SDS)经无水乙醇重结晶两次提纯。用铂环法测 相似文献
995.
Qichen Huang Zheming Wang Qianli Chu Shizheng Zhu 《Journal of inclusion phenomena and macrocyclic chemistry》2006,54(3-4):177-180
X-ray analysis has revealed that N,N,N′,N′-tetramethyl-ethylenediamine 1 form donor–acceptor complex 3 with 1-bromo-2-iodo-tetrafluoroethane 2, in which the N X (X = Br, I) distances are longer than the average covalent bond length between X and N, but are also definitively shorter than the sum of the corresponding van der Waals radii of X and N, thus that indicating weak interactions between the nitrogen and bromine or iodine atoms. In our experimental section, a valuable method for recrystallization and collect X-ray data from crystals that easily exhibit decay and can be cracked is reported. 相似文献
996.
Dihydrothiinone 9a undergoes photocycloaddition regioselectively to all three C?C bonds of penta‐1,2,4‐triene ( 10 ), the relative stabilities of the biradical intermediates determining the product distribution. In contrast, cyclohexenone 9b and dihydropyranone 9c afford more complex mixtures of bicyclo[4.2.0]octanones, which also turn out to be less stable on chromatographic workup, reflecting the higher strain due to the shorter bond lengths (C? O and C? C vs. C? S) in the six‐membered rings, respectively. 相似文献
997.
Fabio E. Penotti 《International journal of quantum chemistry》2006,106(5):1153-1159
Nonorthogonal single‐configuration and multiconfiguration ab initio calculations are carried out on the BeH2 molecule in its equilibrium (D∞h) geometry, using a highly optimized even‐tempered Slater‐type orbital (STO) basis set. The results are used as a basis for a discussion of the electronic structure of the molecule in modern‐VB terms. A value of Re = 1.329 Å is obtained. Values are also obtained for the symmetric‐stretch harmonic frequency (2053 cm?1), electric quadrupole moment (?5.60 Buckingham), and nuclear quadrupole coupling constants (?3.59 MHz for 9Be and 0.0915 MHz for 2H). © 2005 Wiley Periodicals, Inc. Int J Quantum Chem, 2006 相似文献
998.
Phase behavior of the extraction system, Cyanex 923–heptane/H2SO4–H2O has been studied. The third phase appeared at different aqueous H2SO4 concentration with varying initial Cyanex 923 concentration and temperature affects its appearance. Almost all of H2SO4 and H2O are extracted into the middle phase. The H2SO4 concentration in the third phase increases with the increasing aqueous acid concentration (CH2SO4,b) while the water content first increases and then reaches a constant value at CH2SO4,b=11.3 mol l−1. In the region of CH2SO4,b higher than 5.2 mol l−1, the composition of the middle phase is only related to the equilibrium concentration of H2SO4 in the bottom phase. H2SO4 and H2O are transferred into the middle phase mainly by their coordination with Cyanex 923 when CH2SO4,b is less than 11.3 mol l−1. When CH2SO4,b is higher than 11.3 mol l−1, excess H2SO4 is solubilized into the polar layer of the aggregates. In the region considered, the extracted complex changes from C923 · H2SO4 to C923 · H2SO4 · H2O and then to C923 · (H2SO4)2 · H2O. 相似文献
999.
在量子化学对SiH与H2O和H2S反应计算的基础上,运用统计热力学和Wigner校正的Eyring过渡态理论,计算了上述两反应在200~2000 K温度范围内的热力学函数、平衡常数、频率因子A和速率常数随温度的变化。计算结果表明,两反应在低温下具有热力学优势,而在高温下具有动力学优势。比较两反应的计算结果发现,在相同的温度下,SiH与H2O反应比SiH与H2S反应放热较多,但速率常数却较小。SiH与H2O反应和前文报道的SiH与HF反应的比较表明,SiH与H2O反应放热较少,而且在相同温度下,速率常数也较小。 相似文献
1000.
As supported PtxNi1–x catalysts are used for hydrogenation reactions, it seemed necessary to assess the surface composition of the reduced samples. To approach the usual reduction conditions we applied in situ reduction in a reaction chamber (1 mbar H2 up to 500 °C) placed in ultra high vacuum recipient (UHV: 10–9 to 2.10–10mbar). All ion scattering spectroscopy measurements were performed in UHV. Charging of the samples was avoided by electron bombardment (5 eV). The variation of the surface composition was determined after subsequent sputtering, thermal treatment at 500 °C and during oxygen adsorption. A comparison with previous results of surface compositions of binary alloys (polycrystalline foils [1, 2] and single crystals PtxNi1–x [3]) is given.Dedicated to Professor Dr. rer. nat. Dr. h. c. Hubertus Nickel on the occasion of his 65th birthday 相似文献