全文获取类型
收费全文 | 19236篇 |
免费 | 5847篇 |
国内免费 | 8955篇 |
专业分类
化学 | 13142篇 |
晶体学 | 815篇 |
力学 | 4054篇 |
综合类 | 691篇 |
数学 | 2913篇 |
物理学 | 12423篇 |
出版年
2024年 | 186篇 |
2023年 | 644篇 |
2022年 | 691篇 |
2021年 | 748篇 |
2020年 | 609篇 |
2019年 | 707篇 |
2018年 | 576篇 |
2017年 | 772篇 |
2016年 | 803篇 |
2015年 | 858篇 |
2014年 | 1746篇 |
2013年 | 1421篇 |
2012年 | 1427篇 |
2011年 | 1525篇 |
2010年 | 1434篇 |
2009年 | 1520篇 |
2008年 | 1716篇 |
2007年 | 1338篇 |
2006年 | 1376篇 |
2005年 | 1570篇 |
2004年 | 1349篇 |
2003年 | 1546篇 |
2002年 | 1244篇 |
2001年 | 1237篇 |
2000年 | 956篇 |
1999年 | 684篇 |
1998年 | 644篇 |
1997年 | 568篇 |
1996年 | 608篇 |
1995年 | 615篇 |
1994年 | 585篇 |
1993年 | 420篇 |
1992年 | 429篇 |
1991年 | 403篇 |
1990年 | 436篇 |
1989年 | 353篇 |
1988年 | 91篇 |
1987年 | 73篇 |
1986年 | 51篇 |
1985年 | 29篇 |
1984年 | 13篇 |
1983年 | 14篇 |
1982年 | 16篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 4篇 |
1959年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 93 毫秒
991.
用INDO法从正则分子轨道和定域分子轨道讨论了[CuCl_3]~-的电子结构和化学键,铜的4p轨道对成键贡献最大,3d轨道不参与成键。根据[CuCl_3]~-的HOMO和LUMO的原子轨道成份,讨论了它的配位化学性质。 相似文献
992.
测定了一系列有机铵盐与一种全氟烷磺酸盐1:1混合体系水 溶液的表面张力,由此研究有机铵盐对碳氟表面活性剂表面活性及溶度的影响,导出应用于此种混合体系的Gibbs吸附公式,并讨论了混合体系中两表面活性组分的表面分子相互作用和表面层的结构。 相似文献
993.
ZHANG Xiao-Feng HUAND De-Guang CHEN Feng CHEN Chang-Neng LIU Qiu-Tian② 《结构化学》2003,22(5):525-528
1 INTRODUCTION Water oxidation to oxygen gas by photo- synthetic apparatus of green plants and cyano- bacteria is the origin of this gas in the atmosphere. The water oxidation center is a tetranuclear, oxide- bridged manganese cluster with O,N-based peri- pheral ligation by amino acid side-chain group[1, 2]. The binding of aqua to the Mn site may be impor- tant to the oxidation of aqua for producing dioxygen. 1,10-Phenanthroline has been adopted to simulate coordination sphere of manga… 相似文献
994.
Shi-jun Zheng Qun Xu Shao-kui Cao 《高分子科学》2007,(2):171-179
The novel shish-kebab-type liquid crystalline cross-conjugated (p-phenylene)s-poly(p-phenylenevinylene)s hybrid was synthesized through Gilch polymerization. Their structures and properties were characterized by NMR, GPC, DSC, X-ray diffraction and polarizing optical microscope (POM). ^1H-NMR investigation of the polymers indicates that the shish-kebab-structure has a strong ability to suppress the structural defects in the polymers. The polymers are enantiotropic liquid crystals. The melting point (Tm) of the polymers decreases when the length of the alkoxy tails of the mesogenic units increases. The mesophase was identified by X-ray diffraction method. They showed not only a smectic LC phase, but also a strong green fluorescence in chloroform. The maximum absorption band of the "kebabs" of the two, 5-bis(4'- alkoxyphenyl)benzene at 280 nm did not appear in absorption spectra of the polymers. The same phenomena were also observed in the fluorescence spectra. These results imply that the polymers have formed a cross-conjugated uniform structure and achieved an extended n-conjugation polymer. 相似文献
995.
The synthesis and characterization of coil-rod-coil triblock oligomers, poly(ethylene oxide)-b-p-hexaphenyl-b- poly(ethylene oxide), are described. The number of repeating ethylene oxide units in each flexible block are 3 (EO3-PHP- EO3), 8 (EOs-PHP-EO8), 13 (EO13-PHP-EO13), and 17 (EO17-PHP-EO17), respectively. The structures of these oligomers are confirmed by ^1H-NMR, 13C-NMR, EA, and MALDI-TOF mass spectrometry. The introduction of soluble poly(ethylene oxide) coils to the rigid p-hexaphenyl segment significantly improves the solubility of the oligomers, so they can form smooth thin films by spin-coating from their solutions. The oligomers are quite thermally stable and have 1% weight loss temperatures at above 340℃ under nitrogen. They can emit strong blue light in both solution and film state, and have fluorescence quantum yields of about 40% in chloroform. They are expected to have potential applications in optoelectronic devices. 相似文献
996.
四唑及其衍生物的理论研究Ⅷ: 硝氨四唑衍生物的从头算 总被引:3,自引:0,他引:3
运用从头计算法,在HF/6-31G^*水平下,全优化计算了7种硝氨四唑衍生物的分子几何和电子结构。结果表明,标题物的四唑环近似为平面构型;2H式中性分子的芳香性大于相应的1H式异构体。5-硝氨-1H四唑分子内氢键使硝氨基与环共面;其余标题物中硝氨基与环垂直。不同水平下的总能量计算表明,标题物中电子相关效应显著;1H式中性分子较2H式的能量高,5-硝氨四唑负离子在三个负离子中最稳定。根据电荷分布阐明了四唑环质子化位置和标题物与金属的配位方式。此外还计算了各标题物的红外光谱及热力学性质。 相似文献
997.
ZHENG Yan YANG Bing ZHANG Hai-quan LU Ping SHEN Fang-zhong LIU Lin-lin XU Hai YANG Guang-di MA Yu-guang 《高等学校化学研究》2007,23(6):720-725
A soluble poly(meta-phenylene)derivative with rigid twisted biphenyl unit was synthesized by the Yamamoto coupling reaction.The polymer is soluble in common organic solvents,and the number-average molecular weight is about 6500.The UV-Vis and quantum chemical calculation indicate that the different conformation segments named "conformers" exist in the polymer backbones;it was also further confirmed by the single crystal X-ray diffraction study of the dimeric model compound.The π-π transition of biphenyl segments of twisted and planar conformations made the polymer exhibit a strong absorption around 256 nm and a weak absorption at about 300 nm.Furthermore,the polymer exhibits a strong UV photoluminescence at 372 nm when the excitation wavelengths are longer than 300 nm.The ultraviolet-emitting electroluminescence(EL)device with the single layer structure shows EL λmax of the derivative at 370 nm. 相似文献
998.
Time-dependent density-functional theory(TDDFT)has been applied to calculate the electronic structure and second-order nonlinear optical(NLO) properties of some organic molecules.The two-dimensional(2-D)charge transfer charateristics of calculated molecules were studied and compared with corresponding experimental results.All the theoretical results agree well with the measurement.For 2-D molecule with two-fold symmetry,the dominant charge transfer is off-diagonal,while for three-fold symmetry 2-D molecule,the dominant charge transfer is not only between branches and central group but also among branches. 相似文献
999.
A novel coordination polymer {[Zn(ts-gln)(bipy)]3H2O}n (ts-glnH2=N-p-toly-sulfonyl-glutamine,bipy=2,2-bipyridine) has been prepared and structurally characterized by X-ray diffraction method. It crystallizes in orthorhombic,space group P212121 with a=8.2622(5),b=16.6244(10),c=18.2807(10) ,V=2510.9(3) 3,C22H28N4O8SZn,Mr=573.91,Z=4,Dc= 1.518 g/cm3,μ(MoKa)=1.115 mm-1,F(000)=1192,the final R=0.0262 and wR=0.0662 for 5691 independent reflections with Rint=0.0240. The zinc(Ⅱ) atom is coordinated by N(3) and N(4) atoms of a bipy molecule,two carboxylate O(1) and O(2A) and amino N(1) atoms of ts-gln ligands,resulting in a square-pyramidal geometry. The title complex consists of an infinite zigzag chain of zinc(Ⅱ) ions linked by the carboxylate of N-p-tolysulfonyl-glutamine. 相似文献
1000.
Sesquiterpenoids from Chloranthus spicatus (Thunb.) Makino 总被引:2,自引:0,他引:2
Two new sesquiterpenoids, namely 1β,4β-dihydroxy-5 α,8β(H)-eudesm-7(11)Z-en-8,12-olide (1) and 1β,4α-dihydroxy-5α,8β(H)-eudesm-7(11)Z-en-8,12-olide (2), along with six known ones, homalomenol A (3), oplodiol (4), 5α,7α(H)-6,8-cycloeudesma-1β,4β-diol (5), oplopanone (6), 4β,10α-dihydroxyaromadendrane (7) and spathulenol (8), were isolated from the aerial part of Chloranthus spicatus (Thunb.) Makino, and their structures were established by spectroscopic methods. 相似文献