Synthesis and Photocytotoxicity of Mono-functionalised Porphyrin with Valine Moiety

A mono-funtionalised tetraphenylporphyrin (TPP) bearing valine moiety at the phenyl ring was synthesized for photocytotoxicity examination in four steps, starting from regiospecific mono-nitration of TPP at the phenyl ring. The in vitro photocytotoxicitic effect against SPC-Al adenocarcinona cell line was tested.     

Studies on Synthesis and properties of Mg-Al-nitrate Layered Ouble Hydroxides

A positive Mg-Al-nitrate layered double hydroxides(LDHs) has been synthesized using a non-steady coprecipitation method.The shape.size,chemical composition,electrical property and anion exchange property of the positve nanoparticle were studied by SEM,XRD,FTIR,chemical analysis,spectroanalysis and meaxsuring of electrophoretic mobilities.Preliminary results show the positive nanoparticle is a promising precursor of polymer/LDHs nanocomposite.     

法沃尔斯基（FavorskiiAE）重排新进展

本文介绍了近年来法沃尔斯基重排反应在手性药物，立方烷系，杂环衍生物环烷小合成中的最新动态有应用前景。     

2—（4,6—二甲基—2—嘧啶巯基）乙酰芳胺的合成及其生物活性的初步研究

许多乙酰芳胺类化合物具有优异的生物活性，例如除草剂苯噻草胺，可抑制细胞生长和分裂，防除稻田中禾本科杂草［１］；杀菌剂甲霜灵可防治作物霜霉病［２］。本文将具有多种生物活性的嘧啶基团引入到乙酰芳胺结构中［３］，合成下列１０个未见文献报道的标题化合物Ⅰ，通...     

NASICON型化合物结构的NMR研究

在水热晶化合成一系列NASICON型化合物的基础上,应用固体高分辨³¹P和²⁹Si MAS NMR,研究了几种NASICON化合物的结构,观察其骨架原子P和Si在结构中的状态及分布,并解释了由于在结构中发生取代作用而引起,Si或P的化学位移的变化.     

Synthesis of Dimethyl Carbonate from CO2 , Methanol, and Epoxides Using Re（CO） 5 Cl/K2 CO3 as Catalyst System

IntroductionOver the past few years, dimethyl carbonate(DMC) has been proven to be an efficientmethylating,methoxylating, and methoxycarbonylating agent inorganic syntheses, in which DMC is used to replace thetoxic methyl halides, dimethyl sulfate or carb