一种有效记忆热力学关系的方法

 均匀物质的热力学性质是热力学理论的基础知识,也是入门知识,因而对这部分知识的学习和掌握就显得尤为重要。但是,在历年的教学中发现,学生对这部分知识的掌握并不好,究其原因,重要的一条是这部分内容概念多、参量多、公式多、状态多,并且各参量之间,各公式之间互相联系、十分类似,因而记忆时特别容易混淆,从而导致理解和应用的障碍。所以,若能找到一种便于记忆的方法,那么,无论是对学生还是对教师都将有很大帮助。基于以上这些认识,本文将从教学内容出发,本着直观简单的原则,介绍一种十分便于记忆的方法---函数图像法。     

BEPCⅡ LINAC束流光学匹配及轨道校正计算研究

 北京正负电子对撞机直线注入器(BEPCⅡ LINAC)的升级改进要求建立束流光学匹配计算和轨道校正系统，为此对束流光学匹配计算和轨道校正计算的方法进行了研究，并采用VC++语言编写了相应的程序，利用最小二乘法原理进行了束流光学匹配计算，模拟了束流轨道校正，取得了较为理想的结果。     

闪烁光纤在γ射线辐照下部分特性的蒙特卡罗模拟

 闪烁光纤在射线成像方面的应用越来越广泛。为了进一步了解闪烁光纤在射线辐照下的基本特性，基于蒙特卡罗方法，利用计算机模拟分析了γ射线在闪烁光纤中的好事例率与光纤长度及射线能量的关系，能量沉积效率与光纤长度及射线能量的关系。此项工作对于闪烁光纤阵列在射线成像，剂量场测量等方面的研究很有价值。     

衍/折射光学元件消二级光谱的设计

 采用衍/折射光学元件结合的方法，使用两种玻璃设计了星载用长焦距望远物镜，对其二级光谱进行了校正。具体介绍了衍/折透镜望远透镜消二级光谱方法、步骤。计算机模拟结果表明：校正后的望远物镜轴上位置色差小于0.08mm，满足使用要求，并且设计方法步骤简单。     

钌(Ⅱ)卟啉催化顺式二苯乙烯类化合物的选择性合成

由芳醛制得的腙盐在钌(Ⅱ)卟啉催化下发生自身偶合，以较高收率合成了二苯乙烯类化合物(～90％的顺式选择性)。部分中间体及目标化合物的结构经^1H NMR，^13C NMR和MS表征。     

Synthesis of 2-Acyl-2H-1,2,3-diazaphospholes and Their Diels-Alder Reaction with Cyclopentadiene

2H-1,2,3-Diazaphospholes 3a-3h were prepared from various ketone acylhydrazones and phosphorus trichloride in the presence of triethylamine. Compounds 3 underwent feasible hetero-Diels-Alder reactions with cyclopentadiene to afford the respective anellated [1,2,3]diazaphospholes 4a--4d as well as 4a‘--4d‘ in moderate yields. The endo rule in the reaction was observed under kinetic control conditions.     

Synthesis of 5,6-Dihydro-OSW-1 and Its Antitumor Activities

5,6-Dihydro-OSW-1 (1) was synthesized following our previous procedure for the total synthesis of OSW-1. This compound demonstrated slightly stronger potency than that of OSW-1 against the growth of cancer cells.     

New Approach to Synthesis of Tetrahydroisoquino[2,1-c] [1,3]benzodiazepine

A concise and efficient synthesis of the new compounds tetrahydroisoquino [2,1-c] [1,3]benzodiazepine 5 and 7 is reported.     

Microwave Synthesis, Characterization and DNA-binding Properties of a New Cobalt（ Ⅱ ） Complex with 2,6-Bis（benzimidazol-2-yl）pyridine

A new cobalt(Ⅱ) complex with tridentate ligand 2, 6-bis (benzimidazol-2-yl)pyridine has been synthesized by microwave irradiation method and characterized by elemental analysis,electrochemical and spectral methods. The binding of the complex with calf thymus DNA has also been investigated by absorption and fluorescence spectra.     

Regioselective Synthesis of Multi-substituted Phenylselenomethyl Isoxazolines

A mild, regioselective 1, 3-dipolar cycloaddition protocol for the preparation ofphenylselenomethyl isoxazolines through substituted allyl phenyl selenides and nitrile oxides wasreported.