Luminescence of europium and ytterbium ions in strontium hexaborate

We have studied the luminescent properties of Eu^2+/3+ and Yb²⁺ ions in strontium hexaborate SrB₆O₁₀ for excitation in the 120–400 nm region. The luminescence spectra of Ln²⁺ ions in SrB₆O₁₀ consist of overlapping bands in the 370–520 nm region, due to 5d → 4f transitions at several nonequivalent centers. In the excitation spectra, besides the bands associated with 4f → 5d transitions in the Ln²⁺ ions, we also observe a band in the 135–160 nm region due to the transitions O(2p) → B(2s,2p) within the borate anions. The luminescence of the Eu³⁺ ions is excited most efficiently in the region of the Eu³⁺ charge transfer band (λ_max = 226 nm). The results obtained are compared with data for Ln in other strontium borates. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 6, pp. 770–774, November–December, 2006.     

High temperature limit of the order parameter correlation functions in the quantum Ising model

In this paper we use the exact results for the anisotropic two-dimensional Ising model obtained by Bugrii and Lisovyy [A.I. Bugrii, O.O. Lisovyy, Theor. Math. Phys. 140 (2004) 987] to derive the expressions for dynamical correlation functions for the quantum Ising model in one dimension at high temperatures.     

束流位置监测系统的研制及其在国家同步辐射实验室二期工程中的应用

 介绍一种储存环束流位置监测系统的标定装置。这套标定装置是为NSRL二期工程储存环注入段真空盒改造而研制的。系统的标定精度达±0.01mm。该装置已用于新增注入段真空管的束流位置探测器的定标，获得了探头定标值，并根据其拟合和计算结果对注入段真空管进行了筛选，被选中的真空管已装入储存环注入段。     

Asymmetry in the turbulent flow of a viscoelastic liquid through an axisymmetric sudden expansion

This paper concerns the asymmetry in mean axial velocity distributions for the flow through an axisymmetric sudden expansion of a viscoelastic, shear-thinning aqueous solution of a polyacrylamide (PAA). The asymmetry manifests itself as an azimuthal variation in the length of the recirculation region of the separated flow downstream of the expansion inlet. For water, the flow is found to be axisymmetric. The asymmetry for the PAA flow, which remained unchanged despite alterations to the flow facility, is attributed to the high viscoelasticity of the polymer solution. The conclusion is drawn that the asymmetry is a purely physical feature of such a flow, and not the product of upstream or downstream flow conditions deriving from the flow facility, or the result of geometrical imperfections in the axisymmetric sudden expansion set-up.     

Photoluminescence properties of anodic alumina membranes with ordered nanopore arrays

Photoluminescence (PL) of anodic alumina membranes (AAMs) with ordered nanopore arrays fabricated in oxalic acid has been investigated under different annealing temperatures. The PL intensity firstly increases, and at 500 °C reaches a maximum value, then decreases. The structural transition from amorphous to γ-Al₂O₃ in AAMs has been confirmed by X-ray diffraction. Thermogravimetric analysis results and electron paramagnetic resonance measurements revealed that the PL band of alumina membranes could be attributed to the oxygen-related defect centers (F⁺ centers) rather than the luminescent centers transformed from oxalic impurities.     

Radiation chemistry of cis-syn-cis dicyclohexano-18-crown-6 (DCH18C6): Acidity and uranyl nitrate dependence

The cis-syn-cis isomer of dicyclohexano-18-crown-6 (DCH18C6) has been shown to be an efficient extractant able to perform the separation of Pu(IV) and U(VI) from fission products and then the separation of Pu(IV) from U(VI) without valence exchange as required in the PUREX process. This macrocycle was irradiated in nitric acid with a ¹³⁷Cs γ source to study its radiation chemical stability. Radiation chemical yields (G) were determined by gas chromatography. The results show that the presence of uranyl nitrate has a strong influence on DCH18C6 radiation chemical stability. Indeed, the presence of this template ion increases the macrocycle stability by promoting fragments recombination.     

高频环行器打火原因的分析

合肥光源(HLS)储存环高频系统环行器在工作中出现了两种形式的打火——谐波打火和束流丢失打火. 谐波打火的原因已经找到并予以解决, 但丢束打火的机制尚未明确. 文中描述了丢束后高频系统的响应过程, 分析了一些可能造成环行器打火的因素. 为了防止环行器打火受损, 建立了快速联锁保护电路, 该电路在历次打火中成功地保护了环行器.     

基于四象限光位置检测器的同步光位置测量系统

 为了克服现有双丝型检测器无法进行水平、垂直两个方向同时测量同步光位置的缺点,合肥光源新研制了基于四象限光位置检测器的同步光位置测量系统,并使用对数比处理技术进行后续的数据处理。通过分别对光学成像系统和四象限光位置检测器的标定,最终得到基于四象限光位置检测器的光位置测量系统的性能参数为:水平方向灵敏度0.471 2 mm^-1,线性范围为±1.83 mm,垂直方向灵敏度0.635 0 mm-1,线性范围±1.32 mm。与合肥光源现有的光位置测量系统相比,具有较高的性价比。     

Density excitations of a harmonically trapped ideal gas

The dynamic structure factor S(q, ω) of a harmonically trapped Bose gas has been calculated well above the Bose-Einstein condensation temperature by treating the gas cloud as a canonical ensemble of non-interacting classical particles. The static structure factor is found to vanish s8 q ² in the long-wavelength limit. We also incorporate a relaxation mechanism phenomenologically by including a stochastic friction force to study S(q, ω). A significant temperature dependence of the density fluctuation spectra is found. The Debye-Waller factor has been calculated for the trapped thermal cloud as a function of q and the number N of atoms. A substantial difference is found for small- and large-N clouds.     

真空紫外光激发下Ce3+、Tb3+激活的BaCa2(BO3)2的发光性质

利用XRD、VUV及UV光谱等方法对Ce³⁺、Tb³⁺离子掺杂以及Ce³⁺、Tb³⁺离子共掺的3种BaCa₂(BO₃)₂荧光粉的相纯度、发光性质、浓度猝灭现象进行研究。结果表明:3种荧光粉在VUV波段有较好的吸收,基质吸收带位于140～190 nm范围。Ce³⁺在BaCa₂(BO₃)₂的最低4f5d跃迁带位置在360 nm附近,其5d→²F_J(J=5/2, 7/2)发射峰分别位于393,424 nm。Tb³⁺掺杂的样品在172 nm激发下的发射光谱由4个窄带组成,分别对应⁵D₄→⁷F_J(J=3,4,5,6)的跃迁,其中占主导位置的是⁵D₄→⁷F₅的跃迁,大约位于543 nm处,主要为绿光发射。在Ce³⁺,Tb³⁺离子共掺杂的BaCa₂(BO₃)₂光谱中,观察到Ce³⁺-Tb³⁺离子间有能量传递。