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91.
Copper bromide was used as a catalyst for the addition of pyrroles to enones. When both the reactants were used in equimolar amounts, mono and dialkylated products were obtained. However, the use of excess enone furnished only dialkylated products. Thus, copper bromide was shown to be an efficient catalyst for the dialkylation of pyrroles. 相似文献
92.
Examples are worked out using a new equation proposed in the previous paper to show that it has new physical predictions for mesoscopic systems. 相似文献
93.
Anindya Ghose Choudhury Asesh Roy Chowdhury 《International Journal of Theoretical Physics》2002,41(2):321-330
A new integrable long-range model is derived from a new asymmetric R-matrix recently discussed by Bibikov in relation to a XXZ spin chain in an external magnetic field. The algebraic Bethe Ansatz is used to derive the eigenvalues and equations for the eigen momenta both for the usual and long-range model. 相似文献
94.
It is explicitly shown that if phase transition occurs at the core of a newborn neutron star with moderately strong magnetic
field strength, which populates only the electron’s Landau levels, then in the β -equilibrium condition, the quark core is
energetically much more unstable than the neutron matter of identical physical condition. 相似文献
95.
During the course of our investigation of the electron transfer properties of some redox species through highly hydrophobic
long chain alkanethiol molecules on gold in aqueous and non-aqueous solvents, we obtained some intriguing results such as
unusually low interfacial capacitance, very high values of impedance and film resistance, all of which pointed to the possible
existence of a nanometer size interfacial gap between the hydrophobic monolayer and aqueous electrolyte. We explain this phenomenon
by a model for the alkanethiol monolayer—aqueous electrolyte interface, in which the extremely hydrophobic alkanethiol film
repels water molecules adjacent to it and in the process creates a shield between the monolayer film and water. This effectively
increases the overall thickness of the dielectric layer that is manifested as an abnormally low value of interfacial capacitance.
This behaviour is very much akin to the ‘drying transition’ proposed by Lum, Chandler and Weeks in their theory of length
scale dependent hydrophobicity. For small hydrophobic units consisting of apolar solutes, the water molecules can reorganize
around them without sacrificing their hydrogen bonds. Since for an extended hydrophobic unit, the existence of hydrogen bonded
water structure close to it is geometrically unfavourable, there is a net depletion of water molecules in the vicinity leading
to the possible creation of a hydrophobic interfacial gap. 相似文献
96.
X-ray diffraction patterns of nanocrystalline Fe-Cu-Nb-Si-B (FINEMET) alloys reveal that bcc α-Fe/α-FeSi crystallites with
the average grain size of 20(5) nm are dispersed in amorphous matrix. Enhanced electron—electron interaction (EEI) and quantum
interference (QI) effects as well as electron-magnon (and/or electron-spin fluctuation) scattering turn out to be the main
mechanisms that govern the temperature dependence of resistivity. Of all the inelastic scattering processes, inelastic electron-phonon
scattering is the most effective mechanism to destroy phase coherence of electron wave functions. The diffusion constant,
density of states at the Fermi level and the inelastic scattering time have been estimated, for the first time, for the alloys
in question
Article presented at the International Symposium on Advances in Superconductivity and Magnetism: Materials, Mechanisms and
Devices, ASMM2D-2001, 25–28 September 2001, Mangalore, India. 相似文献
97.
《Applied Mathematical Modelling》2005,29(8):711-725
The flow field of a turbulent plane jet in a weak or moderate crossflow, which is characterised by mild streamline curvature, has been investigated computationally. The values of the jet-to-crossflow velocity ratios chosen are 6, 9 and 10. The time-averaged Navier–Stokes equations are solved on a staggered Cartesian grid using the standard k–ϵ model and the k–ϵ model with streamline curvature modification. The predictions using both the models are compared with available experimental data. It has been shown that by accounting for the effect of streamline curvature in the k–ϵ model results in good prediction of this flow configuration. 相似文献
98.
A homologous series of azomesogens, 2″-[4-(4′-n-alkoxybenzoyloxy)-2-chlorophenylazo] naphthalenes, with lateral chloro groups was synthesised. All the homologues synthesized
exhibit enantiotropic nematic mesophase. The mesomorphic properties of the present series are compared with other structurally
related series to evaluate the effect of lateral chloro group and its position on mesomorphism
This paper was presented at the 10th National Conference on Liquid Crystals held at Bangalore, India during 9–11 October 2003. 相似文献
99.
We consider a quark model based on QCD scale anomaly in which the quarks move in the field of an effective glueball field.
Hadrons correspond to solitonic bags of higher energy density in a nonperturbative sea of condensed gluons. We calculate the
static properties of nucleon in this model and find that the nucleon mass is far too large (2.4–4 GeV) and the proton charge
radius (0.37–0.54 fm) is low. The proton gyromagnetic ratio and gA/gv are in reasonable agreement with the experimental numbers. 相似文献
100.
Experimental Techniques - MDRMIN consists of k numbers of identical N/k multistage networks in k planes having k × 1 multiplexers and 1 × k demultiplexers at input and output,... 相似文献