全文获取类型
收费全文 | 3566篇 |
免费 | 255篇 |
国内免费 | 713篇 |
专业分类
化学 | 3231篇 |
晶体学 | 89篇 |
力学 | 58篇 |
综合类 | 9篇 |
数学 | 347篇 |
物理学 | 800篇 |
出版年
2024年 | 4篇 |
2023年 | 115篇 |
2022年 | 75篇 |
2021年 | 145篇 |
2020年 | 137篇 |
2019年 | 37篇 |
2018年 | 39篇 |
2017年 | 45篇 |
2016年 | 69篇 |
2015年 | 102篇 |
2014年 | 184篇 |
2013年 | 198篇 |
2012年 | 308篇 |
2011年 | 305篇 |
2010年 | 225篇 |
2009年 | 281篇 |
2008年 | 321篇 |
2007年 | 328篇 |
2006年 | 339篇 |
2005年 | 253篇 |
2004年 | 200篇 |
2003年 | 125篇 |
2002年 | 101篇 |
2001年 | 86篇 |
2000年 | 131篇 |
1999年 | 63篇 |
1998年 | 48篇 |
1997年 | 39篇 |
1996年 | 47篇 |
1995年 | 24篇 |
1994年 | 35篇 |
1993年 | 41篇 |
1992年 | 32篇 |
1991年 | 23篇 |
1990年 | 9篇 |
1989年 | 5篇 |
1988年 | 10篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1976年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有4534条查询结果,搜索用时 15 毫秒
991.
Ultrasound-promoted synthesis of γ-graphyne for supercapacitor and photoelectrochemical applications
As a novel type of carbon materials, graphynes possesses the merits of high carrier mobility and large surface areas, etc. However, to date, the main research of graphynes is focused on theoretical calculation whereas few strategies have been reported for the fabrication of graphynes. In this work, a facile method named ultrasound-promoted synthesis was developed to fabricate γ-graphyne using PhBr6 and CaC2 as the raw materials. The reaction system in argon atmosphere ultrasonically vibrated for 24 h in the ultrasonic bath at a power of 180 W and frequency of 53 kHz. The structure, morphology, and component of the obtained samples were detected by X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, FT-IR spectra, scanning electron microscopy, transmission electron microscopy, and the selected area electron diffraction. The electrochemical and photoelectrochemical measurements indicate that γ-graphyne can be used as superior electrode mateirals in supercapacitor and photoelectrochemical catalysis. From the results of galvanostatic charge/discharge measurements, the γ-graphyne supercapacitor delivers a maximum specific capacitance of 81 F/g at 0.2 A/g and a capacitance retention rate of 87.5% after 5000 cycles at 3 A/g. Moreover, UV-vis light photoelectrochemical response and high carrier density are observed for γ-graphyne. It is also demonstrated that the charge-transfer resistance is low by Tafel slopes and Nyquist plots. This work puts forward a new and facile strategy for the fabrication of γ-graphyne and explores its application in the field of solar energy conversion and storage. 相似文献
992.
993.
994.
Dihydropyrazole‐bridged dinuclear ferrocenyl derivatives (3a–3c) have been synthesized by the reaction of 1,3‐diferrocenyl‐2‐propen‐1‐on (1) with hydrazine, then acylation with acyl chloride directly. The structures were determined by mass spectrometry, IR and 1H NMR spectroscopy. The compound 3c was characterized by single‐crystal X‐ray analyses. It was found that compounds 3a–3c have significant catalytic effect on the decomposition of ammonium perchlorate (AP). Compared with the thermal decomposition of pure AP, adding 3a, 3b and 3c in AP decreases its decomposition temperature by 78.8, 74.3 and 57.1 °C, respectively. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
995.
Three-dimensional(3-D)saucer-and rod-like WO3 microstructures have been synthesized by a simple hydrothermal route using tartaric acid as the assistant agent.X-ray powder diffraction(XRD)patterns indicate that the as-prepared samples are the pure hexagonal phase WO3.The morphologies are characterized by scanning electron microscope(SEM)and are found to be highly sensitized to the reaction temperature.A probable formation mechanism of the WO3 microstructures from saucer-like at low temperatures to rod-like at high temperatures is proposed.The optical properties of the novel WO3 microstructures are studied by UV-vis diffuse reflectance spectroscopy(DRS).The mechanism of strong absorption at visible region and red shift of calcined sample is also discussed. 相似文献
996.
Hydrothermal carbonization of sucrose was used to controllably synthesize Montroseite VOOH and Paramontroseite VO2 nanoparticles carbonaceous core-shell microspheres. After calcinations, V2O3-VO2-C core-shell microspheres were obtained. When they were used as cathode materials in lithium-ion battery (LIB), it was found that Montroseite VOOH carbonaceous core-shell microspheres exhibited higher discharge capacity than Paramontroseite VO2 counterpart, while the content of V2O3 had some large effects on the electrochemical properties of V2O3-VO2C core-shell microspheres. 相似文献
997.
998.
A boundary element method is presented for the coupled motion analysis of structural vibration with small-amplitude fluid
sloshing in two-dimensional space. The linearized Navier-Stokes equations are considered in frequency domain and transformed
into boundary integral equations. An appropriate fundamental solution for the Helmholtz equation with pure imaginary constant
is found. The condition of zero-stress is imposed on the free surface, and non-slip condition of fluid particles is imposed
on the walls of the container. For rigid motion models, the expressions for added mass and added damping to the structural
motion equations are obtained. Some typical numerical examples are presented. 相似文献
999.
6β,7β,14β-Trihydroxy-1α-acetoxy-7α,20-epoxy-ent-kaur-16-en-15-one was isolated from the natural plant of Isodon japonica (Burm.f), Haravar. galaucocalyx (maxim) Hara. The structure was elucidated by means of spectral and chemical studies. In addition, its crystal was determined by single-crystal X-ray diffraction analysis. It crystallizes in triclinic, space group P1, Z = 2, a = 6.3506(4), b = 13.5766(8), c = 15.2777(9) , α = 80.506(1), β = 83.856(1), γ = 88.307(1)o, C25H36O9, Mr = 480.54, V = 1291.64(13) 3, Z = 2, Dc = 1.236 g/cm3, F(000) = 516, μ = 0.093 mm-1, S = 0.988, the final R = 0.0761 and wR = 0.1955. Flack factor is 0.02(19), and the largest peak and deepest hole on the final difference Fourier map are 0.556 and –0.265 e/3, respectively. The X-ray diffraction shows the existence of intermolecular C–H…O (DA) hydrogen bonds between adjacent molecules. 相似文献
1000.
Taohai Li Shuiying Gao Feng Li Rong Cao 《Journal of colloid and interface science》2009,338(2):500-505
The photocatalytic activity composite films incorporating the Keggin-type polyoxometalates (POM) K6CoW12O40·16H2O and K3PW12O40·nH2O (MW12 (M = P, Co)) and [Cu(II)(1,8-dimethyl-1, 3, 6, 8, 10, 13-hexaazacycloteradecane)]2+(L) have been prepared by the layer-by-layer (LbL) self-assembly method. The experimental results show that the deposition process is linear and highly reproducible from layer to layer. Atomic force microscopy (AFM) images of the L/MW12 composite films indicate that the film surface is relatively uniform and smooth. In addition, the films show high photocatalytic activity to the degradation of organic dye model (methyl orange (MO)), attributed to the formation of an O → W charge-transfer excited state at W–O–W bridge bond, resulting in generating highly reactive holes and electrons; The photocatalytic efficiency of the films have little change after several times of photocatalytic cycle, indicating that the composite films are stable, reused and recovered. 相似文献