Axi-symmetric wave propagation in a cylinder coated with a piezoelectric layer

This paper presents the wave propagation in a cylinder coated with a thin piezoelectric layer. The piezoelectric coupling effects are fully modeled in the mechanics model for this piezoelectric coupled cylindrical shell with bending resistance. The decoupled torsional wave velocity and the dispersion curves for the two- mode shell model are obtained theoretically. The cut-off frequency and phase velocities at limit wave number are also derived. The numerical simulations are conducted to present the results of wave propagation in this cylindrical shell and as well as to compare the results by the current bending theory and the membrane shell theory. From the comparisons, the results display obvious deference of wave propagations in terms of dispersion characteristics by different shell theories when thicker piezoelectric layer are used and when higher wave number is considered. The results of this paper can serve as a reference for future study on wave propagation in coupled structures as well as in the design of smart structures incorporating piezoelectric materials.     

一种提高生物体拉曼光谱痕量测量精度的方法

微量物质拉曼光谱测量精度的提高是拉曼分析技术的难点之一,特别是高荧光背景下生物体中微量物质的测量。根据拉曼谱峰突发、离散特点,分别给出荧光背景和噪声拟合函数,通过监测总体拟合偏差A类不确定度函数实现拉曼谱峰定位和干扰信号滤波;进一步根据谱峰位置划分光谱区间,在单调区间内弱化非谱峰信号,实现谱峰信号增强。与其他光谱处理方法比较,可以准确拆分重叠特征峰,不会降低特征峰高度,提供更加灵敏的半谱峰面积指标。实验表明,该方法在处理皮肤拉曼光谱时,可以准确得到螺旋构象的酰胺I带、神经酰胺和CO的归属拉曼谱峰;另外经过该方法处理后数据建立水溶性糖(水稻叶片)含量测量模型,其精度优于小波分解、多项式拟合和非线性最小二乘法。     

Photoionization of Ru(bpy)32+ ions in aqueous solutions containing sodium dodecyl sulfate. Influence of ion binding

Sodium dodecyl sulfate (SDS) augments the yield of biphotonic ionization of tris-2,2′-bipyridyl ruthenium(II) ions (3.75×10⁻⁵ mol dm⁻³) in aqueous solution at room temperature to different extents at two different concentration ranges: by a factor 4 at [SDS] just below the critical concentration for precipitation (4.5×10⁻⁴ mol dm⁻³) and by a factor 1.4 at [SDS] above the critical micellar concentration (8×10⁻³ mol dm⁻³). The augmentation of the photoionization yield is explained in terms of ion binding, i.e. electrostatic interaction between Ru(bpy)₃²⁺ ions and dodecyl sulfate ions which results in a partial charge neutralization with the consequence of a decrease in the ionization potential.     

An unusual electrochemically induced demetalation of iron-substituted Keggin-type undecatungstozincate ZnW11FeIII(H2O)O7−39

Firstly reported for Fe-containing transition metal substituted polyoxometalates was an unusual Fe-centered demetalation process induced by the reduction of ZnW₁₁Fe^III to ZnW₁₁Fe^II, which resulted in a new couple of Fe-relating redox waves at positive potentials.     

Study on Molybdenum(v)-Thiocyanate Complex in Solvent of Dimethyl Sulfoxide with Water in Different Proportional Volume by Spectrophotometry

The stability constant(β_i), molar absorbency (Δε_i), and percentage of composition([MoO(SCN)_i]^3-i%) (i=1,2,3) of molybdenum(V)-thiocynate complex were determined. All reagents employed are analytical grade.     

高效液相色谱法快速测定冰淇淋中的糖精钠

用高效液相色谱法快速测定了冰淇淋中的糖精钠。使用反相径向加压柱,紫外检测定量。样品用硫酸铜及氢氧化钠处理后,滤液不用萃取即可上机检测。方法的最低检测限为0．38mg／kg,变异系数为1．72％,回收率为96．25％。     

新型二维气相色谱系统的理论研究──双柱条件对保留时间及峰扩展的影响

从色谱动力学角度推导出微填充柱-毛细管柱二维气相色谱系统流出曲线一级矩及二级中心矩的表达式,并据此讨论了柱温、柱间分流比等条件对保留时间及峰扩展的影响规律。结果表明:柱间分流是主毛细管柱与预微填充柱之间联系的纽带,分流比是影响峰特征的重要因素。预柱条件的改变对二维气相色谱保留时间及峰扩展的影响较小。双柱条件对峰特征的影响表现出一些特殊的规律性。     

气相色谱SnO_2/SnCl_2半导体检测器的研制

对SnO2／SnCl2半导体气敏元件的制作及其用于气相色谱检测的最佳条件、响应灵敏性、检测范围等方面予以讨论。     

多维液相色谱-质谱用于酶解猪血蛋白中活性肽的研究

以强阳离子交换柱（SCX）为一维色谱柱,反相柱（RP）为二维色谱柱,采用在线捕集接口形式,通过10通阀连接一、二维色谱柱,构建了二维液相色谱分离系统。将该系统用于酶解猪血蛋白中对血管紧缩素Ⅰ转移酶（ACE）具有活性抑制作用的肽进行分离、鉴定,共检测出104个组分。收集一维馏分,离线注入LC—MS,鉴定出其中含有SAL、DKF、ESF、STVL及FESF5个小肽。     

g-C3N4基异质结的光催化应用研究进展

半导体异质结光催化剂因其在太阳能利用和转化方面广阔的应用前景而备受关注。合理构建两种或两种以上半导体材料的异质结构,可以集成多种组分的优点,改善光生电荷分离,扩大对可见光的吸收范围,保持光催化剂的高氧化还原能力。近年来,由于g-C₃N₄具有合成简单、稳定性高、独特的光学和电学特性等诸多优点,g-C₃N₄基异质结构的构建成为研究热点。本文针对近年来g-C₃N₄基异质结改性的研究现状,依据g-C₃N₄与其他半导体电荷转移路径的不同综述了三种异质结结构(g-C₃N₄基Ⅱ型异质结、g-C₃N₄基Z型异质结和g-C₃N₄基S型异质结),以及其在环境修复和能源方面的应用。最后对g-C₃N₄基异质结光催化剂存在的问题进行总结和展望。