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101.
102.
通过考虑横法向热变形,本文建立了预先满足层间应力连续的C0型整体-局部高阶层合梁理论,并用于分析复合材料层合梁热膨胀和热弯曲问题。虽然考虑了横法向应变,不增加额外的位移变量。此理论位移场不含有横向位移一阶导数,便于构造多节点高阶单元。基于虚功原理推导了复合材料层合梁平衡方程,并分析了简支多层复合材料梁热膨胀和热弯曲问题。数值结果表明,建立的模型能准确分析复合材料层合梁热膨胀和热弯曲问题,忽略横法向应变的理论分析热膨胀问题误差较大。 相似文献
103.
Influence of Cu ion implantation on the microstructure and cathodoluminescence of ZnS nanostructures
The microstructure and optical properties of as-synthesized and Cu ion implanted ZnS nanostructures with branched edges are studied by using high-resolution transmission electron microscope (TEM) and spatially-resolved cathodoluminescence measurement. Obvious crystalline deterioration has been observed in Cu-doped ZnS nanostructures due to the invasion of Cu ions into ZnS lattice. It was found that the optical emissions of ZnS nanostructures can be selectively modified through the control of Cu ion dose and subsequent heat treatment. An increase of Cu dopant content will lead to an apparent red-shift of the intrinsic band-gap emission in the UV range and the broadening of defect-related emission in visible range. The influences of Cu ion implantation on the microstructure and related optical properties were discussed. 相似文献
104.
Magnetization of anisotropic quantum dots in the presence of the Rashba spin–orbit interaction has been studied for three and four interacting electrons in the dot for non-zero values of the applied magnetic field. We observe unique behaviors of magnetization that are direct reflections of the anisotropy and the spin–orbit interaction parameters independently or concurrently. In particular, there are saw-tooth structures in the magnetic field dependence of the magnetization, as caused by the electron–electron interaction, that are strongly modified in the presence of large anisotropy and high strength of the spin–orbit interactions. We also report the temperature dependence of magnetization that indicates the temperature beyond which these structures due to the interactions disappear. Additionally, we found the emergence of a weak sawtooth structure in magnetization for three electrons in the high anisotropy and large spin–orbit interaction limit that was explained as a result of merging of two low-energy curves when the level spacings evolve with increasing values of the anisotropy and the spin–orbit interaction strength. 相似文献
105.
This research article presents development of an economical, simple, immune and environment friendly process to grow few-layer graphene by controlling evaporation rate of polystyrene on copper foil as catalyst and substrate utilizing atmospheric pressure chemical vapor deposition (APCVD) method. Evaporation rate of polystyrene depends on molecular structure, amount of used material and temperature. We have found controlling rate of evaporation of polystyrene by controlling the source temperature is easier than controlling the material weight. Atomic force microscopy (AFM) as well as Raman Spectroscopy has been used for characterization of the layers. The frequency of G′ to G band ratio intensity in some samples varied between 0.8 and 1.6 corresponding to few-layer graphene. Topography characterization by atomic force microscopy confirmed Raman results. 相似文献
106.
This paper presents a new approach to asymptotic synchronization problems based on regulation of connection weights for a class of Cohen–Grossberg neural networks with bounded time-varying delays. By using the adaptive technique, this approach requires no information about weights and bounds of amplification and activation functions, as well as the bounds of time-delays. As opposed to other existing methods, the adverse effects of delays can be completely eliminated by regulating weights and without using any control inputs. Through Lyapunov functions and adaptive schemes, we prove the regulation laws can ensure the neural network asymptotically synchronize to the targeted equilibrium point. The proposed theoretical result is finally evaluated in the light of a simulation example. 相似文献
107.
基于新的各向异性修正偶应力理论提出一个Mindlin复合材料层合板稳定性模型。该理论包含纤维和基体两个不同的材料长度尺度参数。不同于忽略横向剪切应力的修正偶应力Kirchhoff薄板理论,Mindlin层合板考虑横向剪切变形引入两个转角变量。进一步建立了只含一个材料细观参数的偶应力Mindlin层合板工程理论的稳定性模型。计算了正交铺设简支方板Mindlin层合板的临界载荷。计算结果表明该模型可以用于分析细观尺度层合板稳定性的尺寸效应。 相似文献
108.
基于新修正偶应力理论建立了一个Reddy型复合材料层合板稳定性模型。该理论中曲率张量不对称,而偶应力矩张量对称。Reddy型层合板模型能够满足横向剪切应力为0的自由表面条件,而且横向剪切为二次函数,避免了常剪力一阶理论需要引入的剪力修正系数。为了便于工程应用,通过虚功原理推导了只含纤维材料尺度参数正交铺设的Reddy型层合板偶应力模型的稳定性方程,并以微尺度正交铺设四边简支层合方板为例,分析了不同铺设角和轴向载荷作用时临界载荷的细观尺度效应,并且与一阶剪切变形和Kirchhoff板理论结果对比。结果表明,本文建立的新修正偶应力Reddy型层合板模型更适合分析较厚的复合材料层合板稳定性的尺度效应。 相似文献
109.
用甲基三辛基氯化铵和钨酸钠一步法合成甲基三辛基季铵钨酸盐离子液体[(CH3)N(n-C8H17)3]2W2O11,以该离子液体为催化剂,在无反应溶剂条件下催化过氧化氢氧化苯甲醇生成苯甲酸。 考察了反应温度、催化剂用量以及氧化剂过氧化氢用量对苯甲酸产率的影响。 确定优化条件:反应温度70 ℃,苯甲醇用量5 mmol,催化剂用量是底物的0.4%(摩尔分数),30%过氧化氢用量2 mL,苯甲醇的转化率可达99%,苯甲酸选择性为98%。 该方法具有反应条件温和、产率高和选择性好的优点。 相似文献
110.
Hydrogen-bonded Intramolecular Charge Transfer Excited State of Dimethylaminobenzophenone using Time Dependent Density FunctionalTheory 下载免费PDF全文
Yu-ling Chu Zhong Yang Zhe-feng Pan Jing Liu Yue-yi Han Yong Ding Peng Song 《化学物理学报(中文版)》2012,25(6):654-658
Density functional theory and time-dependent density-functional theory have been used to investigate the photophysical properties and relaxation dynamics of dimethylaminobenzophe-none (DMABP) and its hydrogen-bonded DMABP-MeOH dimer. It is found that, in non-polar aprotic solvent, the transitions from S0 to S1 and S2 states of DMABP have both n→π* and π→π* characters, with the locally excited feature mainly located on the C=O group and the partial CT one characterized by electron transfer mainly from the dimethylaminophenyl group to the C=O group. But when the intermolecular hydrogen bond C=O…H-O is formed, the highly polar intramolecular charge transfer character switches over to the first excited state of DMABP-MeOH dimer and the energy difference between the two low-lying electronically excited states increases. To gain insight into the relaxation dynamics of DMABP and DMABP-MeOH dimer in the excited state, the potential energy curves for con-formational relaxation are calculated. The formation of twisted intramolecular charge trans-fer state via diffusive twisting motion of the dimethylamino/dimethylaminophenyl groups is found to be the major relaxation process. In addition, the decay of the S1 state of DMABP-MeOH dimer to the ground state, through nonradiative intermolecular hydrogen bond stretching vibrations, is facilitated by the formation of the hydrogen bond between DMABP and alcohols. 相似文献