层状双金属氢氧化物微观结构与性质的理论研究进展

总结了近年来理论计算方法在研究层状双金属氢氧化物(LDHs)结构与功能方面的应用现状. 结合LDHs材料的结构特点, 归纳了量子力学、分子力学、几何建模及物理静电模型相结合对LDHs材料进行结构模拟的思路, 比较了各种方法在LDHs结构模拟上的优势及存在的不足. 量子力学方法能够精确获得水滑石材料的层板构成及作用机制、简单阴离子插层水滑石主客体间的超分子作用实质以及电子性质、反应机理等方面的信息. 与量子力学相比较, 分子力学方法可以快速得到插层水滑石材料的层间阴离子排布及取向、水合膨胀特性及宏观力学性质等. 几何模型和物理静电模型能构建直观、形象的数学模型, 大大简化了计算量,因此能计算接近实际LDHs尺寸的体系, 为推测LDHs结构信息提供了可能性. 随着理论方法和计算机硬件水平的发展, 使得计算机模拟技术逐渐成为获得LDHs材料微观结构参数、电子性质和动力学性质的一种有效手段.     

Effects of CO2 concentration and moisture content of sugar-free media on the tissue-cultured plantlets in a large growth chamber

The dynamic fluctuations of CO₂ concentration in the tissue culture growth chamber after transplantation of petunia, chrysanthemum and tomato plantlets were recorded with a real-time control system to determine the critical CO₂ concentration levels of 35 μl l^?1 at which CO₂ enrichment is needed. The experimental data showed that the tissue-cultured plantlets of petunia, chrysanthemum and tomato had the same CO₂ concentration dynamics. The results indicated that CO₂ enrichment was proper on the second day after transplantation. Petunia plantlets were used to conduct experiments under PPFD of 80 μmol m^?2 s^?1, and CO₂ concentrations of 350 ± 50 μl l^?1, 650 ± 50 μl l^?1 and 950 ± 50 μl l^?1 as well as medium moisture contents of 60%, 70% and 80%, with the result that plantlets grew better under CO₂ concentration of 650 ± 50 μl l^?1 than under the other two concentrations with all the different media water contents. Three media water contents under the same CO₂ concentration produced plantlets with the same quality. The impacts of CO₂ concentrations on plantlets are more important than those of the media water contents. Sugar-free tissue culture, as compared with the conventional culture, showed that CO₂ enrichment to 350 ± 50 μl l^?1 can promote the growth of the cultured plantlets. Sugar-free tissue culture produced healthy plantlets with thick roots, almost equivalent to the common plantlets.     

Precise asymptotics in complete moment convergence of the associated counting process

Let be the associated counting process. In this paper, we prove the precise asymptotics in complete moment convergence of the associated counting process generated by i.i.d. random variables.     

含稀土铕络合物的三元共聚物的光电性质

合成了可平衡电荷(空穴与电子)传输的三功能合一的稀土铕发光材料,将几种稀土铕络合物单体与乙烯基咔唑、甲基丙烯酸甲酯共聚制得含咔唑和稀土铕络合物的空穴传输层发光层电子传输层(HTLEMLETL)三功能合一的聚合物,并研究它们的电化学及电致发光性能.电化学分析表明这类三元共聚物兼有氧化性和还原性,氧化电位及还原电位分别为0.75V和-1.8V左右,可见这类材料同时具有空穴传输和电子传输功能.从测定的电致发光谱看,AlQ3、TPD及咔唑基等发光单元在器件中没有共发光,而是起电荷传输作用,以这些材料制作的电致发光器件所发的红光纯度都比较高.     

Asymptotical stability of multi-delayed cellular neural networks with impulsive effects

In this work, the stability issues of the equilibrium points of multi-delayed cellular neural networks with impulsive effects are investigated. Based on the method of linear matrix inequality (LMI) and parameterized first-order model transformation, several new delay-dependent and delay-independent asymptotical stability conditions are derived by the stability theory of Lyapunov–Krasovskii. A numerical example is given to illustrate the effectiveness of our results.     

Nonorthogonal Wavelet Packets with r Scaling Functions

In this paper, we discuss the multiresolution analysis generated by finite scaling functions ¹, ²,... , , ^r in L²(R). We also consider the direct wavelet decomposition and direct wavelet packet decomposition in L²(R). Besides, we obtain some results about (dual) nonorthogonal wavelet packet as well as the stability of the basis generating the packet. At last, we give an example of nonorthogonal wavelet packets of multiplicity r by using fractal interpolation functions.     

The topological AC effect on non-commutative phase space

The Aharonov–Casher (AC) effect in non-commutative (NC) quantum mechanics is studied. Instead of using the star product method, we use a generalization of Bopp’s shift method. After solving the Dirac equations both on non-commutative space and non-commutative phase space by the new method, we obtain corrections to the AC phase on NC space and NC phase space, respectively. PACS 02.40.Gh; 11.10.Nx; 03.65.-w     

氨基膦酸树脂对汞的吸附性能及其机理

研究了Hg2+在氨基膦酸树脂上的吸附行为。结果表明:静态饱和吸附容量为 581.9mg/g树脂,用0.5mol/L的HCl和0.2~0.3mol/L的EDTA洗脱,洗脱率分别为:97%和99%以上;测得吸附热力学参数分别为: △H=8.45kJ/mol,△G=-3.02kJ/mol,△S= 38.5J/mol稫。等温吸附服从Freundlich经验式;表观活化能Ea=13.6kJ/mol,表观速率常数k298=2.46×10-5/s;树脂功能基与Hg2+的配位比为1∶1;并用化学和红外光谱的方法探讨了树脂对Hg2+的吸附机理。     

关于多指标变量大数律尾概率级数的完全收敛性

本文对iid多指标随机变量序列的部分和及H(t)↑+∞,(t→+∞),提出并讨论了Порохоров的3个问题(d≥2),并讨论了多指标随机变量和的完全收敛性.     

甲基苯基氯硅烷和苯基三氯硅烷混合物的GC-MS分析

使用GC—MS分析热缩合法生产的氯硅烷粗单体时,发现甲基苯基二氯硅烷和苯基三氯硅烷在HP-5毛细管柱上难以得到有效的分离。采用过量甲醇对粗产品氯硅烷进行甲氧基化后,甲基苯基二氯硅烷和苯基三氯硅烷相应的甲氧基化产物在色谱柱上能得到有效的分离,可为其色谱分析提供依据。