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151.
152.
Jun-Wei Yang Jing Zhang Yan Yan Xiao-Chun Huang Shan-Ling Tong 《Solid State Sciences》2010,12(7):1242-1247
A first example of 1D coordination polymer [MnTHPP·H2O·(DMF)2 (1)] with right-handed helicity and opticity was successfully assembled. Crystal analyses indicate that the right-handed helical assembly is based on coordination bonds from peripheral to center, associating with the saddle distortion of the molecular planes. In its crystal architecture, MnTHPP [manganese (III) ion coordinated by 5,10,15,20-tetra(4-hydroxyphenyl) porphyrin] molecules were ligated each other via the axial coordination between –PhO? → MnIII (peripheral to center model, from the peripherally deprotonated hydroxyphenyl to the central metal of the neighbor molecule) to construct the right-handed helices, and the helices are sustained by plentiful hydrogen bonding. Meanwhile DMF molecules are entrapped within the voids among the helices. This is a rare example of the multiporphyrin arrays with right-handed helices bearing opticity. 相似文献
153.
On the basis of the resonance light scattering (RLS) of Ag nanoparticles (AgNPs), an RLS off–on system was developed for studies
of the selective interaction between adriamycin (ADM) and DNA. In this strategy, addition of ADM could induce a proportional
decrease in the RLS intensity of AgNPs; this could be used to detect trace amounts of ADM with a detection limit of 12.75 ng mL−1 in the range 0.021–10.0 μg mL−1. Subsequently, by investigating the ability of different DNA sequences to restore the RLS intensity of the analytical systems,
we found that ADM was selective to dsDNA and had an obvious preference for sequences that were rich in guanine and cytosine
bases. In order to validate the results of the RLS assay, fluorescence quenching was used, and binding constants and binding
numbers of each system were calculated. Compared with other methods, this RLS off–on strategy was more sensitive, fast, and
reliable. It has also supplied a novel method for studying the sequence selectivity of DNA-targeted anticancer drugs and is
a novel application of the RLS technique in analytical chemistry. 相似文献
154.
Chongrui Wu Fuming Zhang Xiangshang Xiao Junyan Chen Junqi Sun Dayakar Gandla Yair Ein-Eli Daniel Q. Tan 《Molecules (Basel, Switzerland)》2021,26(14)
Fabricating electrical double-layer capacitors (EDLCs) with high energy density for various applications has been of great interest in recent years. However, activated carbon (AC) electrodes are restricted to a lower operating voltage because they suffer from instability above a threshold potential window. Thus, they are limited in their energy storage. The deposition of inorganic compounds’ atomic layer deposition (ALD) aiming to enhance cycling performance of supercapacitors and battery electrodes can be applied to the AC electrode materials. Here, we report on the investigation of zinc oxide (ZnO) coating strategy in terms of different pulse times of precursors, ALD cycles, and deposition temperatures to ensure high electrical conductivity and capacitance retention without blocking the micropores of the AC electrode. Crystalline ZnO phase with its optimal forming condition is obtained preferably using a longer precursor pulse time. Supercapacitors comprising AC electrodes coated with 20 cycles of ALD ZnO at 70 °C and operated in TEABF4/acetonitrile organic electrolyte show a specific capacitance of 23.13 F g−1 at 5 mA cm−2 and enhanced capacitance retention at 3.2 V, which well exceeds the normal working voltage of a commercial EDLC product (2.7 V). This work delivers an additional feasible approach of using ZnO ALD modification of AC materials, enhancing and promoting stable EDLC cells under high working voltages. 相似文献
155.
A feedback high birefringence fiber loop mirror with a piece of erbium-doped fiber and a polarization controller is newly proposed. When the erbium-doped fiber is properly pumped to offset the loss of the feedback ring in the loop mirror, narrowband transmission peaks with large effective free spectral range can be achieved by the intrinsic vernier effect between orthogonally polarized lights respectively traveling along the two primary axes of the high birefringence fiber. In addition, the side transmission suppression ratio can reach about 6 dB. These special properties are independent of the polarization state of the input signal, which makes it feasible for the proposed feedback high birefringence fiber loop mirror to be employed as a narrowband filter in single-frequency fiber lasers. 相似文献
156.
Yi Yuan Guo‐Qiang Zhang Feng Lu Prof. Qing‐Xiao Tong Qing‐Dan Yang Hin‐Wai Mo Dr. Tsz‐Wai Ng Dr. Ming‐Fai Lo Dr. Zheng‐Qing Guo Chuan Wu Prof. Chun‐Sing Lee 《化学:亚洲杂志》2013,8(6):1253-1258
A new triphenylamine‐bridged fluoranthene derivative, 4‐(7,10‐diphenylfluoranthen‐8‐yl)‐N‐[4‐(7,10‐diphenylfluoranthen‐8‐yl)phenyl]‐N‐phenylaniline (BDPFPA), with a high glass transition temperature of 220 °C has been synthesized and characterized. BDPFPA is a highly fluorescent and versatile material that can be used as a nondoped green emitter and as a hole transporter. BDPFPA was used in a standard trilayer device as the emitting layer, which showed a low turn‐on voltage (<3 V) and a high efficiency of 11.6 cd A?1. The device also shows little efficiency roll‐off at high brightness. For example, the efficiency can still be maintained at 11.4 cd A?1 (5.4 lm W?1) at a brightness of 10 000 cd m?2. These results are among the best reported for nondoped fluorescent green organic light‐emitting diodes. A simple bilayer device, in which BDPFPA serves as a hole‐transporting layer, has a maximum power efficiency of 3.3 lm W?1 and the performance is nearly 40 % higher than that of an N,N′‐bis(1‐naphthyl)‐N,N′‐ diphenyl‐1,1′‐biphenyl‐4,4′‐diamine (NPB)‐based standard device. 相似文献
157.
本文中采用电弧熔炼和感应熔炼后喷铸的方法制备了厚度为4 mm的Fe基块体非晶合金. 通过对Fe41Co7Cr15Mo14C15B6Y2块体非晶合金进行30次和60次冷热循环处理,并在往复式摩擦磨损条件下,研究冷热循环工艺对其摩擦磨损性能的影响. 结果表明:冷热循环处理没有显著改变铁基非晶合金的非晶态结构. 30次冷热循环处理后,Fe基块体非晶合金发生了明显的软化,平均硬度由铸态的16.06 GPa降为14.06 GPa,平均弹性模量由241 GPa降为216 GPa. 随着冷热循环次数和载荷的增加,非晶合金的平均摩擦系数和磨损率先减小后增大. 冷热循环处理有利于降低非晶合金的平均摩擦系数和磨损量. 当冷热循环次数为30次、载荷为30 N时,铁基非晶的摩擦系数由0.77降至0.72,表现出最小的摩擦系数,同时磨损率降低13.3%,表现出最小的磨损率[1.04×10?6 mm3/(m·N)]. 铸态Fe基块体非晶合金的磨损机理以疲劳断裂为主,伴随着轻微的磨粒磨损. 随着冷热循环次数的增加,疲劳导致的脆性断裂程度降低,磨损机制向磨粒磨损和疲劳断裂的共同作用转变. 所以,冷热循环处理有望成为调控非晶态金属材料摩擦学性能的有效手段. 进一步深化对冷热循环处理的理解,必将有利于推动非晶态材料在摩擦学领域的应用. 相似文献
158.
159.
The Singular Structure of Non-selfsimilar Global Solutions of n Dimensional Burgers Equation 总被引:1,自引:0,他引:1
Xiao-zhou Yang 《应用数学学报(英文版)》2005,21(3):505-518
We investigate the singular structure for n dimensional non-selfsimilar global solutions and interaction of non-selfsimilar elementary wave of n dimensional Burgers equation, where the initial discontinuity is a n dimensional smooth surface and initial data just contain two different constant states, global solutions and some new phenomena are discovered. An elegant technique is proposed to construct n dimensional shock wave without dimensional reduction or coordinate transformation. 相似文献
160.
Recently, a room temperature electrically induced metastability in semi-insulating (SI)-GaAs has been reported in which the normally high resistance state of SI-GaAs converts into a low resistance state when breakdown electric fields are applied to the metal/SI-GaAs/metal system. The low resistance state continues to persist when the electric field is lowered below the breakdown bias and as such may be treated as metastable state of the material. This phenomenon is believed to be closely related to the ‘lock-on’ effect utilized in high power photoconductive semiconductor switches made from SI-GaAs. The present study seeks to understand the mechanism for this electrically induced metastability by studying the influence of the injection current on the metastable phase. The data favor an interpretation of the high current state of the SI-GaAs in terms of double carrier injection and the sustaining of an internal electron-hole plasma in the material. 相似文献