新型螯合磁性纳米Fe_3O_4的制备及其性能研究

采用共沉淀法制备了磁性四氧化三铁(Fe3O4)纳米粒子,并通过硅烷偶联剂对其表面进行改性,进一步在其表面偶联修饰氨基硫脲,制备了螯合磁性纳米Fe3O4粒子。利用广角X射线衍射仪(WAXD)、红外光谱仪(FTIR)、分光光度计等对磁性纳米粒子的结构和性能进行了表征。结果表明,纳米Fe3O4为反尖晶石结构,通过偶联修饰可以实现氨基硫脲在纳米粒子表面的化学改性。螯合磁性纳米粒子具有良好的分散性和磁响应性,且对多种金属离子(Pb2+、Hg2+、Zn2+、Cd2+)具有良好的螯合效果。     

光谱法研究PA612/TPU熔融共混体系相互作用

采用熔融共混制备尼龙(PA)612/热塑性聚氨酯(TPU)复合材料,通过广角X射线衍射仪(WAXD)和傅里叶变换红外光谱仪(FTIR)研究了PA612和TPU之间的相互作用。WAXD结果表明,TPU的加入影响了PA612的结晶完善度,且随着TPU含量的增加,PA612的结晶度逐渐降低。FTIR的结果证实了共混样品中PA612与TPU形成了新的氢键,且熔融共混过程中两组分之间有少量化学反应发生。     

m次数量幂等矩阵线性组合的可逆性

如果有非零数λ与μ使Pm=λP,Qm=μQ,则称P,Q分别是由λ,μ确定的m次数量幂等矩阵．本文证明了,若有非零数a与b,当μam-1（-1）m-1μbm-1≠0时,使可交换的分别由λ,μ确定的m次数量幂等矩阵P,Q的线性组合aP＋bQ是可逆的,那么对任意非零数u,u,当λμm-1-（-1）m-1μvm-1≠0时,uP＋vQ也是可逆的．本文主要结果和方法的应用,可以推广已有文献的2次、3次幂等矩阵的线性组合可逆的结论．     

基于调制方向提取载波散斑条纹中心线的方法

条纹中心线法是一种重要的电子散斑干涉条纹解调方法,其前提条件是获得高准确度的条纹中心线.本文在分析载波电子散斑干涉条纹自身特征的基础上,提出了一种基于载波条纹调制方向提取条纹中心线的方法.该方法首先通过同态滤波有效滤除高频乘性散斑噪音,提取出载波条纹;然后应用基于调制方向提取中心线算法确定载波条纹灰度极值点并做二值化处理;再采用基于中心线拟合或者基于条纹间距的边沿中心线补偿法,获得完整的条纹中心线图.实验结果表明:该方法简单、可靠,能快速、准确地提取出连续的中心线.     

（m，l）幂等矩阵的代数等价与正交的一些性质

应用数域上（m,l）幂等矩阵与m幂等矩阵的关系,得到了数域上（m,l）幂等矩阵的l次方幂的代数等价、相似和特征多项式相等是互为确定的结论,由此推广改进了数域上m幂等矩阵的代数等价与正交性的相应结果．     

Improved cell morphology and reduced shrinkage ratio of ETPU beads by reactive blending

Thermoplastic polyurethane foam beads (ETPU) have attracted attention of researchers in recent years due to their wide use in industrial applications. In this study, a small amount of acrylonitrile-butadiene-styrene copolymer (ABS) was blended with TPU under the assistance of dicumyl peroxide (DCP) and maleic anhydride (MAH) to improve the cell morphology and reduce shrinkage ratio of the resulting blends. These blends were then foamed to prepare TPU/ABS blends foam beads in an autoclave using supercritical CO₂ as the blowing agent at different temperatures and FTIR spectra, and rheological and foaming properties of the samples were evaluated. The melt viscosity, melt strength and elasticity of TPU/ABS were improved with the increase of the ABS content. These results were attributed to the grafting and heterogeneous nucleation points provided by the ABS. These enhanced properties were used to produce foams with better cell morphology and increased expansion ratio. Furthermore, the TPU/ABS blends foam beads showed lower shrinkage ratios with increasing ABS content. Thus, the addition of ABS is a facile method for improving the cell morphology and anti-shrinkage properties of ETPU.