催化剂对CaO固硫反应动力学的影响

提高CaO的固硫率是对煤炭燃烧污染防治的研究热点。本研究探索用催化剂提高CaO固硫率的可行性及其对固硫反应动力学的影响。用热天平测试了在CaO中添加不同催化剂的固硫反应的进程,并采用等效粒子模型处理实验数据,计算了表面化学反应控制阶段及产物层扩散控制阶段的动力学参数。实验表明,CaO固硫反应初期为表面化学反应控制阶段,后期转为产物层扩散控制阶段。以碱金属的盐类为催化剂,它们均能使固硫反应前期的化学反应控制阶段的反应活化能下降,并按Li,Na,K,Cs的顺序依次递减,而碱金属盐的负离子主要影响产物层扩散阶段的固硫反应。     

芳香反离子与离子表面活性剂胶团的相互作用

用紫外吸收光谱的方法研究了多种芳香反离子与离子表面活性剂胶团之间的相互作用。发现阳离子表面活性剂和阴离子表面活性剂胶团对芳香反离子的吸收光谱有着显著不同的影响,芳香反离子结构的细微变化可导致光谱特性显著不同。这被解释为阳离子表面活性剂胶团与芳香环之间的阳离子-π相互作用。阳离子-π相互作用需要阳离子表面活性剂分子与芳香反离子具有合适的相对位置与距离。通过测定各混合体系的吸附量证明,不同的芳香反离子在胶团表面有不同的排列方式。NMR的实验结果支持了上述解释。     

The Berlin axisymmetric boundary layer facility

An account is given of the working life of the recently decommissioned axisymmetric turbulent-boundary-layer windtunnel in the Hermann-Föttinger-Institut of the Technische Universität Berlin, and some principal investigations conducted in it.     

Uniqueness of positive solutions of a class of quasilinear ordinary differential equations

Abstract. Uniqueness results are obtained for positive solutions of a class of quasilinear ordi-nary differential equations. The methods rely on the energy analysis and a scale argument.     

LOWER BOUNDS ON THE MAXIMUM GENUS OF LOOPLESS MULTIGRAPHS

§ 1　IntroductionThe maximum genusγM(G) of a graph G is the maximum among the genera,which Ghas a cellularembedding on a sphere with k handles.Since any embedding of G has atleastone face,by Euler polyhedral equation,itcan be obtained thatγM(G)≤β(G) / 2 ,whereβ(G) is the Betti number of G.A graph G is called up-embeddable ifγM(G) =β(G) / 2 .[1 ] has showed that thereare atleasttwo edge-disjointspanning trees in G if G is 4 -edge connected.Let T be a span-ning tree of G.An odd …     

A semi-analytical approach to Biot instability in a growing layer: Strain gradient correction,weakly non-linear analysis and imperfection sensitivity

Many experimental works have recently investigated the dynamics of crease formation during the swelling of long soft slabs attached to a rigid substrate. Mechanically, the spatially constrained growth provokes a residual strain distribution inside the material, and therefore the problem is equivalent to the uniaxial compression of an elastic layer.The aim of this work is to propose a semi-analytical approach to study the non-linear buckling behaviour of a growing soft layer. We consider the presence of a microstructural length, which describes the effect of a simple strain gradient correction in the growing hyperelastic layer, considered as a neo-Hookean material. By introducing a non-linear stream function for enforcing exactly the incompressibility constraint, we develop a variational formulation for performing a stability analysis of the basic homogeneous solution. At the linear order, we derive the corresponding dispersion relation, proving that even a small strain gradient effect allows the system to select a critical dimensionless wavenumber while giving a small correction to the Biot instability threshold. A weakly non-linear analysis is then performed by applying a multiple-scale expansion to the neutrally stable mode. By applying the global conservation of the mechanical energy, we derive the Ginzburg–Landau equation for the critical single mode, identifying a pitchfork bifurcation. Since the bifurcation is found to be subcritical for a small ratio between the microstructural length and the layer׳s thickness, we finally perform a sensitivity analysis to study the effect of the initial presence of a sinusoidal imperfection on the free surface of the layer. In this case, the incremental solution for the stream function is written as a Fourier series, so that the surface imperfection can have a cubic resonance with the linear modes. The solutions indicate the presence of a turning point close to the critical threshold for the perfect system. We also find that the inclusion of higher modes has a steepening effect on the surface profile, indicating the incipient formation of an elastic singularity, possibly a crease.     

Comparison of the texture functions describing the grain alignment in NdFeB magnets

Two types of Gaussian distribution function (`θ type’ and `tan θ type') describing the degree of grain alignment in sintered NdFeB magnets have been compared in the distribution coefficient σ (or σ_g), the distribution probability P(θ) and the grain alignment dependence of coercivity. The results show that when the grain alignment is good (the ratio of remanence-to-saturation polarization J_r/J_s⩾0.90), σ(σ_g) and P(θ) for the two types of Gaussian functions have similar variation tendencies, the calculated values of normalized coercivity based on the starting field theory are basically the same and are consistent with experiments. When the grain alignment is not good (J_r/J_s⩾0.80), the variation tendencies of σ and P(θ) are different. In addition, according to `tan θ type’ Gaussian function, the theoretical values of the normalized coercivity based on the starting field theory are still consistent with the experiments, but according to `θ type’ Gaussian function, the theoretical values seriously deviate from the experiments. This means that the `tan θ type’ Gaussian function is a better texture function for describing the grain alignment.