Analysis of stratified thermal storage systems: An overview

The presence of stratification is well known to improve the performance of stratified thermal energy storage systems (STESS). The major energy and exergy methods for modeling and assessing the performance of STESS are reviewed in this presentation. Current analytical and numerical methods for modeling STESS are surveyed, with their strengths and weaknesses. An extensive survey of performance assessment methods based on energy, entropy and exergy analyses is also presented. This survey highlights entropy generation ratios, which are based on second law considerations, as effective in quantifying the improvements in STESS performances that result from the presence of stratification unlike energy-based measures. The entropy generation number, N _s is suggested as an effective tool for future performance studies on STESS.     

An iterative algorithm for solving split equality fixed point problems for a class of nonexpansive-type mappings in Banach spaces

In this paper, an iterative algorithm that approximates solutions of split equality fixed point problems (SEFPP) for quasi-?-nonexpansive mappings is constructed. Weak convergence of the sequence generated by this algorithm is established in certain real Banach spaces. The theorem proved is applied to solve split equality problem, split equality variational inclusion problem, and split equality equilibrium problem. Finally, some numerical examples are given to demonstrate the convergence of the algorithm. The theorems proved improve and complement a host of important recent results.

     

Numerical approximation of a nonisothermal two-dimensional general rate model of reactive liquid chromatography

A nonlinear and nonisothermal two-dimensional general rate model is formulated and approximated numerically to allow quantitatively analyzing the effects of temperature variations on the separations and reactions in liquid chromatographic reactors of cylindrical geometry. The model equations form a nonlinear system of convection-diffusion-reaction partial differential equations coupled with algebraic equations for isotherms and reactions. A semidiscrete high-resolution finite volume method is modified to approximate the system of partial differential equations. The coupling between the thermal waves and concentration fronts is demonstrated through numerical simulations, and important parameters are pointed out that influence the reactor performance. To evaluate the precision of the model predictions, consistency checks are successfully carried out proving the accuracy of the predictions. The results allow to quantify the influence of thermal effects on the performance of the fixed beds for different typical values of enthalpies of adsorption and reaction and axial and radial Peclet numbers for mass and heat transfer. Furthermore, they provide useful insight into the sensitivity of nonisothermal chromatographic reactor operation.     

A generalised life-expectancy model for a population

In a recent paper, it was shown that the life-expectancy behaviour for homogeneous and non-homogeneous population differs markedly for moderately high and low ages. One therefore has two curves for each of these regions and the problem is how to construct a single life-expectancy curve which blends these two curves together in a satisfactory way. This note offers a simple mathematical and analytical model which is useful in estimating an acceptable life expectancy under all severities of life situation. A simple numerical example is given to illustrate the application of the method.     

Collective dynamics of a dinuclear system

There are theoretical and experimental evidences that show that the cluster model, consisting of a dinuclear system, is capable of explaining several features of deformed heavy nuclei. Examples are the fusion to super-heavy nuclei and the nuclear-structure effects arising from parity splitting in alternating rotational parity bands, especially of the actinide nuclei. The model developed by Shneidman et al. has been able to explain the parity splitting in the actinides using the cluster model in which oscillations in mass asymmetry and relative motion were considered. On the other hand, Hess and Greiner developed a model for nuclear molecules in which the degrees of freedom of butterfly, belly-dancer-type motions, - and -vibrations of individual nuclei were incorporated. The purpose of this work is to extend the model of Shneidman et al. to include some of the degrees of freedom in the work of Hess et al. and, in addition, to consider nuclear molecular rotations and the coupling of these degrees of freedom among themselves, arising from mass asymmetry.Received: 7 April 2003, Revised: 5 February 2004, Published online: 15 April 2004PACS: 21.60.Ev Collective models - 21.60.Gx Cluster modelsE.D. Mshelia: Permanent address: Department of Physics, Abubakar Tafawa Balewa University, Bauchi, NigeriaWork supported by the German Academic Exchange Service (DAAD), Bonn, Germany.     

Spontaneous resolution of a novel chiral coordination polymer through supramolecular interactions and solvent symmetry breaking

The spontaneous resolution reaction of racemic trans-2,3-dihydro-2,3-dipyridyl-benzo[e]indole 1 with Cd(ClO₄)₂·6H₂O in the presence of 2-butanol under solvothermal reaction conditions favors the formation of crystal 2 [P-Cd(R,R,-1)₂(ClO₄)₂], while a similar reaction in the presence of ethanol only favors the formation of crystal 3 [M-Cd(S,S,-1)₂(ClO₄)₂]. The crystal structural determination shows that both 2 and 3 crystallize in chiral enantiomorphous space groups (P6₁22 and P6₅22) and their structures are 1D infinite chain, and are just enantiomorphous pairs most like. The spontaneous resolution process displays estimated ee values of ca. +0.6 for 2-butanol and ca. −0.4 for ethanol. Enantiomerically pure (S,S)-trans-2,3-dihydro-2,3-dipyridyl-benzo[e]indole (S,S,-1) can be obtained through the decomposition of mechanically separated 3. Additionally (S,S,-1) also crystallizes in a chiral space group (P2₁). The CD (circular dichroism) spectra of both 2 and 3 in the solid state are also approximately enantiomorphous pairs. However, their fluorescent spectra in the solid state display a moderate difference in maximum emission peaks (Δλ = 19 nm). Crystal data for 2: C₄₄H₃₄Cl₂N₆O₈Cd, M = 958.07, hexagonal, P6₁22, a = 10.5488(5), c = 68.256(4) Å, α = γ = 90°, β = 120°, V = 6577.8(6) Å³, Z = 6, D_c = 1.451 mg m⁻³, R₁ = 0.0498, wR₂ = 0.1124, μ = 0.679 mm⁻¹, S = 0.623, Flack χ = −0.02(6). For space group P6₅22, R₁ = 0.0670, wR₂ = 0.1602, S = 0.725 with a Flack value of 1.03(7); Crystal data for 3, C₄₄H₃₄Cl₂N₆O₈Cd, M = 958.07, hexagonal, P6₅22, a = 10.5446(3), c = 68.265(3) Å, V = 6573.3(4) Å³, Z = 6, D_c = 1.452 mg m⁻³, R₁ = 0.0444,wR₂ = 0.1002, μ = 0.679 mm⁻¹, S = 0.558, Flack χ = 0.01(5). For space group P6₁22, R₁ = 0.0501, wR₂ = 0.1178, S = 0.599 with a Flack value of 1.00(5). The low Flack parameter indicates that the absolute configurations of 2 and 3 are stated; Crystal data for (S,S)-1, C₂₂H₁₇N₂, M = 323.39, orthorhombic, P2₁2₁2₁, a = 9.2598(7), b = 9.4617(8), c = 19.1452(16) Å, V = 1677.4(2) Å³, Z = 4, D_c = 1.281 mg m⁻³, R₁ = 0.0417, wR₂ = 0.1191, T = 293 K, μ = 0.077 mm⁻¹, S = 0.862.     

Defect and doping concentration study with series and shunt resistance influence on graphene modified perovskite solar cell: A numerical investigation in SCAPS-1D framework

Perovskite solar cells (PSCs) have the potential to be highly efficient, low-cost next-generation solar cells. By raising open circuit voltage (V_oc), the interfacial recombination kinetics can further improve device performance. In this study, we used simulation concept to elucidate the influence of using graphene as a surface passivation material in perovskite solar cells. Graphene works well as an interlayer to promote hole extraction and reduce interfacial recombination. In order to evaluate the effect of graphene in PSCs, the simulation was done in the SCAPS-1D framework to compare the performance of a device with and without graphene. Three interface layers were included to the model: TiO₂/MAPbI₃, MAPbI₃/Graphene, and Graphene/Spiro-OMeTAD, in order to account for the impacts of interface defect density on device performance. The impacts of absorber doping concentration, absorber defect density, ETL doping concentration, HTL doping concentration, series resistance, and shunt resistance were also evaluated for the modelled PSC. Without any optimization, the control device with power conversion efficiency (PCE) of 20.677% was outperformed by the graphene-modified device with PCE of 20.911%. This difference is mostly due to the lower recombination losses and more effective suppression of interfacial non-radiative recombination. With optimization, the modified graphene-based device has a PCE of 26.667%. This result shows an enhancement of ∼1.28 times over that of the pristine graphene-based device. The outcomes have opened the way for the development of cost-effective and comparable state-of-the-art, high-efficiency perovskite solar cells with graphene interlayer by eliminating defects and managing non-radiative recombination.     

Challenges in slug modeling and control for offshore oil and gas productions: A review study

The upstream offshore multi-phase well-pipeline-riser installations are facing huge challenges related to slugging flow: An unstable flow regime where the flow rates, pressures and temperatures oscillate in the multi-phase pipelines. One typical severe slug is induced by vertical wells or risers causing the pressure to build up and hence originates the oscillating pressure and flow. There exist many negative consequences related to the severe slugging flow and thus lots of investments and effort have been put into reducing or completely eliminating the severe slug. This paper reviews in details the state-of-the-art related to analysis, detection, dynamical modeling and elimination of the slug within the offshore oil & gas Exploration and Production (E&P) processes. Modeling of slugging flow has been used to investigate the slug characteristics and for design of anti-slug control as well, however most models require specific facility and operating data which, unfortunately, often is not available from most offshore installations. Anti-slug control have been investigated for several decades in oil & gas industry, but many of these existing methods suffer the consequent risk of simultaneously reducing the oil & gas production. This paper concludes that slug is a well defined phenomenon, but even though it has been investigated for several decades the current anti-slug control methods still have problems related to robustness. It is predicted that slug-induced challenges will be even more severe as a consequence of the longer vertical risers caused by deep-water E&P in the future.