13C and 1H chemical shift assignments and conformation confirmation of trimedlure-Y via 2-D NMR

The conformation of 1,1-dimethylethyl 5-chloro-cis-2-methylcyclohexane-1-carboxylate (trimedlure-Y) was confirmed as 1,2,5 equatorial, axial, equatorial via ¹³C, ¹H, APT, CSCM and COSY NMR analyses. The carbon and proton nuclei in trimedlure-Y and the previously unassigned eight cyclohexyl protons (1.50–2.60 ppm) in 1,1-dimethylethyl 5-chloro-trans-2-methylcyclohexane-1-carboxylate (trimedlure-B₁; 1,2,5 equatorial, equatorial, equatorial) were also characterized by these methods. The effects of the 2-CH₃ in the axial or equatorial conformation upon the chemical shifts of the other nuclei in the molecule are discussed.     

An efficiemt synthetic method of methyl (±)-jasmonate

An efficient synthetic Method of methyl (±)-jasmonate is described. 2-Pentyny1-2-cyc1opentenone, the key intermediate in this route, was synthesized by applying the palladium-catalyzed enone formation from a11y1 β-keto carboylate as a key reaction.     

Quantum entanglement and quantum phase transitions in frustrated Majumdar-Ghosh model

By using the density matrix renormalization group technique, the quantum phase transitions in the frustrated Majumdar-Ghosh model are investigated. The behaviors of the conventional order parameter and the quantum entanglement entropy are analyzed in detail. The order parameter is found to peak at J₂∼0.58, but not at the Majumdar-Ghosh point (J₂=0.5). Although, the quantum entanglements calculated with different subsystems display dissimilarly, the extremes of their first derivatives approach to the same critical point. By finite size scaling, this quantum critical point J^C₂ converges to around 0.301 in the thermodynamic limit, which is consistent with those predicted previously by some authors (Tonegawa and Harada, 1987 [6]; Kuboki and Fukuyama, 1987 [7]; Chitra et al., 1995 [9]). Across the J^C₂, the system undergoes a quantum phase transition from a gapless spin-fluid phase to a gapped dimerized phase.     

Landau electron in a rotating environment: A general factorization of time evolution

For the Landau problem with a rotating magnetic field and a confining potential in the (changing) direction of the field, we derive a general factorization of the time evolution operator that includes the adiabatic factorization as a special case. The confining potential is assumed to be of a general form and it can correspond to nonlinear Heisenberg equations of motion. The rotation operator associated with the solid angle Berry phase is used to transform the problem to a rotating reference frame. In the rotating reference frame, we derive a natural factorization of the time evolution operator by recognizing the crucial role played by a gauge transformation. The major complexity of the problem arises from the coupling between motion in the direction of the magnetic field and motion perpendicular to the field. In the factorization, this complexity is consolidated into a single operator which approaches the identity operator when the potential confines the particle sufficiently close to a rotating plane perpendicular to the magnetic field. The structure of this operator is clarified by deriving an expression for its generating Hamiltonian. The adiabatic limit and non-adiabatic effects follow as consequences of the general factorization which are clarified using the magnetic translation concept.     

Microstructure,Rheology, and Potential Oil Absorbency of Poly(Butyl Methacrylate) and Poly(Hydroxyethyl Methacrylate) Blends

To prepare oil-absorptive polymers with moderate cross-linking structure, poly(butyl methacrylate) (PBMA) was synthesized as a linear hydrophobic polymer by suspension polymerization. In addition, hydroxyethyl methacrylate (HEMA), as a monomer, which could construct a network structure among the macromolecules via hydrogen bond interactions, was solution polymerized in dimethylacetamide (DMAc) with PBMA, yielding a polymer blend of PBMA and PHEMA. The solution of the polymer blend was investigated by rotational viscometry and extended rheometry. The results showed that the viscosity varied greatly with the temperature and shear rate for three different compositions. Fourier transform infrared (FTIR) spectra indicated that an entanglement or interlocking cross-linking structure of molecular chains was constructed by hydrogen bonds. The results from nuclear magnetic resonance (NMR) spectra exhibited a downfield movement of the proton peak as influenced by end groups or hydroxyls in the polymer chains. The rheological measurements demonstrated that the cross-linking structure greatly affected the rheological behavior of the blend solution. In addition, the cross-linking structure was also evaluated by oil absorbency of films.     

酞菁铜成膜特性的多重分形谱

运用多重分形理论,研究了酞菁铜颗粒的团聚生长成膜特性.研究表明薄膜生长是远离平衡态过程,在团聚生长中,颗粒分布有很大随机性,存在大范围的非均匀区域,这些区域具有多重分形特征.测试了酞菁铜对二氧化氮的气敏特性,结果表明通气前后,涂膜通道的频率有明显移动.     

关于声光效应光束偏转角的实验研究

对声光效应中光束偏转角进行了一系列实验研究.基于传统声光效应的基本原理,建立了光束偏转角理论模型并进行了相关计算.在此基础上进行声光效应的布拉格衍射实验.大量实验结果显示,所测量到的光束偏转角和理论值存在一定的差距.     

磁单极子进展概述

自磁单极子概念被狄拉克提出以来,不管是理论还是实验物理学家都一直在努力寻找,但迄今仍然没能找到它们存在的确凿证据.最近,一些凝聚态物理学家声称在动量空间以及自旋冰材料中找到了磁单极子存在的有力证据,并通过磁单极子的集体激发行为解释了一些新颖的物理现象.这使得磁单极子艰难的探索之路出现了一丝新的曙光.作为电动力学教学内容的补充,本文拟把磁单极子的最新进展做一个概述,让大学生对此有一个全面的认识,从而激发他们学习和科研的兴趣.     

Gray photorefractive polymeric optical spatial solitons

We show that gray spatial optical solitons are possible in biased photorefractive polymers under steady-state conditions. We find that for a given material parameter the absolute value of a gray photorefractive polymeric soliton's phase decreases with an increase in the beam's grayness, whereas it increases with the material parameter for a given beam's grayness and that the full width half maximum (FWHM) of the gray soliton beam's intensity increases with the beam's grayness when the normalized background intensity and the material parameter are fixed and decreases with an increase in the normalized background intensity when the material parameter is fixed. On the other hand, we also show that N coupled beam evolution equations in biased photorefractive polymers can exhibit multicomponent gray solitons. These multicomponent gray solitons can be obtained provided that the N coupled beams share the same polarization, wavelength, and are incoherent with one another. The characteristics and stability properties of these multicomponent gray solitons are also discussed in detail.