全文获取类型
收费全文 | 289篇 |
免费 | 68篇 |
国内免费 | 8篇 |
专业分类
化学 | 54篇 |
晶体学 | 5篇 |
力学 | 51篇 |
综合类 | 5篇 |
数学 | 97篇 |
物理学 | 153篇 |
出版年
2024年 | 2篇 |
2023年 | 11篇 |
2022年 | 48篇 |
2021年 | 32篇 |
2020年 | 30篇 |
2019年 | 11篇 |
2018年 | 15篇 |
2017年 | 11篇 |
2016年 | 10篇 |
2015年 | 14篇 |
2014年 | 18篇 |
2013年 | 22篇 |
2012年 | 33篇 |
2011年 | 19篇 |
2010年 | 15篇 |
2009年 | 12篇 |
2008年 | 5篇 |
2007年 | 3篇 |
2006年 | 2篇 |
2005年 | 2篇 |
2003年 | 3篇 |
2002年 | 1篇 |
2001年 | 4篇 |
1999年 | 2篇 |
1997年 | 4篇 |
1996年 | 1篇 |
1995年 | 2篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 2篇 |
1989年 | 1篇 |
1988年 | 5篇 |
1987年 | 12篇 |
1986年 | 8篇 |
1985年 | 2篇 |
1979年 | 1篇 |
排序方式: 共有365条查询结果,搜索用时 78 毫秒
1.
《European Journal of Operational Research》2006,174(1):646-667
We assess the benefits of sharing demand forecast information in a manufacturer–retailer supply chain, consisting of a traditional retail channel and a direct channel. The demand is a linear function of price with a Gaussian primary demand (i.e., zero-price market potential). Both the manufacturer and the retailer set their price based on their forecast of the primary demand. In this setting, we investigate the value of sharing demand forecasts. We analyze the ‘make-to-order’ scenario, in which prices are set before and production takes place after the primary demand is known, and the ‘make-to-stock’ scenario, in which production takes place and prices are set before the primary demand is known. We also compare the supply chain performance with and without the direct channel under some assumptions (production cost is zero, and each demand function has the same slope of price). We find that the direct channel has a negative impact on the retailer’s performance, and, under some conditions, the manufacturer and the whole supply chain are better off. Our research extends and complements prior research that has investigated only the inventory and replenishment-related benefits of information sharing. 相似文献
2.
正Molecular materials,together with metals,ceramics,and polymer materials,are among the most important materials.The research efforts on molecular materials are targeting three main aspects,namely the assembly technique,multi-functionality,and their diverse application.In this regard,the main attention from the community is focused on the identification and 相似文献
3.
The structural properties of the moments of the time to ruin are studied in dependent Sparre Andersen models. The moments of the time to ruin may be viewed as generalized versions of the Gerber–Shiu function. It is shown that structural properties of the Gerber–Shiu function hold also for the moments of the time to ruin. In particular, the moments continue to satisfy defective renewal equations. These properties are discussed in detail in the model of Willmot and Woo (2012), which has Coxian interclaim times and arbitrary time-dependent claim sizes. Structural quantities needed to determine the moments of the time to ruin are specified under this model. Numerical examples illustrating the methodology are presented. 相似文献
4.
《中国化学快报》2020,31(10):2698-2704
Multiple pollutants including pathogenic microorganism contaminations and emerging organic contaminations (EOCs) have shown a growing threat to the environment, especially the natural waters. However, the control and removal of pathogenic microorganism contaminations and EOCs have been greatly limited since limited knowledge of their environmental behaviors. Thus, a novel and efficient photocatalyst Ag2O/BiOBr heterojunction was synthesized and used for removal of multiple pollutants including Escherichia coli (E. coli), Staphylococcus aureus (S. aureus), tetracycline and acetaminophen under visible light. The results showed that there were valid electron transfer pathways between BiOBr and Ag2O, the main electron transfer direction was the BiOBr to Ag2O. Photo-generated electrons were stored in Ag2O and thus separation efficiency between holes and photo-generated electrons was obviously enhanced. Active oxygen species were highly produced and eventually end up with the high efficiency of removal of multiple pollutants. For Ag2O/BiOBr with Ag2O content at 3% (the best performance) under visible light, log decrease of E. coli was 7.16 (removal efficiency was 100%) in 120 min, log decrease of S. aureus was 7.23 (removal efficiency was 100%) in 160 min, C/C0 of tetracycline was 0.06 in 180 min, C/C0 of acetaminophen was 0.17 in 180 min. This work could provide a promising candidate in the actual contaminated natural waters for cleaning multiple pollutants. 相似文献
5.
目前许多新型高效金属催化剂在设计制备中都考虑到表面力学因素, 例如层状结构、核壳结构等, 其表面高活性原子受到不同程度的应变作用. 应变可直接改变金属的能带带隙, 对催化剂表面的电化学反应产生显著影响, 是一种有效提升材料催化活性的新思路和制备高性能催化剂的新途径, 因此受到了科研工作者的广泛关注. 传统的材料应变工程手段存在着活性物质层的应变值难以精确定量, 并缺少实时调控以及制备工艺繁琐等难题, 导致应变与电催化活性相关性规律识别方面的理论和实验研究进展缓慢. 相比于传统的材料手段, 交变载荷产生的应变具有幅值和频率的可变性以及连续的调控性, 在实验中可以完全排除噪声、缺陷、空位、基底效应等其他外部或材料本征的影响因素. 该综述从经典固液界面热力学表述出发, 简要介绍了电催化体系中的力?电?化学耦合效应, 归纳总结目前电催化体系中应变施加的实验手段和分析方法, 并基于目前相关研究着重讨论在交变载荷作用下应变对金属表面电催化反应的作用机理, 最后从力学角度展望了表面力学在电催化体系中的研究重点及发展趋势. 相似文献
6.
《Particuology》2022
The analytical infinite series solution of submicron particle transport in a circular tube bounded by a porous wall, such as a pinhole, is determined under the slip velocity boundary condition, and the solution is verified by using the experimental data in the previous studies for the specific cases. The results show that particle penetration rate increases with the increase of the porous parameter, the axial pressure drop, and the pinhole radius, whereas it decreases with increasing the pinhole length. The penetration rate of nano-particles are more sensitive to the variation of these parameters. However, the differences between the penetrations of particles ranging from 0.3 μm to 1 μm are not evident because the diffusion becomes weak gradually in this size range. In addition, a further comparison is performed between the analytical solution and the existing studies, and approximate expressions are presented for accurate calculation of particle penetration rate through pinholes appearing in porous materials including filter devices and masks. 相似文献
7.
8.
A citric acid ligand assisted self-assembly method is used for the synthesis of ternary mesoporous cerium lanthanum solid solution doped with metal elements (Co, Zr, Mg). Their textural property was characterized by X-ray diffraction, transmission electron microscopy, N2 adsorption-desorption, X-ray photoelectron spectroscopy and TPD techniques, and so on. The results of catalytic testing for synthesis of dimethyl carbonate (DMC) from CH3OH and CO2 indicated that the DMC yield reached 316 mmol/g on Ce-La-Co solid solution when the reaction temperature was 413 K and the reaction pressure was 8.0 MPa. It was found that Co had synergistic effect with La and Ce, doping of Co on the mesoporous Ce-La solid solution was helpful to increase the surface area of the catalyst, promote CO2 adsorption and activation, and improve the redox performance of solid solution catalyst. The conversion of Co2+ to Co3+ resulted in the continuous redox cycle between Ce4+ and Ce3+, and the oxygen vacancy content of the catalyst was increased. Studies have shown that the catalytic performance of Ce-La-Co solid solution is positively correlated with oxygen vacancy content. On this basis, the reaction mechanism of DMC synthesis from CO2 and CH3OH on the catalyst was speculated. 相似文献
9.
《Physics letters. A》1988,130(1):47-51
The hole-polarization mechanism of superconductivity proposed previously in the case of donors producing holes, which are distributed at random, is extended to systems with regular donor positions. The disordered arrangement of the real donor states, on which the indirect interaction between holes is based, is realized statistically within every unit cell. The optimum choice of the model parameters is discussed. 相似文献
10.
《Heat Recovery Systems and CHP》1988,8(6):549-558
The second law of thermodynamics has recently applied to various components and cycles by a theoretical approach. However, the application of this law practically is not common because the relevant concepts do not seem to be very important yet. In this study, the second law will be applied to absorption cooling cycles by defining two new effectivenesses of the system for two working fluids and the choice of working fluids will be based on this law. Besides permitting more realistic performance concepts from the economic and thermodynamic points of view, the second law analysis of absorption cooling cycles also offers an alternative absorbent/cooling combination (lithium bromide/water), which does not destroy the ozone layer. 相似文献