The effect of P2O5 on the ultra broadband near-infrared luminescence from bismuth-doped SiO2-Al2O3-CaO glass

The effect of P₂O₅ on infrared luminescence properties of bismuth-doped SiO₂-Al₂O₃-CaO (SAC) glass was investigated. Under excitation of 690 and 808 nm LD, two infrared emissions from bismuth ions central at 1100 and 1300 nm were observed, respectively. The addition of P₂O₅ was not only found to lead to the increase of full width at half maximum (FWHM) of two infrared emissions, but also result in intensity variety of the infrared emissions. The intensity of the infrared emission located at 1300 nm is reduced by a factor of 2, while the luminescence at 1110 nm is increased by a factor of 5. We propose that the infrared emissions at 1100 and 1300 nm may originate from different valence Bi ion in glasses. Compared with emission at 1300 nm, the infrared emissions at 1100 nm is more possibly from the transition of lower valent Bi ion.     

电热原子吸收光谱法测定奥沙利铂中的铅和砷

采用电热原子吸收光谱法测定抗肿瘤新药奥沙利铂中的痕量铅和砷,实验优选了灰化、原子化的最佳温度条件,进行了加标回收实验和精密度实验,加标回收率铅在97.88%—103.96%之间,砷在92.12%—105.72%之间。奥沙利铂是含贵金属的原料药,价格昂贵,检测时不耗费大量的样品、降低成本很重要。本法取样量少,不需要高温灰化和繁琐的样品富集和前处理技术,简单的酸溶解处理配成溶液后,即可直接上机测定,试样中的有机成分在灰化阶段可被除去。     

Dual-mode MMW/IR simulation of beam combiner

Along with the development of the optoelectronic interference technology, invisible technology and anti-radiation missile technology, missile guidance with single band or single mode cannot adapt for modern warfare. So the technology of combined guidance is proposed. In the field of combined guidance, MMW/IR combined guidance is more significant. The critical component of the MMW/IR semi-physical simulation will be discussed in this paper, and the selection principle of the substrate and coating materials used for dichroic beam combiner (DBC) is analyzed: MMW/IR beam combiner. By researching the method of the beam combiner of 8-18 GHz MW and 3-5 μm IR, the theory and simulation are discussed in detail in this paper. And the result is given. At the same time, the distortion effect on the MMW signal is analyzed theoretically and the method is presented. Substrate material is selected. The main problems and study factors include: MMW transmission, insertion phase delay, size of substrate material, and coating. At last, the substrate material is determined, and the thickness of the substrate material is optimized.     

A new insight into the LiFePO4 delithiation process

Raman and Fourier transform infrared measurements for Li_xM_0.03Fe_0.97PO₄, M = Cr, Cu, Al, Ti were performed. The spectra for delithiated samples to a low content of lithium extraction are practically the same as those of LiFePO₄. For a high content of lithium extraction, the spectra repeat that of FePO₄. In the case of the Li_0.11FePO₄ oxide the spectra cannot be reproduced just by the superposition of the end member profiles. An additional broad band contribution is found in both Raman and infrared spectra probably due to a disordered structure present in the mixture. This suggests that the well accepted two-phase model for the delithiation process in LiFePO₄ is incorrect. The model should be revised to include the new phase as detected here for a particular level of lithium extraction close to that of complete oxidation of the Fe²⁺ ions to Fe³⁺.     

Interfacial properties of g-C_3N_4/TiO_2 heterostructures studied by DFT calculations

Constructing the hetrostructure is a feasible strategy to enhance the performances of photocatalysts. However, there are still some fundamental details and mechanisms for the specific design of photocatalysts with heterostructure,which need further confirming and explain.In this work,g-C₃N₄-based heterostructures are constructed with TiO₂ in different ways,and their intrinsic factors to improve the photocatalytic activity are systematically studied by density functional theory(DFT).When g-C₃N₄ combines horizontally with TiO₂ to form a heterostructure,the interaction between them is dominated by van der Waals interaction.Although the recombination of photo-generated electron-hole pair cannot be inhibited significantly,this van der Waals interaction can regulate the electronic structures of the two components,which is conducive to the participation of photo-generated electrons and holes in the photocatalytic reaction.When the g-C₃N₄ combines vertically with TiO₂ to form a heterostructure,their interface states show obvious covalent features,which is very beneficial for the photo-generated electrons’ and holes’ transport along the opposite directions on both sides of the interface.Furthermore,the built-in electric field of g-C₃N₄/TiO₂ heterostructure is directed from TiO₂ layer to g-C₃N₄ layer under equilibrium,so the photo-generated electron-hole pairs can be spatially separated from each other.These calculated results show that no matter how g-C₃N₄ and TiO₂ are combined together,the g-C₃N₄/TiO₂ heterostructure can enhance the photocatalytic performance through corresponding ways.     

一个含有多余约束的线性规划问题改进算例

为了在不改变原有约束条件的情况下,充分利用现有条件,使规划的目标达到更优解。给出了两种含有多余约束的线性规划问题的改进方法:增加资源量或者减少资源量,并给出了一个具体的算例。     

Bifurcations of limit cycles in a Z6-equivariant planar vector field of degree 5

A concrete numerical example of Z₆-equivariant planar perturbed Hamiltonian polynomial vector fields of degree 5 having at least 24 limit cycles and the configurations of compound eyes are given by using the bifurcation theory of planar dynamical systems and the method of detection functions. There is reason to conjecture that the Hilbert number H(2k + 1) ⩾ (2k + I)² - 1 for the perturbed Hamiltonian systems.     

Improved electrical properties of La2/3Ba1/3MnO3:Ag0.04 thin films by thermal annealing

La_2/3Ba_1/3MnO₃:Ag_0.04 (LBMO:Ag_0.04) thin films were prepared on single crystalline (001)-orientated LaAlO₃ substrates by pulsed laser deposition technique. Thermal annealing with temperatures of 780, 800 and 820 °C has been investigated to improve electrical properties of the films. All the samples are shown along the (00l) orientation in rhombohedral structure with \( R\overline{3} c \) space group. With thermal annealing temperature increasing, insulator–metal transition temperature (T _p) and resistivity at T _p ( \( \rho_{{T_{\text{p}} }} \) ) of the epilayer reach optimal value of 288 K and 0.03 Ω·cm, respectively. The electrical properties improvement of the LBMO:Ag_0.04 films is due to an improved film crystallization, oxygen balance and photon scattering suppression. The fitting curves show that the region of ferro-magnetic metallic (FM, T < T _p) is fitted with grain/domain boundary, electron–electron and magnon scattering mechanism, as well as the region of para-magnetic insulating (PI, T > T _p) is fitted with adiabatic small polaron hopping mechanism.     

Exact explicit traveling wave solutions for two nonlinear Schrödinger type equations

The traveling wave solutions of the generalized nonlinear derivative Schrödinger equation and the high-order dispersive nonlinear Schrödinger equation are studied by using the approach of dynamical systems and the theory of bifurcations. With the aid of Maple, all bifurcations and phase portraits in the parametric space are obtained. All possible explicit parametric representations of the bounded traveling wave solutions (solitary wave solutions, kink and anti-kink wave solutions and periodic wave solutions) are given.     

The center conditions and bifurcation of limit cycles at the infinity for a cubic polynomial system

In this paper, the problem of center conditions and bifurcation of limit cycles at the infinity for a class of cubic systems are investigated. The method is based on a homeomorphic transformation of the infinity into the origin, the first 21 singular point quantities are obtained by computer algebra system Mathematica, the conditions of the origin to be a center and a 21st order fine focus are derived, respectively. Correspondingly, we construct a cubic system which can bifurcate seven limit cycles from the infinity by a small perturbation of parameters. At the end, we study the isochronous center conditions at the infinity for the cubic system.