Monolayer assembly and striped architecture of Co nanoparticles on organic functionalized Si surfaces

We present a new strategy to fabricate a monolayer assembly of Br-terminated Co nanoparticles on functionalized Si surfaces by using chemical covalent bonding and microcontact printing method. Self-assembled monolayers (SAMs) of the Co nanoparticles formed on the hydroxyl-terminated Si surface exhibit two-dimensional island networks with locally ordered arrays via covalent linkage between nanoparticles and surface. On the other hand, SAMs of the nanoparticles on the aminopropyl-terminated Si surface show an individual and random distribution over an entire surface. Furthermore, we have fabricated striped architectures of Co nanoparticles using a combination of microcontact printing and covalent linkage. Microcontact printing of octadecyltrichlorosilane and selective covalent linkage between nanoparticles and functionalized Si surfaces lead to a hybrid nanostructure with selectively assembled nanoparticles stripes on the patterned functionalized Si surfaces. PACS 81.07.Ta; 61.46.+w; 81.16.Dn; 81.16.Be; 68.37.Hk; 82.80.Pv     

Multi-resolution analysis of the large-scale coherent structure in a turbulent separation bubble affected by an unsteady wake

Multi-resolution analysis (MRA) was applied to the large-scale coherent structure in a turbulent separation bubble affected by an unsteady wake. The unsteady wake was generated using a spoked-wheel type wake generator, which was installed in front of the separation bubble. The wake generator was rotated either clockwise (CW) or counter-clockwise (CCW) with a normalized passing frequency of St_H=0.2. The Reynolds number based on the half-thickness of the blunt body was Re_H=5600. To show the unsteady dynamic flow structures between the ‘cutting’ and ‘wrapping’ regimes, a MRA using the maximal overlap discrete wavelet transform (MODWT) was performed. This method enabled delineation of the coherent structure of the turbulent separation bubble through a scale-resolved analysis. Reconstruction of the flow field in combination with conditional averaging was attempted. Flapping motions as well as sawtooth movements of the unsteady separation bubble were analyzed using the MODWT. The unsteady wakes decayed faster in the system with CCW rotation than in that with CW rotation.     

High-throughput screening of ferroelectric materials for non-volatile random access memory using multilayer perceptrons

During the last several years, the development of combinatorial technology has enabled synthesis of a huge amount of chemical compounds in a short time. The large number of variables makes the direct human interpretation of data derived from combinatorial experimentation for high-throughput screening (HTS) very difficult. Artificial neural networks using multilayer perceptrons (MLP) have been successfully applied to the regression problems with various material data. In this work, MLP model was applied to HTS of ferroelectric materials including Bi_4−xLa_xTi₃O₁₂ (BLT) and Bi_4−xCe_xTi₃O₁₂ (BCT). The model using MLP was made to predict the ferroelectric properties of whole feasible experimental conditions. Once a neural network model with high accuracy and good generalization performance was established, we could predict the expected optimal reaction conditions with the best characteristics. The highest gradient value obtained using MLP model is higher than the maximum value found from experiments, thereby accelerating the discovery of the optimal compositions and post-annealing time of BCT and BLT.     

Structural and optical properties of In0.5Ga0.5As/GaAs quantum dots in an In0.1Ga0.9As well using repeated depositions of InAs/GaAs short-period superlattices for the application of optical communication

We report structural and optical properties of In_0.5Ga_0.5As/GaAs quantum dots (QDs) in a 100 Å-thick In_0.1Ga_0.9As well grown by repeated depositions of InAs/GaAs short-period superlattices with atomic force microscope, transmission electron microscope (TEM) and photoluminescence (PL) measurement. The QDs in an InGaAs well grown at 510 °C were studied as a function of n repeated deposition of 1 monolayer thick InAs and 1 monolayer thick GaAs for n=5–10. The heights, widths and densities of dots are in the range of 6–22.0 nm, 40–85 nm, and 1.6–1.1×10¹⁰/cm², respectively, as n changes from 5 to 10 with strong alignment along [1 −1 0] direction. Flat and pan-cake-like shape of the QDs in a well is found in TEM images. The bottoms of the QDs are located lower than the center of the InGaAs well. This reveals that there was intermixing—interdiffusion—of group III materials between the InGaAs QD and the InGaAs well during growth. All reported dots show strong 300 K-PL spectrum, and 1.276 μm (FWHM: 32.3 meV) of 300 K-PL peak was obtained in case of 7 periods of the QDs in a well, which is useful for the application to optical communications.     

Oscillatory behavior of supersonic impinging jet flows

Oscillatory flows of a choked underexpanded supersonic impinging jet issuing from a convergent nozzle have been computed using the axisymmetric unsteady Navier--Stokes system. This paper focuses on the oscillatory flow features associated with the variation of the nozzle-to-plate distance and nozzle pressure ratio. Frequencies of the surface pressure oscillation and flow structural changes from computational results have been analyzed. Staging behavior of the oscillation frequency has been observed for both cases of nozzle-to-plate distance variation and pressure ratio variation. However, the staging behavior for each case exhibits different features. These two distinct staging behaviors of the oscillation frequency are found to correlate well if the frequency and the distance are normalized by the length of the shock cell. It is further found that the staging behavior is strongly correlated with the change of the pressure wave pattern in the jet shear layer, but not with the shock cell structure. Communicated by K. Takayama PACS 02.60.Cb; 47.40.−x; 47.40.Nm; 47.35.+I; 47.15.−x     

The least-squares meshfree method for rigid-plasticity with frictional contact

The least-squares meshfree method (LSMFM) for rigid-plasticity based on J₂-flow rule and infinitesimal theory is proposed. In the least-squares formulation the squared residuals of the constitutive and equilibrium equations are minimized. Those residuals are represented in a form of first-order differential system using the velocity and stress components as nodal unknowns and thus the proposed formulation is a mixed-type method. Also the penalty scheme for the enforcement of the boundary and frictional contact conditions is devised and the reshaping of nodal supports is introduced to avoid the difficulties due to the severe local deformation near the contact interface. The proposed method does not require any structure of extrinsic cells for the construction of shape functions, the treatment of incompressibility, the integration of variational formulation and the reconstruction of approximation. Through some numerical examples of metal forming processes, the validity and effectiveness of the method are discussed.     

Embedded Surfaces for Symplectic Circle Actions

The purpose of this article is to characterize symplectic and Hamiltonian circle actions on symplectic manifolds in terms of symplectic embeddings of Riemann surfaces.More precisely, it is shown that(1) if(M, ω) admits a Hamiltonian S~1-action, then there exists a two-sphere S in M with positive symplectic area satisfying c1(M, ω), [S] 0,and(2) if the action is non-Hamiltonian, then there exists an S~1-invariant symplectic2-torus T in(M, ω) such that c1(M, ω), [T] = 0. As applications, the authors give a very simple proof of the following well-known theorem which was proved by Atiyah-Bott,Lupton-Oprea, and Ono: Suppose that(M, ω) is a smooth closed symplectic manifold satisfying c1(M, ω) = λ· [ω] for some λ∈ R and G is a compact connected Lie group acting effectively on M preserving ω. Then(1) if λ 0, then G must be trivial,(2) if λ = 0, then the G-action is non-Hamiltonian, and(3) if λ 0, then the G-action is Hamiltonian.     

Fatigue crack growth behavior of Al7050-T7451 attachment lugs under flight spectrum variation

This paper discusses an analytical and experimental investigations of the fatigue crack growth behavior in attachment lugs subjected to a randomized flight-by-flight spectrum. In the analysis, the stress intensity factors for through-the-thickness cracks initiating from lug holes were compared by weight function method, boundary element method (BEM), the interpolation of Brussat’s solution. The stress intensity factors of a corner crack at a transition region were obtained using two parameter weight function method and correction factors. Fatigue life under a load spectrum was predicted using stress intensity factors and Willenborg retardation model considering the effects of a tensile overload. Experiments were performed under a load spectrum and compared with the fatigue life prediction using the stress intensity factors by different methods. Changes of fatigue life and aspect ratio according to the clipping level of the spectrum were discussed through experiment and prediction. Effect of the spectrum clipping level on the fatigue life was experimentally evaluated by using beach marks of fractured surface.     

Large-scale vortical structure of turbulent separation bubble affected by unsteady wake

The large-scale vortical structure of a turbulent separation bubble under the influence of an unsteady wake was investigated. The unsteady wake was generated by a spoked-wheel type wake generator installed in front of the separation bubble. This wake generator was rotated either clockwise or counter-clockwise at Re _H=5.600. The mechanism of vortex shedding from the separation bubble was analyzed in detail by taking a conditional average as well as a phase average. Spatial box filtering (SBF) was used to extract the large-scale vortical structure from the turbulent separation bubble affected by the unsteady wake. To elucidate the influence of the unsteady wake on the large-scale vortical structure, conditional averages of the velocity, vorticity and turbulent kinetic energy were calculated. The nature of the convection of the vortical structure under the influence of an unsteady wake was analyzed. The dipole acoustic pressure level was predicted using Curle's integral of wall-pressure fluctuations.     

Investigation on novel thermoplastic poly(urethane-thiourea-imide)s with enhanced chemical and heat resistance

A new generation of segmented thermoplastic poly(urethane-thiourea-imide)s (PUTIs) was synthesized via reaction of polyethylene glycol and thiourea-based prepolymer with dianhydride as chain extenders. NCO-terminated prepolymer was synthesized from a new diisocyanate, 3-(3-((4-isocyanatophenyl)carbamoyl)thioureido)phenyl-4-isocyanatophenylcarbamate (IPCT), as a hard segment and PEG forming soft segment. The starting materials and polymers were characterized by conventional methods and physical properties such as solubility, solution viscosity, molecular weight, thermal stability and thermal behavior were studied. PUTIs showed partially crystalline structures. Weight average molecular weights of PUTIs (GPC measurements) were in the range of 1,68,694-1,97,035. Moreover, thermogravimetric analysis indicated that poly(urethane-thiourea-imide)s were fairly stable above 500 °C having T₁₀ of 521-543 °C. Investigation of the results authenticated the approach of introducing thiourea (using IPCT) and imide structure in polyurethanes for the improvement of thermal stability. In comparison to typical polyurethanes, these polymers exhibited better heat resistance, chemical resistance as well as processability.